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101. 发明授权

US4909832A Herbicidal 5-dichloroacetamido-4-nitro-1-aryl-pyrazoles 失效
标题翻译：除草的5-二氯乙酰氨基-4-硝基-1-芳基 - 吡唑
公开(公告)号：US4909832A
公开(公告)日：1990-03-20
申请号：US183862
申请日：1988-04-02
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Albercht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Albercht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/16 , C07D231/38 , C07D231/40
CPC分类号： C07C243/00 , A01N43/56 , C07D231/38 , C07D231/40
摘要： 5-Dichloracetamido-4-nitro-1-aryl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, fluorine, chlorine or bromine,R.sup.2 represents hydrogen, fluorine or chlorine,R.sup.3 represents halogen, halogenoalkyl, halogenoalkoxy, halogenoalkythio or halogenoalkylsulphonyl,R.sup.4 represents hydrogen, fluorine, or chlorine, andR.sup.5 represents fluorine, chlorine or bromine, but in the case in which R.sup.1 and R.sup.5 simultaneously represent chlorine and in addition R.sup.2 and R.sup.4 simultaneously represent hydrogen, R.sup.3 does not represent chlorine or trifluoromethyl,exhibit herbicidal and plant growth-regulating properties. Novel intermediates therefor are also shown.

102. 发明授权

US4877439A Herbicidal 1-arylpyrazoles, compositions and use 失效
标题翻译：除草1-芳基吡唑，组合物和用途
公开(公告)号：US4877439A
公开(公告)日：1989-10-31
申请号：US210607
申请日：1988-06-23
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
IPC分类号： A01N57/24 , C07F9/6503
CPC分类号： A01N57/24 , C07F9/65037
摘要： Herbicidal 1-arylpyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or nitro,R.sup.2 represents hydrogen or alkyl,R.sup.3 and R.sup.4 independently of one another each represent alkyl, halogenoalkyl or optionally substituted aryl,Ar represents optionally substituted phenyl or optionally substituted pyridyl,x represents a number 0 or 1 andy represents a number 0 or 1.
摘要翻译：式（I）的除草1-芳基吡唑其中R1代表氢或硝基，R2代表氢或烷基，R3和R4彼此独立地表示烷基，卤代烷基或任选取代的芳基，Ar代表任意取代的苯基或任选取代的吡啶基，x表示数字0或1，y表示数字0或1。

103. 发明授权

US4863937A 1-Arylpyrazoles, pesticidal compositions and use 失效
标题翻译： 1-芳基吡唑，农药组合物和用途
公开(公告)号：US4863937A
公开(公告)日：1989-09-05
申请号：US223188
申请日：1988-07-22
申请人： Reinhold Gehring , Uta Korte-Jensen , Otto Schallner , Jorg Stetter , Benedikt Becker , Wolfgang Behrenz , Bernhard Homeyer , Wilhelm Stendel
发明人： Reinhold Gehring , Uta Korte-Jensen , Otto Schallner , Jorg Stetter , Benedikt Becker , Wolfgang Behrenz , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N43/56 , A01N47/02 , C07D231/44 , C07D401/04 , G03G15/04 , G03G15/043
CPC分类号： C07D231/44 , A01N43/56 , A01N47/02
摘要： Pest-combating agents, especially as insecticides, which are 1-arylpyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl or halogenoalkyl,R.sup.2 represents alkyl, halogenoalkyl, optionally substituted aralkyl or optionally substituted aryl,R.sup.3 represents hydrogen, alkyl or halogenoalkyl,R.sup.4 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, halogenoalkinyl or in each case optionally substituted aryl or heteroaryl,X represents oxygen, sulphur or an N-alkyl radical,Ar represents in each case optionally substituted phenyl or pyridyl,m represents a number 0 or 1 andn represents a number 0, 1 or 2,have been found.
摘要翻译：杀虫剂，特别是作为杀虫剂，其为式“IMAGE”的1-芳基吡唑，其中R 1表示氢，烷基或卤代烷基，R 2表示烷基，卤代烷基，任选取代的芳烷基或任选取代的芳基，R 3表示氢，烷基或卤代烷基，R 4表示烷基，烯基，炔基，卤代烷基，卤代烯基，卤代烷基，或在各种情况下均为任选取代的芳基或杂芳基，X表示氧，硫或N-烷基，Ar表示在任何情况下均为任选取代的苯基或吡啶基，m表示数字0或1，n表示数字0,1或2。

104. 发明授权

US4804398A 1-aryl-4-cyano-5-halogenopyrazoles, composition containing them, and method of using them as selective herbicides 失效
标题翻译： 1-芳基-4-氰基-5-卤代吡唑，含有它们的组合物，以及使用它们作为选择性除草剂的方法
公开(公告)号：US4804398A
公开(公告)日：1989-02-14
申请号：US57471
申请日：1987-06-03
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/16 , C07D231/22 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/16
摘要： Herbicidally active novel 1-phenyl-4-cyano-5-halogenopyrazoles of the formula ##STR1## in which R is hydrogen or alkyl,Hal is halogen, andAr is phenyl substituted at least once by a radical other than halogen.Intermediates of the formulas ##STR2## are also new.
摘要翻译：式“IMAGE”的除草活性新型1-苯基-4-氰基-5-卤代吡唑，其中R为氢或烷基，Hal为卤素，Ar为至少一个被卤素以外的基团取代的苯基。公式 + TR 的中间体也是新的。

105. 发明授权

US4799951A 5-acylamino-pyrazole derivatives, composition containing them and herbicidal method of using them 失效
标题翻译： 5-酰基氨基 - 吡唑衍生物，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4799951A
公开(公告)日：1989-01-24
申请号：US113298
申请日：1987-10-26
申请人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Harry Strang
发明人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Harry Strang
IPC分类号： C07D231/38 , A01N43/56 , C07D231/40 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/40
摘要： Herbicidal 5-acylamino-pyrazole derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl or optionally substituted cycloalkyl,R.sup.3 represents hydrogen or alkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl,Ar represents in each case optionally substituted phenyl or pyridyl,X.sup.1 represents oxygen or sulphur,A represents a straight-chain or branched optionally substituted alkylene bridge,n represents the number 0 to 1 andX.sup.2 represents oxygen, or represents a radical .dbd.N--O--R.sup.4, or represents a radical ##STR2## wherein R.sup.4 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted aralkyl, or represents optionally substituted aryl,R.sup.5 represents hydrogen or alkyl andR.sup.6 represents hydrogen or alkyl, or represents optionally substituted aryl, or represents a radical ##STR3## wherein X.sup.3 represents oxygen or sulphur andR.sup.7 represents hydrogen, alkyl, alkoxy, alkylamino or dialkylamino.
摘要翻译：其中R1代表氢，卤素或硝基，R2代表氢，烷基，烯基，炔基或任选取代的环烷基，R3代表氢或烷基，或代表任意取代的环烷基，或者代表任选取代的环烷基，或其代表任意取代的环烷基的除草的5-酰基氨基吡唑衍生物，表示任选取代的芳基，Ar表示在任何情况下为任选取代的苯基或吡啶基，X1表示氧或硫，A表示直链或支链任选取代的亚烷基桥，n表示0至1，X 2表示氧，或表示或者代表任意取代的芳烷基，或表示任意取代的芳基，R 5表示氢或烷基，或者表示任选被取代的芳烷基，或者表示任选被取代的芳烷基， R 6表示氢或烷基，或表示任选取代的芳基，或表示基团表示氧或硫，R7表示氢，烷基，烷氧基，烷基氨基或二烷基氨基。

106. 发明授权

US4787930A 5-amino-1-phenyl-pyrazole herbicides and plant growth regulators 失效
标题翻译： 5-氨基-1-苯基 - 吡唑除草剂和植物生长调节剂
公开(公告)号：US4787930A
公开(公告)日：1988-11-29
申请号：US4353
申请日：1987-01-16
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , A01N47/18 , C07D231/38 , C07D231/40 , C07D231/42
CPC分类号： C07D231/38 , A01N43/56 , A01N47/18 , C07D231/40
摘要： Herbicidal and plant growth regulating 5-amino-1-phenyl-pyrazoles of the formula ##STR1## in which R.sup.1 to R.sup.4 each represents hydrogen or various organic radicals,X represents oxygen or sulphur,n represents the number 0, 1 or 2, andm represents the number 1, 2 or 3,but wherein, in the case where R.sup.1 and R.sup.3 represent hydrogen and R.sup.2 represents nitro, R.sup.4 does not simultaneously represent a propionyl radical.
摘要翻译：调节式“IMAGE”的5-氨基-1-苯基 - 吡唑的除草和植物生长，其中R 1至R 4各自表示氢或各种有机基团，X表示氧或硫，n表示0,1或2的数，和 m表示数字1,2或3，但其中，在R1和R3表示氢且R2表示硝基的情况下，R4不同时表示丙酰基。

107. 发明授权

US4771066A 4-haloalkylthio-5-amino-1-arylpyrazoles, composition containing them, and insecticidal and acaricidal method of using them 失效
标题翻译： 4-卤代烷硫基-5-氨基-1-芳基吡唑，含有它们的组合物，以及使用它们的杀虫和杀螨方法
公开(公告)号：US4771066A
公开(公告)日：1988-09-13
申请号：US13741
申请日：1987-02-12
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Heinz-Jurgen Wroblowsky , Benedikt Becker , Wolfgang Behrenz , Bernhard Homeyer , Wilhelm Stendel
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Heinz-Jurgen Wroblowsky , Benedikt Becker , Wolfgang Behrenz , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N43/56 , A01N47/02 , A61K31/415 , A61K31/44 , A61K31/4427 , A61P33/00 , C07D231/44 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , A01N47/02 , C07D231/44
摘要： Insecticidally and acarididally active 1-arylpyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl or halogen alkyl,R.sup.2 represents alkyl, alkenyl, alkinyl, cycloalkyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl, alkylsulphinylalkyl, alkylsulphonylalkyl, optionally substituted aralkyl or optionally substituted aryl,R.sup.3 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or optionally substituted aralkyl,R.sup.4 represents alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl or optionally substituted aralkyl, and, in addition, also represents hydrogen in the case where R.sup.3 does not simultaneously represent unsubstituted alkyl, orR.sup.3 and R.sup.4, together with the nitrogen atom to which they are bound, represent a saturated heterocycle, which can optionally contain further heteroatoms,Ar represents in each case optionally substituted phenyl or pyridyl, andn represents a number 0, 1 or 2.
摘要翻译：具有式“IMAGE”的杀虫和杀螨活性1-芳基吡唑其中R1代表氢，烷基或卤素烷基，R2代表烷基，烯基，炔基，环烷基，卤代烷基，卤代烯基，烷氧基烷基，烷硫基烷基，烷基亚磺酰基烷基，烷基磺酰基烷基，任选取代的芳烷基或任选取代的芳基，R 3表示烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基烷基，烷硫基烷基，环烷基或任选取代的芳烷基，R 4表示烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基烷基，烷硫基烷基，环烷基或任选取代的芳烷基，此外，在R3不同时表示未取代的烷基的情况下也表示氢，或者R 3和R 4与它们所连接的氮原子一起代表饱和的杂环，其可以任选地含有另外的杂原子，Ar表示每个任选取代的苯基或吡啶基，n表示数字0，1或2。

108. 发明授权

US4770688A 5-azido- or 5-phosphoroimido-1-arylpyrazoles, composition containing them, and herbicidal and plant growth regulating methods of using them 失效
标题翻译： 5-叠氮基或5-亚氨基亚氨基-1-芳基吡唑，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4770688A
公开(公告)日：1988-09-13
申请号：US942141
申请日：1986-12-16
申请人： Reinhold Gehring , Markus Lindig , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Markus Lindig , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , A01N57/32 , C07D231/38 , C07D401/04 , C07F9/6503 , C07F9/6558 , C07D403/04 , C07F9/65
CPC分类号： C07D231/38 , A01N43/56 , A01N57/32 , C07D401/04 , C07F9/65037
摘要： A 1-aryl-pyrazole of the formula ##STR1## in which R represents cyano or nitro,Ar represents in each case optionally substituted phenyl or pyridyl,X represents an azido group, or represents the radical ##STR2## and R.sup.1, R.sup.2 and R.sup.3 each independently represents alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxy, alkoxyalkyl, cycloalkyl or cycloalkyloxy, or represents in each case optionally substituted aryl, aryloxy, aralkyl or aralkyloxy,but wherein, in the case where R represents cyano and X simultaneously represents an azido group, Ar does not represent unsubstituted phenyl and does not represent 5-nitro-2-pyridyl. The compounds exhibit herbicidal and plant growth-regulating activity.
摘要翻译：式“IMAGE”的1-芳基吡唑其中R表示氰基或硝基，Ar表示各自为任意取代的苯基或吡啶基，X表示叠氮基，或表示基团R 1，R 2和R 3 或者代表任意取代的芳基，芳氧基，芳烷基或芳烷氧基，但其中，在R代表氰基，X同时代表叠氮基的情况下，基团，Ar不表示未取代的苯基，并不代表5-硝基-2-吡啶基。该化合物显示除草和植物生长调节活性。

109. 发明授权

US4695308A Herbicidal substituted 5-amino-1-aryl-pyrazoles 失效
标题翻译：除草取代的5-氨基-1-芳基 - 吡唑
公开(公告)号：US4695308A
公开(公告)日：1987-09-22
申请号：US925845
申请日：1986-10-30
申请人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
发明人： Reinhold Gehring , Markus Lindig , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Jorg Stetter
IPC分类号： A01N57/08 , A01N57/32 , C07F9/6503 , C07F9/6561 , C07F9/65
CPC分类号： C07F9/65037 , A01N57/32
摘要： Herbicidally active substituted 5-amino-1-aryl-pyrazoles of the formula ##STR1## in which R represents hydrogen, cyano, nitro or alkoxycarbonyl,R.sup.1 represents hydrogen or alkyl,R.sup.2 and R.sup.3 independently of one another in each case represent alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl, cycloalkyl, alkoxy or cycloalkoxy, or represent in each case optionally substituted aryl, aryloxy, aralkyl or aralkyloxy,X represents oxygen or sulphur andAr represents in each case optionally substituted phenyl or pyridyl,or salts thereof.
摘要翻译：其中R表示氢，氰基，硝基或烷氧羰基的除草活性取代的5-氨基-1-芳基 - 吡唑，R1代表氢或烷基，R2和R3各自独立地表示烷基，烯基，烷基，卤代烷基，烷氧基烷基，环烷基，烷氧基或环烷氧基，或在每种情况下表示任选取代的芳基，芳氧基，芳烷基或芳烷氧基，X表示氧或硫，Ar表示在任何情况下均为任选取代的苯基或吡啶基或其盐。

110. 发明授权

US4279813A Aqueous process for the preparation of aromatic phosphorus compounds 失效
标题翻译：用于制备芳香族磷化合物的水性方法
公开(公告)号：US4279813A
公开(公告)日：1981-07-21
申请号：US43496
申请日：1979-05-29
申请人： Otto Schallner , Rainer Hamprecht
发明人： Otto Schallner , Rainer Hamprecht
IPC分类号： C07F9/38 , C07F9/32 , C07F9/40 , C07F9/44 , C07F9/6503 , C09B43/40 , C09B69/00 , C09B43/00
CPC分类号： C09B69/007 , C07F9/3229 , C07F9/4021 , C07F9/65037 , C09B43/40
摘要： Phosphorus-containing compounds especially azo dyestuffs containing a grouping of the formula ##STR1## standing in ortho-position to the azo bridge are obtained in good yield if compounds of the formula ##STR2## are reacted with compounds of the formula ##STR3## in aqueous medium at a pH of 6-9 in the presence of copper or copper containing compounds.The process is less expensive than applying the conventional solvent method.In the above formulae:K=radical of a coupling component,V.sub.1 -V.sub.3 =H or non-ionic radical,X and Y=--OR, --SR, --NR.sub.2 or R,R=optionally substituted hydrocarbon radical,Z=--OR', --SR' or --NR'.sub.2 andR'=H or R.
摘要翻译：如果将式“IMAGE”的化合物与水溶液中的化合物“IMAGE”反应，则含有含磷化合物，特别是含有与偶氮桥位于邻位的式“IMAGE”分组的偶氮染料得到，在含铜或铜的化合物存在下，pH为6-9的培养基。该方法比应用常规溶剂方法便宜。在上式中：K =偶合组分的基团，V1-V3 = H或非离子基团，X和Y = -OR，-SR，-NR2或R，R =任选取代的烃基，Z = -OR '，-SR'或-NR'2和R'= H或R.

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