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101. 发明授权

US07408074B2 Method for producing an alkene oxide 失效
标题翻译：烯烃生产方法
公开(公告)号：US07408074B2
公开(公告)日：2008-08-05
申请号：US10553516
申请日：2004-04-16
申请人： Hans-Georg Goebbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf
发明人： Hans-Georg Goebbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： Process for preparing an alkene oxide, which comprises at least the steps (i), (ii) and (v): (i) providing a stream S1 comprising compressed, liquid alkene; (ii) depressurizing at least part of the stream S1 with absorption of heat and with at least partial vaporization of the liquid alkene; (v) reacting the alkene obtained in (ii) with a hydroperoxide in the presence of at least one solvent and at least one catalyst to give a mixture comprising alkene oxide and the solvent or solvents.
摘要翻译：制备氧化烯的方法，其至少包括步骤（i），（ii）和（v）：（i）提供包含压缩的液体烯烃的料流S1; （ii）吸收热量并至少部分汽化液态烯烃使至少部分流S1减压; （v）使（ii）中获得的烯烃与至少一种溶剂和至少一种催化剂存在下的氢过氧化物反应，得到包含烯烃氧化物和溶剂或溶剂的混合物。

102. 发明申请

US20070178029A1 Pipe assembly reactor comprising a helically shaped cross section 有权
标题翻译：管组装反应器，其包括螺旋形截面
公开(公告)号：US20070178029A1
公开(公告)日：2007-08-02
申请号：US10586135
申请日：2005-01-20
申请人： Hans-Georg Goebbel , Peter Bassler , Joaquim Teles , Peter Rudolf
发明人： Hans-Georg Goebbel , Peter Bassler , Joaquim Teles , Peter Rudolf
IPC分类号： B01J19/18
CPC分类号： B01J8/067 , B01J19/2425 , B01J19/243 , B01J19/2445 , B01J2208/00849 , B01J2219/1944 , F28D7/024 , F28F1/02 , F28F1/08
摘要： Process and apparatus for the continuous preparation of a chemical compound in at least one reactor, where at least one of the reactors is a shell-and-tube reactor which has a shell and at least one internal tube located within the shell, wherein at least one of the internal tubes has, at least in part, a noncircular cross section and a helical configuration in the region in which it is surrounded by the shell.
摘要翻译：用于在至少一个反应器中连续制备化学化合物的方法和装置，其中至少一个反应器是壳管式反应器，其具有壳和位于壳内的至少一个内管，其中至少内管中的一个至少部分地具有在其被壳包围的区域中的非圆形横截面和螺旋形构造。

103. 发明申请

US20060217576A1 Method for reacting an organic compound with a hydroperoxide 有权
公开(公告)号：US20060217576A1
公开(公告)日：2006-09-28
申请号：US10555985
申请日：2004-05-10
申请人： Ulrich Müller , Peter Bassler , Joaquim Teles , Norbert Rieber
发明人： Ulrich Müller , Peter Bassler , Joaquim Teles , Norbert Rieber
IPC分类号： C07C27/10 , B01J8/04 , B01J8/02 , B01J10/00
CPC分类号： C07D301/19 , B01J8/04 , B01J8/20 , B01J19/2495 , B01J29/40 , B01J29/70 , B01J29/89 , B01J35/0006 , B01J2208/00884 , B01J2208/025 , B01J2219/0004 , C07D301/12
摘要： Process for the catalyzed reaction of an organic compound with a hydroperoxide in at least one reactor using at least two different zeolite catalysts, wherein at least two of the different zeolite catalysts are used physically separately from one another.

104. 发明申请

US20060205964A1 Method for producing propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US20060205964A1
公开(公告)日：2006-09-14
申请号：US10553441
申请日：2004-04-16
申请人： Hans-Georg Gobbel , Peter Bassler , Joaquim Teles , Peter Rudolf
发明人： Hans-Georg Gobbel , Peter Bassler , Joaquim Teles , Peter Rudolf
IPC分类号： C07D301/03
CPC分类号： C07D301/12
摘要： Process for preparing propylene oxide, which comprises at least the steps (iii) and (iv) (iii) separating off propylene oxide from a mixture (M1) comprising propylene oxide and at least one solvent by distillation in a distillation column, giving a bottom stream and a vapor stream consisting essentially of propylene oxide; (iv) compressing the vapor stream obtained in (iii) by means of at least one compressor to give a compressed vapor.
摘要翻译：制备环氧丙烷的方法，其至少包括步骤（iii）和（iv）（iii）通过在蒸馏塔中蒸馏从包含环氧丙烷和至少一种溶剂的混合物（M1）中分离环氧丙烷，得到底部气流和基本上由环氧丙烷组成的蒸气流; （iv）通过至少一个压缩机压缩（iii）中获得的蒸气流，得到压缩蒸气。

105. 发明申请

US20060014969A1 Method for the continuous intermediate separation of an oxirane produced by the oxirane synthesis with no coupling product by means of a partition-wall column 审中-公开
标题翻译：通过环氧乙烷合成制备的环氧乙烷的连续中间分离方法，不用偶联产物通过分隔壁塔
公开(公告)号：US20060014969A1
公开(公告)日：2006-01-19
申请号：US10521790
申请日：2003-07-22
申请人： Peter Bassler , Hans-Georg Gobbel , Joaquim Teles , Peter Rudolf
发明人： Peter Bassler , Hans-Georg Gobbel , Joaquim Teles , Peter Rudolf
IPC分类号： C07D301/19
CPC分类号： C07D301/12 , Y02P20/582
摘要： Continuously operated process for the intermediate isolation of the oxirane formed by reaction of a hydroperoxide with an organic compound in the oxirane synthesis, wherein the product mixture formed in the synthesis is fractionated in a dividing wall column to give a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the oxirane is taken off in the intermediate-boiling fraction at the side offtake and the hydroperoxide is taken off in the high-boiling fraction at the bottom of the column.
摘要翻译：在环氧乙烷合成中通过氢过氧化物与有机化合物的反应形成的环氧乙烷的中间分离的连续操作方法，其中在合成中形成的产物混合物在分隔壁塔中分馏得到低沸点馏分，中间体沸腾馏分和高沸点馏分，环氧乙烷在中间馏分馏出物的一侧取出，氢过氧化物在柱底部的高沸点馏分中取出。

106. 发明授权

US06712942B2 Working up a mixture comprising alkene and oxygen 有权
标题翻译：处理包含烯烃和氧气的混合物
公开(公告)号：US06712942B2
公开(公告)日：2004-03-30
申请号：US10169102
申请日：2002-07-12
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Werner Hefner , Anne Wenzel , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Werner Hefner , Anne Wenzel , Peter Rudolf
IPC分类号： B01D3140
CPC分类号： C07D301/12 , Y02P20/582
摘要： A mixture (M1) comprising an alkene and oxygen is worked up by a process in which (i) oxygen is removed from the mixture (M1) by a nondistillative method to give a mixture (M2) and (ii) the alkene is separated off from the mixture (M2) by distillation.
摘要翻译：包括烯烃和氧气的混合物（M1）通过以下方法处理：其中（i）通过非填充方法从混合物（M1）中除去氧气，得到混合物（M2）和（ii）将烯烃分离从混合物（M2）通过蒸馏。

107. 发明授权

US06518441B2 Method for oxidizing an organic compound containing at least one C-C double bond 有权
标题翻译：氧化含有至少一个C-C双键的有机化合物的方法
公开(公告)号：US06518441B2
公开(公告)日：2003-02-11
申请号：US09424847
申请日：1999-12-06
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
IPC分类号： C07D30112
CPC分类号： C07D301/19 , B01J29/90 , B01J38/14 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
摘要翻译：氧化具有至少一个CC双键的有机化合物或其两种或多种的混合物的方法包括以下步骤：（I）制备氢过氧化物，（II）使具有至少一个CC双键的有机化合物或在沸石催化剂存在下，在步骤（I）中制备的氢过氧化物的两种或更多种的混合物与再生步骤（II）中使用的至少部分失活的沸石催化剂的（III）反应，和（Ⅳ）进行步骤（II）使用含有在步骤（III）中再生的催化剂的沸石催化剂。

108. 发明授权

US5527966A Preparation of triphenylphosphine 失效
标题翻译：三苯膦的制备
公开(公告)号：US5527966A
公开(公告)日：1996-06-18
申请号：US285204
申请日：1994-08-03
申请人： Dieter Hermeling , Peter Bassler , Peter Hammes , Randolf Hugo , Peter Lechtken , Hardo Siegel
发明人： Dieter Hermeling , Peter Bassler , Peter Hammes , Randolf Hugo , Peter Lechtken , Hardo Siegel
IPC分类号： F16B7/18 , B01J31/02 , C07F9/50 , E04B1/19 , E04B1/342 , E04B1/58 , F16B9/02 , C07F9/02
CPC分类号： B01J31/0247 , C07F9/509
摘要： Triphenylphosphine (TPP) is prepared by reacting triphenylphosphine dichloride (TPPCl.sub.2) with magnesium, aluminum and/or iron in the presence of an inert solvent, employing a TPPCl.sub.2 solution whose content of phosgene, chlorine, diphosgene, hydrogen chloride, thionyl chloride, sulfuryl chloride, phosphorus trichloride, phosphorus oxychloride and/or aliphatic halogen compounds (active chlorine compounds) totals less than 1000 ppm Cl.
摘要翻译：三苯基膦（TPP）是通过使三氯化磷（TPPCl 2）与镁，铝和/或铁在惰性溶剂存在下反应制备的，该TPPCl 2溶液含有光气，氯气，二极光，氯化氢，亚硫酰氯，磺酰氯，三氯化磷，三氯氧化磷和/或脂肪族卤素化合物（活性氯化合物）总计小于1000ppm Cl。

109. 发明授权

US5495015A Process for producing caprolactam through hydrolytic cleavage of molten polycaprolactam 失效
标题翻译：通过熔融聚己内酰胺的水解裂解生产己内酰胺的方法
公开(公告)号：US5495015A
公开(公告)日：1996-02-27
申请号：US355286
申请日：1994-12-12
申请人： Peter Bassler , Michael Kopietz
发明人： Peter Bassler , Michael Kopietz
IPC分类号： B03B9/06 , C07D201/12 , C08J11/14
CPC分类号： C07D201/12
摘要： Caprolactam is obtained from caprolactam-containing polymers in the presence of superheated water by bringing polymers which contain the repeating unit--[--N(H)--(CH.sub.2).sub.5 --C(O)--]--or mixtures consisting essentially of______________________________________from 40 to 99.9% by weight of a polymer containing the repeat- ing unit --[--N(H)--(CH.sub.2).sub.5 --C(O)--]--,from 0.01 to 50% by weight of additives selected from the group consisting of inorganic fillers, organic and inorganic pigments and dyes,from 0 to 10% by weight of organic and/or inorganic additives,from 0 to 40% by weight of non-polyamide-containing polymers andfrom 0 to 60% by weight of polyamides, with the exception of polycaprolactam and copolyamides prepared from caprolactam,______________________________________into contact with superheated water at from 280.degree. to 320.degree. C. and from 7.5 to 15 MPa and a weight ratio of water to polymer containing the repeating unit --[--N(H)--(CH.sub.2).sub.5 --C(O)--]-- of from 5:1 to 13:1 and in a reaction time of less than 3 hours, with the proviso that the reaction mixture, consisting essentially of water and the polymer used or the mixture used, contains no gaseous phase under the conditions of the hydrolysis.
摘要翻译：在过热水存在下，通过使含有重复单元 - [ - N（H） - （CH 2）5 -C（O） - ] - 的聚合物或由基本上由40组成的混合物至99.9重量％的含有重复单元的聚合物 - [-N（H） - （CH 2）5 -C（O） - ] - ， - 0.01-50重量％ - 由无机填料，有机和无机颜料和染料组成， - 0至10重量％的有机和/或无机添加剂， - 0至40重量％的非聚酰胺含聚合物和 - 0至60重量％的聚酰胺，除了由己内酰胺制备的聚己内酰胺和共聚酰胺与280℃至320℃和7.5至15MPa的过热水接触，并且水与含有重复单元的聚合物 - [ - N（H） - （CH2）5-C（O） - ] - 为5：1至13：1，反应时间小于3小时，条件是反应mi 主要由水组成，所使用的聚合物或所使用的混合物在水解条件下不含气相。

110. 发明授权

US4520125A Catalyst for the preparation of methyl methacrylate 失效
标题翻译：用于制备甲基丙烯酸甲酯的催化剂
公开(公告)号：US4520125A
公开(公告)日：1985-05-28
申请号：US582727
申请日：1984-02-23
申请人： Karl Baer , Peter Bassler , Gerd Duembgen , Gerd Fouquet , Richard Krabetz , Franz Merger , Friedbert Nees
发明人： Karl Baer , Peter Bassler , Gerd Duembgen , Gerd Fouquet , Richard Krabetz , Franz Merger , Friedbert Nees
IPC分类号： C07C69/54 , B01J23/00 , B01J23/06 , B01J23/62 , C07B61/00 , C07C67/39 , B01J31/04 , C07C67/00
CPC分类号： B01J23/628 , C07C67/39
摘要： Catalysts for the preparation of carboxylates from an aldehyde and an alkanol in the presence of oxygen, which contain palladium and lead as active components, these being present on a carrier containing zinc oxide, and the palladium being applied as a palladium salt in a solution containing hydrochloric acid and then being liberated by reduction, and whose carrier consists solely of zinc oxide, are particularly active and selective.
摘要翻译：在含有钯和铅作为活性组分的氧的存在下由醛和链烷醇制备羧酸盐的催化剂存在于含有氧化锌的载体上，钯作为钯盐以含有然后通过还原释放，并且其载体仅由氧化锌组成，具有特别的活性和选择性。

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