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101. 发明授权

US5646194A Plastic foam material composed of thermoplastic resin and silane-modified thermoplastic resin and method for making same 失效
公开(公告)号：US5646194A
公开(公告)日：1997-07-08
申请号：US651519
申请日：1996-05-22
申请人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
发明人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
IPC分类号： B29C44/02 , B29C44/12 , C08J9/00 , C08J9/10 , C08L23/02 , C08L23/06 , C08L23/10 , C08L23/12 , C08L25/04 , C08L51/06 , C08J3/22 , B29C47/88
CPC分类号： C08L23/02 , B29C44/022 , B29C44/1228 , C08J9/0061 , C08J9/103 , C08L23/06 , C08L23/0853 , C08L23/10 , C08L23/12 , C08L23/14 , C08L25/04 , C08L25/06 , C08J2201/03 , C08J2323/02 , C08J2325/06 , C08J2451/00 , C08L2205/03 , C08L2205/035 , C08L2312/08 , C08L51/06 , Y02P20/52 , Y10T428/1376 , Y10T428/139 , Y10T428/1393 , Y10T428/24744 , Y10T428/249954 , Y10T428/24996 , Y10T428/249971 , Y10T428/249972 , Y10T428/249974 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913
摘要： A plastic foam material composed of a blended resin composition which includes at least two thermoplastic resins and a silane-modified based resin. The blended resin composition consists essentially of 100 parts by weight of at least two thermoplastic resins, from about 1 to about 50 parts by weight of a silane-modified, cross-linked, thermoplastic resin; from about 0.001 to about 2.5 parts by weight of a cross-linking catalyst for use in a silane compound and from about 1 to about 20 parts by weight of a foaming agent. According to one embodiment of the present invention, the thermoplastic resins include at least two substantially incompatible and substantially uncross-linked thermoplastic resins, while in another embodiment the two thermoplastic resins need not be substantially incompatible. The blended resin composition may further include reinforcers such as glass fibers and filler. The thermodecomposition foaming agent decomposes at sufficiently high temperatures to yield a plastic foam material. The resultant plastic foam material, in turn, exhibits superior resilience, improved compression strength and superior heat-insulating properties. A method to produce the plastic foam material from foamable tubes and foamable pieces is also disclosed.

102. 发明授权

US5594038A Plastic foam material composed of thermoplastic resin and silane-modified thermoplastic resin and method for making same 失效
标题翻译：由热塑性树脂和硅烷改性热塑性树脂组成的塑料泡沫材料及其制造方法
公开(公告)号：US5594038A
公开(公告)日：1997-01-14
申请号：US652277
申请日：1996-05-22
申请人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
发明人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
IPC分类号： B29C44/02 , B29C44/12 , C08J9/00 , C08J9/10 , C08L23/02 , C08L23/06 , C08L23/10 , C08L23/12 , C08L25/04 , C08L51/06 , C08G77/00
CPC分类号： C08L23/02 , B29C44/022 , B29C44/1228 , C08J9/0061 , C08J9/103 , C08L23/06 , C08L23/0853 , C08L23/10 , C08L23/12 , C08L23/14 , C08L25/04 , C08L25/06 , C08J2201/03 , C08J2323/02 , C08J2325/06 , C08J2451/00 , C08L2205/03 , C08L2205/035 , C08L2312/08 , C08L51/06 , Y02P20/52 , Y10T428/1376 , Y10T428/139 , Y10T428/1393 , Y10T428/24744 , Y10T428/249954 , Y10T428/24996 , Y10T428/249971 , Y10T428/249972 , Y10T428/249974 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913
摘要： A plastic foam material composed of a blended resin composition which includes at least two thermoplastic resins and a silane-modified based resin. The blended resin composition consists essentially of 100 parts by weight of at least two thermoplastic resins, from about 1 to about 50 parts by weight of a silane-modified, cross-linked, thermoplastic resin; from about 0.001 to about 2.5 parts by weight of a cross-linking catalyst for use in a silane compound and from about 1 to about 20 parts by weight of a foaming agent. According to one embodiment of the present invention, the thermoplastic resins include at least two substantially incompatible and substantially uncross-linked thermoplastic resins, while in another embodiment the two thermoplastic resins need not be substantially incompatible. The blended resin composition may further include reinforcers such as glass fibers and filler. The thermodecomposition foaming agent decomposes at sufficiently high temperatures to yield a plastic foam material. The resultant plastic foam material, in turn, exhibits superior resilience, improved compression strength and superior heat-insulating properties. A method to produce the plastic foam material from foamable tubes and foamable pieces is also disclosed.
摘要翻译：一种由包含至少两种热塑性树脂和硅烷改性基树脂的共混树脂组合物组成的塑料泡沫材料。共混树脂组合物基本上由100重量份的至少两种热塑性树脂，约1至约50重量份的硅烷改性的交联的热塑性树脂组成; 约0.001至约2.5重量份的用于硅烷化合物的交联催化剂和约1至约20重量份的发泡剂。根据本发明的一个实施方案，热塑性树脂包括至少两种基本上不相容的和基本上未交联的热塑性树脂，而在另一个实施方案中，两种热塑性树脂不必基本上不相容。混合树脂组合物还可以包括玻璃纤维和填料等增强剂。热分解发泡剂在足够高的温度下分解以产生塑料泡沫材料。所得到的塑料泡沫材料又具有优异的回弹性，改进的抗压强度和优异的绝热性能。还公开了一种从发泡管和可发泡件生产塑料泡沫材料的方法。

103. 发明授权

US5552448A Plastic foam material composed of thermoplastic resin and silane-modified thermoplastic resin and method for making same 失效
标题翻译：由热塑性树脂和硅烷改性热塑性树脂组成的塑料泡沫材料及其制造方法
公开(公告)号：US5552448A
公开(公告)日：1996-09-03
申请号：US309960
申请日：1994-09-21
申请人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
发明人： Tomoyuki Kobayashi , Kenji Miyazaki , Masanori Nakamura
IPC分类号： B29C44/02 , B29C44/12 , C08J9/00 , C08J9/10 , C08L23/02 , C08L23/06 , C08L23/10 , C08L23/12 , C08L25/04 , C08L51/06 , C08G77/00
CPC分类号： C08L23/02 , B29C44/022 , B29C44/1228 , C08J9/0061 , C08J9/103 , C08L23/06 , C08L23/0853 , C08L23/10 , C08L23/12 , C08L23/14 , C08L25/04 , C08L25/06 , C08J2201/03 , C08J2323/02 , C08J2325/06 , C08J2451/00 , C08L2205/03 , C08L2205/035 , C08L2312/08 , C08L51/06 , Y02P20/52 , Y10T428/1376 , Y10T428/139 , Y10T428/1393 , Y10T428/24744 , Y10T428/249954 , Y10T428/24996 , Y10T428/249971 , Y10T428/249972 , Y10T428/249974 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913
摘要： A plastic foam material composed of a blended resin composition which includes at least two thermoplastic resins and a silane-modified based resin. The blended resin composition consists essentially of 100 parts by weight of at least two thermoplastic resins, from about 1 to about 50 parts by weight of a silane-modified, cross-linked, thermoplastic resin; from about 0.001 to about 2.5 parts by weight of a cross-linking catalyst for use in a silane compound and from about 1 to about 20 parts by weight of a foaming agent. According to one embodiment of the present invention, the thermoplastic resins include at least two substantially incompatible and substantially uncross-linked thermoplastic resins, while in another embodiment the two thermoplastic resins need not be substantially incompatible. The blended resin composition may further include reinforcers such as glass fibers and filler. The thermodecomposition foaming agent decomposes at sufficiently high temperatures to yield a plastic foam material. The resultant plastic foam material, in turn, exhibits superior resilience, improved compression strength and superior heat-insulating properties. A method to produce the plastic foam material from foamable tubes and foamable pieces is also disclosed.
摘要翻译：一种由包含至少两种热塑性树脂和硅烷改性基树脂的共混树脂组合物组成的塑料泡沫材料。共混树脂组合物基本上由100重量份的至少两种热塑性树脂，约1至约50重量份的硅烷改性的交联的热塑性树脂组成; 约0.001至约2.5重量份的用于硅烷化合物的交联催化剂和约1至约20重量份的发泡剂。根据本发明的一个实施方案，热塑性树脂包括至少两种基本上不相容的和基本上未交联的热塑性树脂，而在另一个实施方案中，两种热塑性树脂不必基本上不相容。混合树脂组合物还可以包括玻璃纤维和填料等增强剂。热分解发泡剂在足够高的温度下分解以产生塑料泡沫材料。所得到的塑料泡沫材料又具有优异的回弹性，改进的抗压强度和优异的绝热性能。还公开了一种从发泡管和可发泡件生产塑料泡沫材料的方法。

104. 发明授权

US5089291A Method for forming hard coat on polyolefin 失效
标题翻译：在聚烯烃上形成硬涂层的方法
公开(公告)号：US5089291A
公开(公告)日：1992-02-18
申请号：US295396
申请日：1989-01-10
申请人： Kazuhide Hayama , Noritaka Hosokawa , Takao Yazaki , Masataka Noro
发明人： Kazuhide Hayama , Noritaka Hosokawa , Takao Yazaki , Masataka Noro
IPC分类号： B32B7/02 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/30 , B32B27/32 , B32B37/00 , C08F2/50 , C08J5/12 , C08J7/04
CPC分类号： C08J5/128 , C08J7/047 , C08J2323/02 , C08J2433/00 , C08J2451/00 , Y10T428/31913 , Y10T428/31928
摘要： A method of forming a hard coat on a polyolefin base, a composite laminate or a formed article is disclosed, which comprises coating the surface of the polyolefin base with an ultraviolet-curable resin composition comprising (a) a polymer containing at least 80% by weight of methyl methacrylate and/or a modified polymer containing at least 80% by weight of methyl methacrylate and having introduced into the side chain thereof a (meth)acryloyl group, (b) a polyfunctional acrylate containing at least 50% by weight of dipentaerythritol hexaacrylate, the weight ratio of components (a) to (b) being from 1 to 10, and (c) a photopolymerization initiator, drying the coating to form an ultraviolet-curable resin layer, and curing the ultraviolet-curable resin layer by irradiation with ultraviolet light.

105. 发明授权

US4997882A Acid or anhydride grafted chlorinated polyolefin reacted with monoalcohol and polyepoxide 失效
标题翻译：酸或酸酐接枝的氯化聚烯烃与一元醇和聚环氧化物反应
公开(公告)号：US4997882A
公开(公告)日：1991-03-05
申请号：US376441
申请日：1989-07-07
申请人： Jonathan T. Martz , James B. O'Dwyer , Marvis E. Hartman
发明人： Jonathan T. Martz , James B. O'Dwyer , Marvis E. Hartman
IPC分类号： B05D3/10 , B05D7/02 , C08F8/14 , C08G59/14 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08F8/14 , C08J2323/02 , C08J2451/00
摘要： Disclosed is an ungelled, modified chlorinated polyolefin resin suitable for providing a highly adherent, solvent resistant film on a thermoplastic polyolefin substrate. The modified chlorinated polyolefin resin is prepared by grafting an unsaturated polycarboxylic acid and/or an unsaturated acid anhydride onto a chlorinated polyolefin resin to form an acid- and/or anhydride-modified chlorinated polyolefin resin. The resulting acid- and/or anhydride-modified chlorinated polyolefin resin is reacted with an organic monohydric alcohol to form an esterified product containing acid functionality. The resulting esterified product is reacted with a polyepoxide to form the ungelled modified chlorinated polyolefin resin.Also disclosed is a method of preparing an ungelled modified chlorinated polyolefin resin of the invention, a coating composition containing a resin of the invention, and a method of forming a hardened film from the coating composition on a thermoplastic polyolefin substrate.
摘要翻译：公开了一种未凝胶化的改性氯化聚烯烃树脂，其适于在热塑性聚烯烃基材上提供高粘附性，耐溶剂性的膜。通过将不饱和多羧酸和/或不饱和酸酐接枝到氯化聚烯烃树脂上以形成酸和/或酸酐改性的氯化聚烯烃树脂来制备改性氯化聚烯烃树脂。将所得酸和/或酸酐改性的氯化聚烯烃树脂与有机一元醇反应形成含有酸官能团的酯化产物。所得酯化产物与聚环氧化物反应形成未凝胶化的改性氯化聚烯烃树脂。还公开了制备本发明的未凝胶化改性氯化聚烯烃树脂的方法，含有本发明树脂的涂料组合物和在热塑性聚烯烃基材上由涂料组合物形成硬化膜的方法。

106. 发明授权

US4555442A Polyoxyalkylene/unsaturated diester reaction product for cellular foam stabilization 失效
公开(公告)号：US4555442A
公开(公告)日：1985-11-26
申请号：US722248
申请日：1985-04-11
申请人： Richard L. Frentzel
发明人： Richard L. Frentzel
IPC分类号： C08F283/06 , C08J9/00 , B32B3/26
CPC分类号： C08J9/0061 , C08F283/06 , C08J2451/00 , Y10S521/902 , Y10S521/911 , Y10T428/249976 , Y10T428/249987 , Y10T428/24999
摘要： Polyoxyalkylene surfactants for cellular foams can be prepared by reacting a polyoxyalkylene adduct and an esterified unsaturated dibasic acid in the presence of a free-radical initiator.

107. 发明授权

US4529745A Unsaturated polyoxyalkylene adduct/fumarate diester reaction product for cellular foam stabilization 失效
公开(公告)号：US4529745A
公开(公告)日：1985-07-16
申请号：US490279
申请日：1983-05-02
申请人： Michael E. Londrigan
发明人： Michael E. Londrigan
IPC分类号： B32B5/18 , B01F17/00 , C08F290/00 , C08F290/06 , C08F299/00 , C08G18/00 , C08G65/26 , C08G65/332 , C08J9/00 , C08J9/02 , C08J5/12
CPC分类号： C08J9/0061 , B01F17/0028 , C08F290/062 , C08G65/2609 , C08G65/2615 , C08G65/3322 , C08J2451/00 , Y10T428/31591 , Y10T428/31601 , Y10T428/31605
摘要： Polyoxyalkylene surfactants for cellular foams can be prepared by reacting under free radical polymerization conditions (1) an unsaturated polyoxyalkylene adduct and (2) an esterified unsaturated dibasic acid ingredient, wherein unsaturated diester ingredient (2) either completely or partially comprises a fumarate diester.

108. 发明授权

US4522877A Extraction of polyoxyalkylene surfactants for phenolic foam stabilization 失效
公开(公告)号：US4522877A
公开(公告)日：1985-06-11
申请号：US670785
申请日：1984-11-13
申请人： Richard L. Frentzel , Ernest K. Moss
发明人： Richard L. Frentzel , Ernest K. Moss
IPC分类号： B01F17/00 , B01F17/54 , B32B5/18 , C08F283/06 , C08J9/00 , B32B3/26
CPC分类号： C08J9/0061 , B01F17/005 , B01F17/0064 , B01F17/0071 , B32B5/18 , C08F283/06 , C08J2451/00 , Y10T428/249953 , Y10T428/249976 , Y10T428/249987
摘要： Polyoxyalkylene foam stabilizing surfactants can be prepared by reacting a polyoxyalkylene adduct, a cyclic nitrogenous vinyl monomer and an esterified unsaturated dibasic acid under free radical polymerization conditions in the presence of a free radical initiator, and by subjecting the reaction product obtained to a solvent extraction. The isolated components can be utilized as surfactants in producing cellular foams.

109. 发明授权

US4365024A Polyoxyalkylene/unsaturated diester reaction product for cellular foam stabilization 失效
公开(公告)号：US4365024A
公开(公告)日：1982-12-21
申请号：US282322
申请日：1981-07-10
申请人： Richard L. Frentzel
发明人： Richard L. Frentzel
IPC分类号： B32B5/18 , B32B5/28 , C08F283/06 , C08G18/00 , C08J9/00 , C08J9/04 , C08J9/14
CPC分类号： C08J9/0061 , C08F283/06 , C08J2451/00
摘要： Polyoxyalkylene surfactants for cellular foams can be prepared by reacting a polyoxyalkylene adduct and an esterified unsaturated dibasic acid in the presence of a free-radical initiator.

110. 发明授权

US4204020A Phenolic foam laminated structural panel 失效
标题翻译：酚醛泡沫层压结构面板
公开(公告)号：US4204020A
公开(公告)日：1980-05-20
申请号：US935846
申请日：1978-08-22
申请人： John H. Beale , Ernest K. Moss
发明人： John H. Beale , Ernest K. Moss
IPC分类号： C08F283/00 , C08J9/00 , C08J9/14
CPC分类号： C08J9/0061 , C08F283/00 , C08J2361/06 , C08J2451/00 , Y10T428/249977 , Y10T428/249987 , Y10T428/24999
摘要： A closed cell phenolic-resin foam material comprising phenolic-resin foam forming reactants, a blowing agent, and a surfactant which is the capped reaction product of an alkoxylated amine and a copolymerizable mixture of dialkyl maleate with N-vinyl-2- pyrrolidone or N-vinyl caprolactam.
摘要翻译：一种闭孔酚醛树脂泡沫材料，其包含酚醛树脂泡沫形成反应物，发泡剂和表面活性剂，其是烷氧基化胺和马来酸二烷基酯与N-乙烯基-2-吡咯烷酮或N的可共聚混合物的封端反应产物乙烯基己内酰胺。

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