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101. 发明授权

US6093859A Process for the manufacture of 1,1,1,3,3-pentafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷的方法
公开(公告)号：US6093859A
公开(公告)日：2000-07-25
申请号：US323736
申请日：1999-06-01
申请人： Mario Joseph Nappa , V. N. Mallikarjuna Rao , Allen Capron Sievert
发明人： Mario Joseph Nappa , V. N. Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： B01J27/06 , B01J21/10 , B01J23/06 , B01J23/26 , B01J27/10 , B01J27/12 , B01J27/125 , B01J27/132 , B01J27/138 , C07B61/00 , C07C17/25 , C07C17/354 , C07C17/383 , C07C19/08
CPC分类号： C07C19/08 , B01J27/10 , B01J27/12 , C07C17/25 , C07C17/354 , C07C17/383 , B01J21/10 , B01J23/06 , B01J23/26 , B01J27/125 , B01J27/132 , B01J27/138
摘要： A process is disclosed for producing the hydrofluorocarbon CF.sub.3 CH.dbd.CF.sub.2. The process involves dehydrofluorinating CF.sub.3 CH.sub.2 CF.sub.3 at an elevated temperature in the vapor phase over a catalyst of (1) aluminum fluoride, (2) fluorided alumina, (3) metal supported on a trivalent aluminum compound containing fluoride anion, (4) lanthanum fluoride, (5) fluorided lanthanum oxide, (6) metal supported on a trivalent lanthanum compound containing fluoride anion, (7) trivalent chromium compounds and/or (8) catalysts of (a) at least one compound selected from the oxides, fluorides and oxyfluorides of magnesium, zinc and mixtures of magnesium and zinc, and optionally (b) at least one compound selected from the oxides, fluorides and oxyfluorides of aluminum, provided that the atomic ratio of aluminum to the total of magnesium and zinc in said catalyst is about 1:4, or less, to produce a product containing CF.sub.3 CH.dbd.CF.sub.2 and HF. The CF.sub.3 CH.dbd.CF.sub.2 may then be reacted in the vapor phase with hydrogen over a hydrogenation catalyst in the presence of HF to produce CF.sub.3 CH.sub.2 CHF.sub.2.
摘要翻译：公开了一种生产氢氟烃CF 3 CH = CF 2的方法。该方法包括在（1）氟化铝，（2）氟化氧化铝，（3）负载在含氟化物阴离子的三价铝化合物上的金属，（4）氟化镧（（ⅰ））的催化剂上，在气相中升高的温度下，将CF 3 CH 2 CF 3脱氟化氢 5）氟化镧氧化物，（6）负载在含氟化物阴离子的三价镧化合物上的金属，（7）三价铬化合物和/或（a）至少一种选自氧化物，氟化物和氟氧化物的化合物的催化剂镁，锌和镁和锌的混合物，以及任选地（b）至少一种选自铝的氧化物，氟化物和氟氧化物的化合物，条件是铝与所述催化剂中镁和锌的原子比为约1 ：4或更少，以产生含有CF 3 CH = CF 2和HF的产物。然后在HF存在下，CF 3 CH = CF 2可以在气相中与氢气在氢化催化剂上反应生成CF 3 CH 2 CHF 2。

102. 发明授权

US5945573A Process for the manufacture of 1,1,1,3,3-pentafluoropropane 失效
标题翻译：制备1,1,1,3,3-五氟丙烷的方法
公开(公告)号：US5945573A
公开(公告)日：1999-08-31
申请号：US5400
申请日：1998-01-09
申请人： Mario Joseph Nappa , V. N. Mallikarjuna Rao , Allen Capron Sievert
发明人： Mario Joseph Nappa , V. N. Mallikarjuna Rao , Allen Capron Sievert
IPC分类号： B01J27/06 , B01J21/10 , B01J23/06 , B01J23/26 , B01J27/10 , B01J27/12 , B01J27/125 , B01J27/132 , B01J27/138 , C07B61/00 , C07C17/25 , C07C17/354 , C07C17/383 , C07C19/08 , C07C17/34
CPC分类号： C07C19/08 , B01J27/10 , B01J27/12 , C07C17/25 , C07C17/354 , C07C17/383 , B01J21/10 , B01J23/06 , B01J23/26 , B01J27/125 , B01J27/132 , B01J27/138
摘要： A process is disclosed for producing the hydrofluorocarbon CF.sub.3 CH.sub.2 CHF.sub.2. The process involves dehydrofluorinating CF.sub.3 CH.sub.2 CF.sub.3 at an elevated temperature in the vapor phase over a catalyst of (1) aluminum fluoride, (2) fluorided alumina, (3) metal supported on a trivalent aluminum compound containing fluoride anion, (4) lanthanum fluoride, (5) fluorided lanthanum oxide, (6) metal supported on a trivalent lanthanum compound containing fluoride anion, (7) trivalent chromium compounds and/or (8) catalysts of (a) at least one compound selected from the oxides, fluorides and oxyfluorides of magnesium, zinc and mixtures of magnesium and zinc, and optionally (b) at least one compound selected from the oxides, fluorides and oxyfluorides of aluminum, provided that the atomic ratio of aluminum to the total of magnesium and zinc in said catalyst is about 1:4, or less, to produce a product containing CF.sub.3 CH.dbd.CF.sub.2 and HF; and reacting the CF.sub.3 CH.dbd.CF.sub.2 in the vapor phase with hydrogen over a hydrogenation catalyst in the presence of HF to produce CF.sub.3 CH.sub.2 CHF.sub.2.
摘要翻译：公开了用于生产氢氟烃CF 3 CH 2 CHF 2的方法。该方法包括在（1）氟化铝，（2）氟化氧化铝，（3）负载在含氟化物阴离子的三价铝化合物上的金属，（4）氟化镧（（ⅰ））的催化剂上，在气相中升高的温度下将CF 3 CH 2 CF 3脱氟化氢 5）氟化镧氧化物，（6）负载在含氟化物阴离子的三价镧化合物上的金属，（7）三价铬化合物和/或（a）至少一种选自氧化物，氟化物和氟氧化物的化合物的催化剂镁，锌和镁和锌的混合物，以及任选地（b）至少一种选自铝的氧化物，氟化物和氟氧化物的化合物，条件是铝与所述催化剂中镁和锌的原子比为约1 ：4或更少，以产生含有CF 3 CH = CF 2和HF的产物; 并在氢气存在下使氢气中的CF 3 CH = CF 2与氢气反应，生成CF 3 CH 2 CHF 2。

103. 发明授权

US09139498B2 Catalytical synthesis of hydrohalocarbons 有权
标题翻译：氢卤代烃的催化合成
公开(公告)号：US09139498B2
公开(公告)日：2015-09-22
申请号：US13988121
申请日：2011-11-07
申请人： Mario Joseph Nappa , Ekaterina N Swearingen , Sergei Rafailovich Sterlin
发明人： Mario Joseph Nappa , Ekaterina N Swearingen , Sergei Rafailovich Sterlin
IPC分类号： C07C17/278 , C07C19/10 , C07C17/383
CPC分类号： C07C17/278 , C07C17/383 , C07C19/10
摘要： A process is disclosed for producing addition compound CF3CCl2CH2CClXR, wherein X═H, F, Cl or Br, and R═H or a perhalogenated alkyl group, provided that X and R are not both H. The process involves a liquid phase reaction of 1,1,1-trichlorotrifluoroethane with CH2═CXR in the presence of an addition catalyst.
摘要翻译：公开了制备加成化合物CF 3 CCl 2 CH 2 ClClR的方法，其中X = H，F，Cl或Br，以及R = H或全卤代烷基，条件是X和R不同时为H.该方法涉及液相反应1 ，在加成催化剂存在下，使用CH 2 = C X R的1,1-三氯三氟乙烷。

104. 发明授权

US09102580B2 Catalytic fluorination process of making hydrohaloalkane 有权
标题翻译：制备氢卤代烷烃的催化氟化过程
公开(公告)号：US09102580B2
公开(公告)日：2015-08-11
申请号：US14357345
申请日：2012-11-09
申请人： Mario Joseph Nappa , Andrew Jackson , Daniel C. Merkel
发明人： Mario Joseph Nappa , Andrew Jackson , Daniel C. Merkel
IPC分类号： C07C17/087 , C07C17/25 , C07C17/38 , C07C17/20 , B01J37/26 , B01J27/12 , B01J27/135
CPC分类号： C07C17/38 , B01J27/12 , B01J27/135 , B01J37/26 , C07C17/087 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present disclosure provides a fluorination process which involves reacting a hydrohaloalkene of the formula RfC—Cl═CH2 with HF in a reaction zone in the presence of a fluorination catalyst selected from the group consisting of TaF5 and TiF4 to produce a product mixture containing a hydrohaloalkane of the formula RfCFClCH3, wherein Rf is a perfluorinated alkyl group.
摘要翻译：本公开提供了一种氟化方法，其涉及在选自TaF 5和TiF 4的氟化催化剂的存在下，在反应区中使式RfC-Cl = CH 2的氢卤代烯烃与HF反应，以产生含有氢卤代烷烃的产物混合物式RfCFClCH 3，其中Rf是全氟化烷基。

105. 发明授权

US08907145B2 Aerosol propellants comprising unsaturated fluorocarbons 有权
标题翻译：包含不饱和碳氟化合物的气溶胶推进剂
公开(公告)号：US08907145B2
公开(公告)日：2014-12-09
申请号：US13594007
申请日：2012-08-24
申请人： Mario Joseph Nappa , Joseph Anthony Creazzo , Allen Capron Sievert , Ekaterina N. Swearingen
发明人： Mario Joseph Nappa , Joseph Anthony Creazzo , Allen Capron Sievert , Ekaterina N. Swearingen
IPC分类号： C07C17/00 , C07C19/08 , C07C21/18 , C07C23/00 , C07C25/13 , C09K3/30 , A61K9/12
CPC分类号： C09K3/30 , A61K9/124
摘要： Disclosed herein are propellants comprising fluorocarbons and/or hydrofluorocarbons. Also disclosed are sprayable compositions comprising the propellants.
摘要翻译：本文公开了包含碳氟化合物和/或氢氟烃的推进剂。还公开了包含推进剂的可喷雾组合物。

106. 再颁专利

USRE45076E1 Method of hydrodechlorination to produce dihydrofluorinated olefins 有权
标题翻译：加氢脱氯生产二氢氟化烯烃的方法
公开(公告)号：USRE45076E1
公开(公告)日：2014-08-12
申请号：US13606233
申请日：2012-09-07
申请人： Mario Joseph Nappa , Ekaterina N Swearingen
发明人： Mario Joseph Nappa , Ekaterina N Swearingen
IPC分类号： C07C17/10 , C07C21/18
CPC分类号： B01J23/72 , B01J21/18 , B01J23/58 , B01J23/628 , B01J23/755 , B01J23/78 , B01J23/868 , B01J27/12 , B01J35/023 , C07C17/23 , C07C21/18
摘要： Disclosed herein is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkene with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents with hydrogen. Also disclosed is a catalyst composition for the hydrodechlorination of chlorofluoroalkenes comprising copper metal deposited on a support.
摘要翻译：本文公开了一种制备含氟烯烃的方法，其包括在足以使氢取代氯取代基的温度下在催化剂存在下使氯氟烯与氢接触。还公开了用于加氢脱氯包含沉积在载体上的铜金属的氯氟代烯烃的催化剂组合物。

107. 发明申请

US20140114096A1 CATALYTICAL SYNTHESIS OF INTERNAL FLUOROBUTENES AND INTERNAL FLUOROPENTENES 有权
标题翻译：内部荧光素和内部荧光素的催化合成
公开(公告)号：US20140114096A1
公开(公告)日：2014-04-24
申请号：US13988111
申请日：2011-11-07
申请人： Mario Joseph Nappa , Ekaterina N Swearingen
发明人： Mario Joseph Nappa , Ekaterina N Swearingen
IPC分类号： C07C17/25
CPC分类号： C07C17/25 , C07C17/206 , C07C21/18
摘要： A vapor phase process is disclosed for making internal fluorobutenes. The process involves contacting a halobutane starting material selected from the group consisting of CF2HCHClCH2CCl2H, CF2HCHClCH2CCl3, CF3CHClCH2CCl2H, CF3CHClCH2CCl3, CF3CHClCHClCCl2H, CF3CHClCHClCCl3, CF3CCl2CH2CCl2H, CF3CCl2CH2CCl3, CF3CCl2CHClCCl2H, CF3CCl2CHClCCl3, CF3CClFCHClCCl2H, CF3CClFCHClCCl3, CF3CClFCH2CCl2H, CF3CClFCH2CCl3, CF3CClFCHFCCl2H, CF3CClFCHFCCl3, CF3CClHCHFCCl2H and CF3CClHCHFCCl3, with HF in a reaction zone in the presence of a chromium oxyfluoride catalyst to produce a product mixture comprising an internal fluorobutene. Another vapor phase process is disclosed for making internal fluoropentenes. The process involves contacting a halopentane starting material selected from the group consisting of CF2HCHXCH2CX2CX3, CF3CHXCH2CX2CX3, CF3CHXCHXCX2CX3, CF3CX2CH2CX2CX3, CF3CX2CHXCX2CX3 and CF3CHXCHFCX2CX3, with HF in a reaction zone in the presence of a chromium oxyfluoride catalyst to produce a product mixture comprising an internal fluoropentene, wherein each X is independently selected from the group consisting of F, Cl and Br, provided that not all X are fluorines.
摘要翻译：公开了一种用于制备内部氟代异丁烯的气相方法。该方法包括接触选自CF2HCHClCH2CCl2H，CF2HCHClCH2CCl3，CF3CHClCH2CCl2H，CF3CHClCH2CCl3，CF3CHClCHClCCl2H，CF3CHClCHClCCl3，CF3CCl2CH2CCl2H，CF3CCl2CH2CCl3，CF3CCl2CHClCCl2H，CF3CCl2CHClCCl3，CF3CClFCHClCCl2H，CF3CClFCHClCCl3，CF3CClFCH2CCl2H，CF3CClFCH2CCl3，CF3CClFCHFCCl2H，CF3CClFCHFCCl3，CF3CClHCHFCCl2H和CF3CClHCHFCCl3的组中选择的halobutane起始材料在HF反应区中，在氟氧化铬催化剂的存在下制备包含内部氟代丁烯的产物混合物。公开了制备内部氟代戊烯的另一种气相方法。该方法包括在氟氧化铬催化剂存在下，在反应区中将选自CF2HCHXCH2CX2CX3，CF3CHXCH2CX2CX3，CF3CHXCHXCX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CH2CX2CX3，CF3CX2CHXCX2CX3与CF3CHXCHFCX2CX3的卤代戊烷起始材料与HF接触，制备包含内部氟代戊烯的产物混合物，其中每个X独立地选自F，Cl和Br，条件是不是全部X是氟。

108. 发明授权

US08697922B2 Conversion of 2-chloro-1,1,1,2-tetrafluoropropane to 2,3,3,3-tetrafluoropropene 有权
标题翻译：将2-氯-1,1,1,2-四氟丙烷转化为2,3,3,3-四氟丙烯
公开(公告)号：US08697922B2
公开(公告)日：2014-04-15
申请号：US13478265
申请日：2012-05-23
申请人： Mario Joseph Nappa
发明人： Mario Joseph Nappa
IPC分类号： C07C17/25
CPC分类号： C07C17/25 , C07C21/18
摘要： Described is a method for producing fluoropropenes of formula CF3CX═CX2 wherein each X is F or H, at least one X is H, and at least one X is F, comprising pyrolyzing a hydrofluorochloropropane of formula CF3CXYCX2Y, wherein each X is F or H, at least one X is H, and at least one X is F, and one Y is Cl and the other Y is H, in the gas-phase in a reaction vessel, maintained at a temperature high enough to effect the pyrolysis of said hydrofluorochloropropane to said fluoropropene, wherein the selectivity for the production of the fluoropropene is at least 80%, in the absence of a catalyst.
摘要翻译：描述了制备式CF 3 C X = C X 2的氟丙烯的方法，其中每个X是F或H，至少一个X是H，并且至少一个X是F，包括热解式CF 3 C XYCX 2 Y的氢氟氯丙烷，其中每个X是F或H ，至少一个X是H，至少一个X是F，一个Y是Cl，另一个Y是H，在反应容器中的气相中，保持在足够高的温度下，使所说的氢氟丙烷与所述氟代丙烯反应，其中在不存在催化剂的情况下，制备氟丙烯的选择性为至少80％。

109. 发明授权

US08586804B2 Synthesis of 1,1,3-trichloro-1-propene 有权
标题翻译：合成1,1,3-三氯-1-丙烯
公开(公告)号：US08586804B2
公开(公告)日：2013-11-19
申请号：US13278511
申请日：2011-10-21
申请人： Mario Joseph Nappa , Robert D. Lousenberg , Andrew Jackson
发明人： Mario Joseph Nappa , Robert D. Lousenberg , Andrew Jackson
IPC分类号： C07C17/25
CPC分类号： C07C17/25 , C07C21/04
摘要： Disclosed is a process for the dehydrochlorination of 1,1,1,3-tetrachloropropane comprising contacting 1,1,1,3,tetrachloropropane in the vapor phase in a reaction zone with a catalyst comprising iron, to produce a product mixture comprising 1,1,3-trichloro-1-propene; and recovering said 1,1,3-trichloro-1-propene from the product mixture produced. Also disclosed is a process for the dehydrochlorination of 1,1,1,3-tetrachloropropane comprising heating 1,1,1,3-tetrachloropropane in the liquid phase to produce a mixture comprising 1,1,3-trichloro-1-propene, cooling said mixture, separating hydrogen chloride from said mixture and recovering 1,1,3-trichloro-1-propene.
摘要翻译：公开了1,1,1,3-四氯丙烷的脱氯化氢的方法，包括使反应区中的气相中的1,1,1,3，四氯丙烷与包含铁的催化剂接触，以产生包含1， 1,3-三氯-1-丙烯; 并从所生产的产物混合物回收所述1,1,3-三氯-1-丙烯。还公开了1,1,1,3-四氯丙烷的脱氯化氢的方法，包括在液相中加热1,1,1,3-四氯丙烷以产生包含1,1,3-三氯-1-丙烯，冷却所述混合物，从所述混合物中分离出氯化氢并回收1,1,3-三氯-1-丙烯。

110. 发明授权

US08535556B2 Compositions comprising iodotrifluoromethane and stabilizers 失效
标题翻译：包含三氟甲烷和稳定剂的组合物
公开(公告)号：US08535556B2
公开(公告)日：2013-09-17
申请号：US12161842
申请日：2007-03-26
申请人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
发明人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122
摘要： The present invention relates to compositions comprising iodotrifluoromethane and an effective amount of at least one stabilizer selected from the group consisting of hindered phenols, thiophosphates, butylated triphenylphosphorothionates, organo phosphates, phosphites, aryl alkyl ethers, terpenes, terpenoids, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, amines, nitromethane, alkylsilanes, benzophenone derivatives, aryl sulfides, divinyl terephalic acid, diphenyl terephalic acid, ionic liquids, and mixtures thereof. These stabilized iodotrifluoromethane compositions may be useful as working fluids in multiple applications including cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps.
摘要翻译：本发明涉及包含三氟甲烷和有效量的至少一种选自受阻酚，硫代磷酸酯，丁基化三苯基硫代磷酸酯，有机磷酸酯，亚磷酸酯，芳基烷基醚，萜烯，萜类化合物，环氧化物，氟化环氧化物，氧杂环丁烷，抗坏血酸，硫醇，内酯，硫醚，胺，硝基甲烷，烷基硅烷，二苯甲酮衍生物，芳基硫醚，二乙烯基对苯二酸，二苯基对苯二酸，离子液体及其混合物。这些稳定的三氟甲烷组合物可用作多种应用中的工作流体，包括冷却装置，例如制冷，空调，冷却器和热泵。

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