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    • 106. 发明授权
    • Method for epitaxial growth of silicon carbide
    • 碳化硅外延生长方法
    • US07404858B2
    • 2008-07-29
    • US11521869
    • 2006-09-15
    • Yaroslav Koshka
    • Yaroslav Koshka
    • C30B25/12
    • C30B25/02C23C16/325C30B29/36
    • A method for epitaxial growth of silicon carbide using chemical vapor deposition (CVD) is provided. This method utilizes halogenated carbon precursors and control of the gas-phase interaction of halogen-containing intermediate chemical products involving silicon and carbon, which ensures quality and homogeneity across the silicon carbide crystals. It also ensures a possibility to achieve device-quality epitaxial layers at lower growth temperatures as well as on on-axis or low off-angle substrate surfaces. The growth method can be applied to forming SiC device regions of desirable shape and dimensions by restricting the growth into windows formed in non-silicon carbide region on the top of SiC substrate. Application of the methods described herein will greatly benefit the production of high quality silicon carbide materials and devices.
    • 提供了一种使用化学气相沉积(CVD)进行外延生长的碳化硅的方法。 该方法利用卤代碳前体和控制涉及硅和碳的含卤素中间体化学产品的气相相互作用,确保碳化硅晶体之间的质量和均匀性。 它还确保了在较低生长温度以及在轴上或低偏角基板表面上实现器件质量外延层的可能性。 通过将生长方法限制在SiC衬底顶部的非碳化硅区域中形成的窗口,可以将生长方法应用于形成所需形状和尺寸的SiC器件区域。 本文描述的方法的应用将极大地有利于生产高质量的碳化硅材料和器件。
    • 107. 发明授权
    • Ceramic thin film on various substrates, and process for producing same
    • 各种基材上的陶瓷薄膜及其制造方法
    • US07396563B2
    • 2008-07-08
    • US10515450
    • 2003-05-23
    • Mihai ScarleteCetin Aktik
    • Mihai ScarleteCetin Aktik
    • C23C16/00C23C16/22
    • C23C16/46C23C16/325Y10T428/265Y10T428/31504
    • The process of Polymer Assisted Chemical Vapor Deposition (PACVD) and the semiconductor, dielectric, passivating or protecting thin films produced by the process are described. A semiconductor thin film of amorphous silicon carbide is obtained through vapor deposition following desublimation of pyrolysis products of polymeric precursors in inert or active atmosphere. PA-CVD allows one or multi-layers compositions, microstructures and thicknesses to be deposited on a wide variety of substrates. The deposited thin film from desublimation is an n-type semiconductor with a low donor concentration in the range of 1014-1017 cm−3. Many devices can be fabricated by the PA-CVD method of the invention such as; solar cells; light-emitting diodes; transistors; photothyristors, as well as integrated monolithic devices on a single chip. Using this novel technique, high deposition rates can be obtained from chemically synchronized Si—C bonds redistribution in organo-polysilanes in the temperature range of about 200-450° C.
    • 描述了聚合物辅助化学气相沉积(PACVD)的过程以及由该方法生产的半导体,电介质,钝化或保护薄膜。 非晶碳化硅的半导体薄膜通过气相淀积获得,在惰性或活性气氛中,将聚合物前体的热解产物描述出来。 PA-CVD允许将一层或多层组合物,微结构和厚度沉积在各种基材上。 淀积的沉积薄膜是一种n型半导体,具有低的供体浓度,范围为10〜14℃至3±3℃, 。 许多器件可以通过本发明的PA-CVD法制造,例如: 太阳能电池; 发光二极管; 晶体管 光电晶体管,以及单个芯片上的集成单片设备。 使用这种新技术,可以在约200-450℃的温度范围内从有机聚硅烷中的化学同步Si-C键再分布获得高沉积速率。