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101. 发明授权

US08188295B2 Method for producing difluoromethyl-substituted pyrazole compounds 有权
标题翻译：二氟甲基取代的吡唑化合物的制备方法
公开(公告)号：US08188295B2
公开(公告)日：2012-05-29
申请号：US12664448
申请日：2008-06-13
申请人： Markus Nett , Thomas Grote , Jan Klaas Lohmann , Jochen Dietz , Sebastian Peer Smidt , Michael Rack , Thomas Zierke
发明人： Markus Nett , Thomas Grote , Jan Klaas Lohmann , Jochen Dietz , Sebastian Peer Smidt , Michael Rack , Thomas Zierke
IPC分类号： C07D231/14 , C07C229/06
CPC分类号： C07D231/12 , C07D231/14
摘要： The present invention relates to a process for preparing 3-difluoromethyl-Substituted pyrazole compounds of the formula (I) in which R1 is H, halogen, nitro, C1-C8-alkyl, C1-C8-haloalkyl, C3-C8-cycloalkyl, phenyl, naphthyl, hetaryl, cyano, —C(═O)—OR1a, —C(═O)—NR1bR1c, —C(═O)—SR1d or —C(═S)—SR1e; R2 is H, C1-C4-alkyl, benzyl or phenyl; R3 is H, halogen, C1-C8-alkoxy, C1-C8-haloalkoxy, C3-C8-cycloalkoxy, C2-C8-alkenyloxy, C1-C8-alkylthio, C1-C8-haloalkylthio, C3-C8-cyclo-alkylthio or C2-C8-alkenylthio; compounds of the formula (II.a) or (II.b), in which R1 and R3 each have one of the definitions given above; R4 is halogen, —OR4a, —SR4a, —O—SO2—R4a or an —NR4bR4c group; R5 and R6 are each C1-C8-alkyl, C1-C8-haloalkyl, C3-C8-cycloalkyl, benzyl or phenyl, or, together with the nitrogen atom to which they are bonded, are a 3- to 8-membered heterocycle; Lewis acid adducts of compounds of the formula (II.b); the use of compounds of the formula (II.a) or (II.b) and of the Lewis acid adducts for preparing compounds of the formula (I) or (VI); and to a process for converting such compounds to the corresponding 3-difluoro-pyrazol-4-ylcarboxylic acids.
摘要翻译：本发明涉及一种制备式（I）的3-二氟甲基取代的吡唑化合物的方法，其中R 1是H，卤素，硝基，C 1 -C 8 - 烷基，C 1 -C 8 - 卤代烷基，C 3 -C 8 - 环烷基，苯基，萘基，杂芳基，氰基，-C（= O）-OR1a，-C（= O）-NR1bR1c，-C（= O）-SR1d或-C（= S）-SR1e; R2是H，C1-C4-烷基，苄基或苯基; R 3是H，卤素，C 1 -C 8 - 烷氧基，C 1 -C 8 - 卤代烷氧基，C 3 -C 8 - 环烷氧基，C 2 -C 8 - 烯氧基，C 1 -C 8 - 烷硫基，C 1 -C 8 - 卤代烷硫基，C 3 -C 8环 - C 2 -C 8 - 烯硫基; 式（II.a）或（II.b）化合物，其中R 1和R 3各自具有上述定义之一; R4是卤素，-OR4a，-SR4a，-O-SO2-R4a或-NR4bR4c基团; R 5和R 6各自为C 1 -C 8 - 烷基，C 1 -C 8 - 卤代烷基，C 3 -C 8 - 环烷基，苄基或苯基，或与它们所键合的氮原子一起为3-至8-元杂环; 式（II.b）化合物的路易斯酸加合物; 使用式（II.a）或（II.b）化合物和路易斯酸加成物制备式（I）或（VI）化合物的方法; 以及将这些化合物转化为相应的3-二氟 - 吡唑-4-基羧酸的方法。

102. 发明申请

US20100273650A1 Fungicidal Mixtures Comprising a Substituted 3-Hydroxymethylpyridine and a Further Fungicidal Compound 审中-公开
标题翻译：包含取代的3-羟甲基吡啶和另外的杀真菌化合物的杀真菌混合物
公开(公告)号：US20100273650A1
公开(公告)日：2010-10-28
申请号：US12742717
申请日：2008-11-14
申请人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
发明人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
IPC分类号： A01C1/06 , A61K31/4427 , A61K31/535
CPC分类号： A01N43/40 , A01N2300/00
摘要： The present invention relates to mixtures of fungicidally active compounds comprising at least one substituted 3-hydroxymethylpyridin compound formula I and at least one further fungicidally active compound II. wherein: X is O, S or NR4; R1 is C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro; R2 is H or C1-C4-alkyl; R3 is C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro; R4 is H, C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro;
摘要翻译：本发明涉及杀真菌活性化合物的混合物，其包含至少一种取代的3-羟甲基吡啶化合物式I和至少一种其它杀真菌活性化合物II。其中：X是O，S或NR4; R 1是C 1 -C 6烷基，C 1 -C 6烷氧基-C 1 -C 6烷基，C 1 -C 6卤代烷基，芳基-C 1 -C 4烷基，芳氧基-C 1 -C 4烷基，芳硫基-C 1 -C 4烷基，芳基或杂芳基，其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素，C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，氰基和硝基; R2是H或C1-C4-烷基; R 3是C 1 -C 6烷基，C 1 -C 6烷氧基-C 1 -C 6烷基，C 1 -C 6卤代烷基，芳基-C 1 -C 4烷基，芳氧基-C 1 -C 4烷基，芳硫基-C 1 -C 4烷基，芳基或杂芳基，其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素，C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，氰基和硝基; R 4是H，C 1 -C 6烷基，C 1 -C 6烷氧基-C 1 -C 6烷基，C 1 -C 6卤代烷基，芳基-C 1 -C 4烷基，芳氧基-C 1 -C 4烷基，芳硫基-C 1 -C 4 - 烷基，芳基或杂芳基，其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素，C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基，C 1 -C 4 - C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，氰基和硝基;

103. 发明申请

US20100179059A1 Fungicidal Mixtures 审中-公开
标题翻译：杀菌混合物
公开(公告)号：US20100179059A1
公开(公告)日：2010-07-15
申请号：US12602790
申请日：2008-06-05
申请人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
发明人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
IPC分类号： A01N43/40 , A01N43/54 , A01C1/06 , A01P3/00
CPC分类号： A01N43/80 , A01N43/54 , A01N43/653 , A01N43/78 , A01N47/12 , A01N47/14 , A01N47/18 , A01N47/20 , A01N47/24 , A01N61/00 , A01N2300/00
摘要： The present invention relates to mixtures comprising, as active components, 1) a fungicidal compound of formula (I) wherein: R1 is alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryl; or heteroaryl; R2 is alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryl; heteroaryl; 5-pyrimidinyl; or 2- or 5-thiazolyl; R3 is H; alkyl; alkoxyalkyl; haloalkyl; arylalkyl; aryloxyalkyl; arylthioalkyl; aryl; heteroaryl; or alkylsilyl; R4 is H; acyl; haloacyl, alkoxycarbonyl; aryloxycarbonyl; alkylaminocarbonyl; or dialkylaminocarbonyl; or a salt thereof; and 2) a fungicidal compound II selected from azoles, strobilurins, carboxamides, heterocylic compounds, carbamates, and other active compounds in synergistically effective amounts.
摘要翻译：本发明涉及包含作为活性成分的1）式（I）的杀真菌化合物的混合物，其中：R 1是烷基; 烷氧基烷基卤代烷基芳烷基芳基; 或杂芳基; R2是烷基; 烷氧基烷基卤代烷基芳烷基芳基; 杂芳基; 5-嘧啶基; 或2-或5-噻唑基; R3为H; 烷基; 烷氧基烷基卤代烷基芳烷基芳氧基烷基; 芳硫基烷基芳基; 杂芳基; 或烷基甲硅烷基; R4是H; 酰基; 卤代酰基，烷氧基羰基; 芳氧基羰基; 烷基氨基羰基; 或二烷基氨基羰基; 或其盐; 和2）协同有效量的选自吡唑，嗜球半胱氨酸，羧酰胺，杂环化合物，氨基甲酸酯和其它活性化合物的杀真菌化合物II。

104. 发明申请

US20100273649A1 Fungicidal Mixtures III 审中-公开
标题翻译：杀菌混合物III
公开(公告)号：US20100273649A1
公开(公告)日：2010-10-28
申请号：US12742487
申请日：2008-11-14
申请人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
发明人： Jens Renner , Sarah Ulmschneider , Jochen Dietz , Egon Haden
IPC分类号： A01N25/26 , A01N43/40 , A01N43/54 , A01P3/00
CPC分类号： A01N43/40 , A01N37/34 , A01N37/50 , A01N43/50 , A01N43/54 , A01N43/653 , A01N47/04 , A01N47/12 , A01N47/14 , A01N47/24 , A01N61/00 , A01N2300/00
摘要： The present invention relates to mixtures of fungicidally active compounds comprising at least one substituted 2-[hydroxyl(pyridine-3-yl)methyl]acrylate compound of the formula I wherein: R1 is H, C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl or heteroaryl, wherein the cyclic moieties of the last two radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, cyano and nitro; A is a covalent bond or C1-C4-alkylen, which is unsubstituted or which may carry a substitutent selected from C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and cyano; Ar is aryl or heteroaryl, wherein the cyclic moieties of the aromatic radicals are unsubstituted or substituted with 1, 2 or 3 radicals Ra, where the radicals Ra are identical or different and selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano, nitro, aryl, hetaryl, aryloxy, hetaryloxy, aryloxy-C1-C4-alkyl and hetaryloxy-C1-C4-alkyl, wherein the cyclic moieties of the six last mentioned radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, cyano and nitro; or a salt thereof; and at least one further fungicidally active compound II.
摘要翻译：本发明涉及包含至少一种式I的取代的2- [羟基（吡啶-3-基）甲基]丙烯酸酯化合物的杀真菌活性化合物的混合物，其中：R1是H，C1-C6-烷基，C1-C6- 烷氧基-C 1 -C 6 - 烷基，C 1 -C 6卤代烷基，芳基或杂芳基，其中最后两个基团的环状部分是未取代的或被1,2或3个选自卤素，C 1 -C 4 - 烷基， C 4 - 炔基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，氰基和硝基; A是共价键或C1-C4-亚烷基，其是未取代的或可以携带选自C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基和氰基的取代基; Ar是芳基或杂芳基，其中芳族基团的环状部分是未取代的或被1,2或3个基团R a取代，其中基团R a相同或不同并且选自卤素，C 1 -C 4烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，氰基，硝基，芳基，杂芳基，芳氧基，芳氧基-C 1 -C 4烷基和芳基氧基-C 1 -C 4烷基，其中六个最后提到的基团的环状部分是未取代的或被1,2或3个选自卤素，C 1 -C 4 - 烷基，C 1 -C 4 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷氧基，氰基和硝基; 或其盐; 和至少一种其它杀真菌活性化合物II。

105. 发明申请

US20080249113A1 Fungicidal Mixtures 审中-公开
标题翻译：杀菌混合物
公开(公告)号：US20080249113A1
公开(公告)日：2008-10-09
申请号：US11659192
申请日：2005-07-28
申请人： Carsten Blettner , Jochen Dietz , Wassilios Grammenos , Thomas Grote , Udo Hunger , Bernd Muller , Matthias Niedenbruck , Joachim Rheinheimer , Peter Schafer , Frank Schieweck , Anja Schwogler , Barbara Nave , Maria Scherer , Siegfried Strathmann , Ulrich Schofl , Reinhard Stierl
发明人： Carsten Blettner , Jochen Dietz , Wassilios Grammenos , Thomas Grote , Udo Hunger , Bernd Muller , Matthias Niedenbruck , Joachim Rheinheimer , Peter Schafer , Frank Schieweck , Anja Schwogler , Barbara Nave , Maria Scherer , Siegfried Strathmann , Ulrich Schofl , Reinhard Stierl
IPC分类号： A01N43/90 , C07D487/04 , A01N25/26 , A01P3/00
CPC分类号： A01N43/90 , A01N43/653 , A01N47/14 , A01N43/50 , A01N57/12 , A01N47/04 , A01N37/34 , A01N43/40 , A01N37/50 , A01N37/46 , A01N43/84 , A01N37/38 , A01N43/28 , A01N47/38 , A01N43/54 , A01N43/32 , A01N59/20 , A01N2300/00
摘要： Fungicidal mixtures, comprising as active components 1) a 5-chloro-6-phenyl-7-heterocyclylaminotriazolopyrimidine of the formula I, in which D together with the nitrogen atom forms a pyrrolidine, piperidine or azepine ring, which rings are unsubstituted or substituted by one or two methyl groups or by an ethyl, propyl or butyl group; and L is methyl, fluorine or chlorine; and 2) at least one active compound II selected from the following groups: A) azoles; B) strobilurins; C) acylalanines; D) amine derivatives; E) anilinopyrimidines; F) dicarboximides; G) cinnamides and analogs; H) antibiotics; K) dithiocarbamates; L) heterocyclic compounds according to the description; M) sulfur and copper fungicides; N) nitrophenyl derivatives; O) phenylpyrroles; P) sulfenic acid derivatives; Q) other fungicides according to the description; or R) growth retardants; in a synergistically effective amount, novel triazolopyrimidines, methods for controlling harmful fungi using compounds or mixtures of a compound I with an active compound of groups A) to R) and the use of the compounds I with the active compounds of groups A) to R) for preparing such mixtures, and also compositions comprising these compounds or mixtures.
摘要翻译：包含作为活性组分的杀真菌混合物1）式I的5-氯-6-苯基-7-杂环基氨基三唑并嘧啶，其中D与氮原子一起形成吡咯烷，哌啶或氮杂环，该环是未取代的或被一个或两个甲基或乙基，丙基或丁基; L为甲基，氟或氯; 和2）至少一种选自以下组的活性化合物II：A）唑类; B）嗜球果伞素 C）酰基丙氨酸; D）胺衍生物; E）苯胺嘧啶嘧啶; F）二羧酰亚胺; G）肉桂酸酯类似物; H）抗生素; K）二硫代氨基甲酸盐; L）杂环化合物; M）硫和铜杀菌剂; N）硝基苯基衍生物; O）苯基吡咯; P）亚磺酸衍生物; Q）其他杀菌剂根据说明; 或R）生长阻滞剂; 协同有效量的新型三唑并嘧啶，使用化合物或化合物I与A）至R）的活性化合物的混合物来控制有害真菌的方法以及将化合物I与基团A）至R的活性化合物），以及包含这些化合物或混合物的组合物。

106. 发明申请

US20080132522A1 2-Substituted Pyrimidines, Method for Their Production and Their Use for Controlling Pathogenic Fungi 审中-公开
标题翻译： 2-取代嘧啶，其生产方法及其用于控制病原真菌
公开(公告)号：US20080132522A1
公开(公告)日：2008-06-05
申请号：US11631006
申请日：2005-07-12
申请人： Joachim Rheinheimer , Frank Schieweck , Thomas Grote , Carsten Blettner , Anja Schwogler , Markus Gewehr , Wassilios Grammenos , Udo Hunger , Bernd Muller , Peter Schafer , Jochen Dietz , John-Bryan Speakman , Maria Scherer , Siegfried Strathmann , Ulrich Schofl , Reinhard Stierl
发明人： Joachim Rheinheimer , Frank Schieweck , Thomas Grote , Carsten Blettner , Anja Schwogler , Markus Gewehr , Wassilios Grammenos , Udo Hunger , Bernd Muller , Peter Schafer , Jochen Dietz , John-Bryan Speakman , Maria Scherer , Siegfried Strathmann , Ulrich Schofl , Reinhard Stierl
IPC分类号： A01N43/54 , C07D401/04 , A01P3/00 , A01P13/00 , A01P15/00
CPC分类号： C07D239/34 , C07D401/04 , C07D403/12
摘要： The invention relates to 2-substituted pyrimidines of the formula I in which the index n and the substituents R1 to R4, B and L are as defined in the description and Y is a group —O— or —S—, and to processes for their preparation, pesticidal compositions and methods for controlling harmful fungi and animal pests using the compounds according to the invention.
摘要翻译：本发明涉及式I的2-取代嘧啶，其中指数n和取代基R 1至R 4，B和L如说明书中所定义，以及 Y是基团-O-或-S-，并且使用本发明的化合物进行制备，杀虫组合物和控制有害真菌和动物害虫的方法。

107. 发明申请

US20070270311A1 6-Phenyl-7-Aminotriazolopyrimidines, Processes For Their Preparation And Their Use For Controlling Harmful Fungi, And Also Compositions Comprising Them 审中-公开
公开(公告)号：US20070270311A1
公开(公告)日：2007-11-22
申请号：US11661566
申请日：2005-09-02
申请人： Carsten Blettner , Jordi Blasco , Bernd Muller , Markus Gewehr , Wassilios Grammenos , Thomas Grote , Udo Hunger , Joachim Rheinheimer , Peter Schafer , Frank Schieweck , Anja Schwogler , Jochen Dietz , John-Bryan Speakman , Thorsten Jabs , Siegfried Strathmann , Ulrich Schofl , Maria Scherer , Reinhard Stierl
发明人： Carsten Blettner , Jordi Blasco , Bernd Muller , Markus Gewehr , Wassilios Grammenos , Thomas Grote , Udo Hunger , Joachim Rheinheimer , Peter Schafer , Frank Schieweck , Anja Schwogler , Jochen Dietz , John-Bryan Speakman , Thorsten Jabs , Siegfried Strathmann , Ulrich Schofl , Maria Scherer , Reinhard Stierl
IPC分类号： A01N43/90 , A01P3/00 , C07D487/02
CPC分类号： A01N43/90 , A01N47/06 , A01N47/12 , A01N47/16 , C07D487/04
摘要： 6-Phenyl-7-aminotriazolopyrimidines of the formula I in which the substituents are as defined below: R1 is hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle, which comprises one to four heteroatoms from the group consisting of O, N and S, R2 is alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle which comprises one to four heteroatoms from the group consisting of O, N and S, R3,R4,R5,R6,R7 are hydrogen or one of the groups mentioned under R2, R4, together with R3 or R6, may also form a five- or six-membered saturated or unsaturated ring which, in addition to carbon atoms, may comprise one to three further heteroatoms from the group consisting of O, N and S as ring members; R2 with R3, R4 with R5, R6 with R7 may in each case together, with formation of spiro groups, also form a C2-C5-alkylene, or alkenylene or alkynylene chain which may be interrupted by one to three heteroatoms from the group consisting of O, N and S; p is zero or 1; L is halogen, alkyl, haloalkyl, alkoxy, cyano, nitro, amino, alkylamino, dialkylamino, alkylcarbonylamino, C(O)—R, S(O)n—R; where n is zero, 1 or 2; R is hydrogen, alkyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, amino, alkylamino, dialkylamino; m is 1, 2, 3, 4 or 5; X is halogen, cyano, alkyl, alkoxy, alkenyloxy, alkynyloxy or haloalkoxy; Y is oxygen or sulfur; Z is hydrogen, alkyl, haloalkyl, cycloalkyl, alkylcarbonyl, cycloalkylcarbonyl, alkenyl, haloalkenyl, cycloalkenyl, alkynyl, haloalkynyl, phenyl, naphthyl, a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle which comprises one to four heteroatoms from the group consisting of O, N and S; or Z together with R4 or R6 may also form a five- or six-membered saturated or unsaturated ring which, in addition to carbon atoms and Y, may comprise one or two further heteroatoms from the group consisting of O, N and S as ring members the groups R1 to R7, Z and R may be substituted according to the description; processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.

108. 发明申请

US20120289706A1 Method for Producing Triazolinthione Derivatives and Intermediates Thereof 审中-公开
标题翻译：生产三唑啉衍生物及其中间体的方法
公开(公告)号：US20120289706A1
公开(公告)日：2012-11-15
申请号：US13515064
申请日：2010-12-13
申请人： Jens Renner , Jochen Dietz , Thomas Grote , Joachim Gebhardt , Markus Nett , Michael Keil
发明人： Jens Renner , Jochen Dietz , Thomas Grote , Joachim Gebhardt , Markus Nett , Michael Keil
IPC分类号： C07D405/06 , C07D303/36
CPC分类号： C07D249/12
摘要： The present invention relates to a new process for the preparation of substituted thiotriazolo groups of the general formula (I) wherein the variables have the meanings as given in the claims and the description.
摘要翻译：本发明涉及制备通式（I）的取代的三优唑基的新方法，其中变量具有权利要求书和说明书中给出的含义。

109. 发明申请

US20140045687A1 Use of substituted dithiine-dicarboximides for combating phytopathogenic fungi 有权
标题翻译：取代二硫代二碳酰亚胺与植物病原真菌的对抗
公开(公告)号：US20140045687A1
公开(公告)日：2014-02-13
申请号：US14111271
申请日：2012-04-10
申请人： Wassilios Grammenos , Nadege Boudet , Richard Riggs , Jochen Dietz , Egon Haden , Marcus Fehr
发明人： Wassilios Grammenos , Nadege Boudet , Richard Riggs , Jochen Dietz , Egon Haden , Marcus Fehr
IPC分类号： A01N43/90
CPC分类号： A01N43/90 , C07D403/04 , C07D405/04 , C07D409/04 , C07D411/04 , C07D413/04 , C07D417/04 , C07D487/04 , C07D491/056 , C07D495/04 , C07D513/04 , C09B57/00
摘要： The present invention relates to the use of dithiine-dicarboximide compounds of formula I as defined in the description, and the N-oxides, and salts thereof for combating harmful fungi and seed coated with at least one such compound. The invention also relates to novel dithiine-dicarboximides, processes and intermediates for preparing these compounds and also to compositions comprising at least one such compound.
摘要翻译：本发明涉及在描述中定义的式I的二硫代二羧酰亚胺化合物及其N-氧化物及其盐用于防治有害真菌和用至少一种这样的化合物包被的种子。本发明还涉及用于制备这些化合物的新型二硫代二羧酰亚胺，方法和中间体，还涉及包含至少一种这样的化合物的组合物。

110. 发明授权

US09137997B2 Use of substituted dithiine-dicarboximides for combating phytopathogenic fungi 有权
标题翻译：取代二硫代二碳酰亚胺与植物病原真菌的对抗
公开(公告)号：US09137997B2
公开(公告)日：2015-09-22
申请号：US14111271
申请日：2012-04-10
申请人： Wassilios Grammenos , Nadege Boudet , Richard Riggs , Jochen Dietz , Egon Haden , Marcus Fehr
发明人： Wassilios Grammenos , Nadege Boudet , Richard Riggs , Jochen Dietz , Egon Haden , Marcus Fehr
IPC分类号： A01N43/90 , C07D403/04 , C07D405/04 , C07D409/04 , C07D411/04 , C07D413/04 , C07D417/04 , C07D487/04 , C07D491/056 , C07D495/04 , C07D513/04 , C09B57/00
CPC分类号： A01N43/90 , C07D403/04 , C07D405/04 , C07D409/04 , C07D411/04 , C07D413/04 , C07D417/04 , C07D487/04 , C07D491/056 , C07D495/04 , C07D513/04 , C09B57/00
摘要： The present invention relates to the use of dithiine-dicarboximide compounds of formula I as defined in the description, and the N-oxides, and salts thereof for combating harmful fungi and seed coated with at least one such compound. The invention also relates to novel dithiine-dicarboximides, processes and intermediates for preparing these compounds and also to compositions comprising at least one such compound.
摘要翻译：本发明涉及在描述中定义的式I的二硫代二羧酰亚胺化合物及其N-氧化物及其盐用于防治有害真菌和用至少一种这样的化合物包被的种子。本发明还涉及用于制备这些化合物的新型二硫代二羧酰亚胺，方法和中间体，还涉及包含至少一种这样的化合物的组合物。

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