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91. 发明授权

US4120855A Bactericidally active monochlorotriazine dyes 失效
标题翻译：杀菌活性单氯三嗪染料
公开(公告)号：US4120855A
公开(公告)日：1978-10-17
申请号：US733369
申请日：1976-10-18
申请人： Vladimir Leibovich Liverant , Lev Moiseevich Yagupolsky , Andrei Yakovlevich Ilichenko , Faina Borisovna Timashpolskaya , Elena Alexeevna Fedorovskaya , Lidia Ivanovna Petrik , Iosif Yakubovich Kalantarov , Mira Semenovna Kopylova , Idima Evgenievna Meitus
发明人： Vladimir Leibovich Liverant , Lev Moiseevich Yagupolsky , Andrei Yakovlevich Ilichenko , Faina Borisovna Timashpolskaya , Elena Alexeevna Fedorovskaya , Lidia Ivanovna Petrik , Iosif Yakubovich Kalantarov , Mira Semenovna Kopylova , Idima Evgenievna Meitus
IPC分类号： C09B62/04 , D06M16/00 , C09B62/06 , A61L1/00 , C09B62/08 , C09B62/10
CPC分类号： D06M16/00 , C09B62/04
摘要： A method and composition for producing a bactericidal active monochlorotriazine dye, by reacting active dichlorotriazine dye with a bactericidal compound containing hydroxyl or amino groups. The reaction is run in an aqueous, organic, or water-organic medium at 20.degree.-40.degree. C. The monochlorotriazine dye thus formed is active and possesses bactericidal properties. On dyeing fibres, it endows them with high bactericidal properties retained after repeated wet treatments.
摘要翻译：一种通过活性二氯三嗪染料与含有羟基或氨基的杀菌化合物反应生产杀菌活性单氯三嗪染料的方法和组合物。该反应在20℃-40℃的水，有机或水 - 有机介质中进行。由此形成的一氯三嗪染料是有活性的，具有杀菌性。在染色纤维上，赋予它们在反复湿处理后保留的高杀菌性。

92. 发明授权

US4058516A Sulfo group-containing azo compounds having a tetrazo component radical derived from an optionally substituted 3,8-diaminodibenzofuran 失效
标题翻译：具有衍生自任选取代的3,8-二氨基二苯并呋喃的双偶氮组分基团的含磺基的偶氮化合物
公开(公告)号：US4058516A
公开(公告)日：1977-11-15
申请号：US481181
申请日：1974-06-20
申请人： Roland Mislin , Hanspeter Uehlinger
发明人： Roland Mislin , Hanspeter Uehlinger
IPC分类号： C09B35/00 , C09B35/34 , C09B35/376 , C09B35/40 , C09B45/24 , C09B62/006 , C09B62/08 , C09B43/00 , C09B43/12 , C09B43/18
CPC分类号： C09B45/28 , C09B35/34 , C09B35/376 , C09B35/40 , C09B62/09
摘要： Dyes of the formula ##STR1## AND SUBSTITUTED DERIVATIVES THEREOF, WHEREIN R is a coupling component radical,R.sub.1 is a coupling component radical, with the proviso that R and R.sub.1 are different, andN is 1 to 8,Are disclosed. They are useful for dyeing and printing natural and synthetic polyamides, cotton and other cellulosic fibers, polypropylene fibers modified by basic groups, synthetic polyamides and polyesters modified by acid groups, paper and leather. They exhibit good fastness to light, wet treatments and abrasion.
摘要翻译：下式的染料及其取代的衍生物，其中R是偶合成分基团，R1是偶合成分基团，条件是R和R1不同，并且N IS 1至8被公开。它们可用于染色和印刷天然和合成聚酰胺，棉花和其他纤维素纤维，由碱性基团改性的聚丙烯纤维，合成聚酰胺和由酸基改性的聚酯，纸和皮革。它们具有良好的耐光牢度，湿润处理和耐磨性。

93. 发明授权

US4054559A Reactive disazo monohalogenotriazine dyestuffs 失效
标题翻译：活性双偶氮单卤代三嗪染料
公开(公告)号：US4054559A
公开(公告)日：1977-10-18
申请号：US541770
申请日：1975-01-17
申请人： Kisuke Aoki , Teruhito Sotogoshi , Masahiro Hiraki
发明人： Kisuke Aoki , Teruhito Sotogoshi , Masahiro Hiraki
IPC分类号： C09B62/095 , C09B45/42 , C09B62/08 , D06P1/10 , D06P1/382
CPC分类号： C09B62/095
摘要： Reactive disazo dyestuffs of the following formula are disclosed. ##STR1## or --NHR wherein w.sub.1, w.sub.2, w.sub.3, and w.sub.4 represent hydrogen or methyl; Q represents --SO.sub.2 -- or --CO--; k, r, l and q represent 1 or 0; R represents hydrogen; --COCH.sub.3 ; ##STR2## which may be substituted by methyl or chloro; phenyl which may be substituted by sulfo or carboxy; or --CH.sub.2 CH.sub.2 OH. Hal represents chloro or bromo. X represents amino; mono- or di-alkylamino having from 1 to 3 carbon atoms; mono- or di-hydroxyalkylamino having from 1 to 3 carbon atoms; anilino which may be substituted by a sulfo group, carboxy group, methyl, ethyl, nitro, methoxy, ethoxy, acetylamino, sulfamoyl, .beta.-sulfatoethylsulfonyl, cyano, chloro, or bromo; N-methylanilino; carboxymethylamino; .beta.-sulfoethylamino; N-(.beta.-hydroxyethyl)-methylamino; naphthylamino which may be substituted by a sulfo group; morpholino; alkoxy having from 1 to 3 carbon atoms; or phenoxy which may be substituted by chloro, nitro, sulfo, or methyl, and p is 0 or 1, m is a whole number from 1 to 3 and n is a whole number from 1 to 2. These dyestuffs are useful for dyeing of such materials as cellulosic fibers.
摘要翻译：公开了下式的活性双偶氮染料。其中Y是：＆lt; IMAGE＆gt; Z是：＆lt; IMAGE＆gt;或-NHR，其中w1，w2，w3和w4表示氢或甲基; Q表示-SO 2 - 或-CO-; k，r，l和q表示1或0; R代表氢; -COCH3; 可以被甲基或氯取代的可被磺基或羧基取代的苯基; 或-CH 2 CH 2 OH。 Hal代表氯或溴。 X表示氨基; 具有1至3个碳原子的单或二烷基氨基; 具有1至3个碳原子的单 - 或二 - 羟烷基氨基; 可以被磺基，羧基，甲基，乙基，硝基，甲氧基，乙氧基，乙酰氨基，氨磺酰基，β-磺酰基乙基磺酰基，氰基，氯或溴取代的苯胺基; N-甲基苯胺基羧甲基氨基; β-磺乙基氨基; N-（β-羟乙基） - 甲基氨基; 可被磺基取代的萘基氨基; 吗啉代具有1至3个碳原子的烷氧基; 或可被氯，硝基，磺基或甲基取代的苯氧基，p为0或1，m为1至3的整数，n为1至2的整数。这些染料可用于染色诸如纤维素纤维的材料。

94. 发明授权

US4051118A Water-soluble disazo dyestuffs containing a 3- or 4-[pyrazolylene-(1)-benzoylamino]-6-sulphophenyl moiety 失效
标题翻译：含有3-或4- {8-吡唑基 - （1） - 苯甲酰氨基{9-6磺基苯基部分的水溶性双偶氮染料
公开(公告)号：US4051118A
公开(公告)日：1977-09-27
申请号：US566520
申请日：1975-04-08
申请人： Hans Ackermann , Fabio Beffa
发明人： Hans Ackermann , Fabio Beffa
IPC分类号： C09B31/02 , C09B62/01 , C09B62/08 , C09B62/24 , C09B62/74 , C09B62/82
CPC分类号： C09B31/025 , C09B62/01
摘要： Water-soluble disazo dyestuffs of the formula ##STR1## WHEREIN A represents phenyl, naphthyl or phenyl or naphthyl substituted by lower alkyl or sulphamoyl,B represents phenyl, lower alkyl-phenyl, naphthyl, phenol, lower alkylphenol, naphthol, benzoylaminonaphthol, N-methyl-N'-m-chloro-phenyl barbituric acid, or di-(phenylamino) malonic acid,Q represents 1,3- or 1,4-phenylene or 1,3- or 1,4-phenylene substituted by lower alkyl, chloro or bromo,R represents lower alkyl or COO.sup.- M.sup.+,X represents hydroxy or amino,Y represents a fiber reactive grouping capable of covalent bonding with cellulose and polyamide fibers group directly linked to a ring carbon atom of A or B,m represents a positive integer of at most 3, andn represents a positive integer of at most 5,And wherein which when m is 3, one Y is linked to A and the other to B are described. These dyestuffs are useful as dyes for cellulose and polyamide fibers.
摘要翻译：式A的水溶性双偶氮染料代表苯基，萘基或被低级烷基或氨磺酰基取代的苯基或萘基，B代表苯基，低级烷基 - 苯基，萘基，苯酚，低级烷基酚，萘酚，苯甲酰基氨基萘酚，N-甲基-N'-m-氯 - 苯基巴比妥酸或二 - （苯基氨基）丙二酸，Q表示1,3-或1,4-亚苯基或1,3-或1,4-亚苯基被低级烷基，氯或溴取代，R代表低级烷基或COO-M +，X代表羟基或氨基，Y代表能够与纤维素和聚酰胺纤维基团共价连接的纤维反应性基团，直接连接到A的环碳原子或 B，m表示最多3的正整数，N表示最多5的正整数，当M是3时，一个Y与A相连，另一个与B相连。这些染料可用作纤维素和聚酰胺纤维的染料。

95. 发明授权

US3905950A Reactive disazo dyestuffs containing 1-aminoalkyl-6-hydroxypyrid-6-one and monochlorotriazinyl groupings 失效
标题翻译：含有1-氨基烷基-6-羟基吡啶-6-酮和一氯三嗪基的活性双偶氮染料
公开(公告)号：US3905950A
公开(公告)日：1975-09-16
申请号：US36668673
申请日：1973-06-04
申请人： ICI LTD
发明人： CRABTREE ALLEN
IPC分类号： C09B62/006 , C09B62/04 , C09B62/09 , C09B62/08 , D06P1/38 , D06P3/60
CPC分类号： C09B62/043 , C09B62/0067 , C09B62/09
摘要： Disazo dyestuffs of the formula:

wherein N IS 0, 1 OR 2 P IS 0, 1 OR 2 Q IS 2 OR 3 AND Q is a member of the group consisting of 4,6-disulpho-1,3phenylene, 2,5-disulpho-1,4-phenylene,

D R A W I N G
in which Q1 is a direct link or -CH CH-, -NH-CONH-, -S-, OCH2CH2O-, -CH2- or -CH2CH2- . These dyestuffs are greenish-yellow cellulose-reactive dyes of good fastness to washing, light, hypochlorite bleaching and to acid and alkali treatments. Mixtures with phthalocyanine dyes exhibit better resistance to catalytic wet fading than similar dyes based on pyrazolone coupling components.
摘要翻译：下式的二重唑染料：SO3H | |（HO3S）n CH3 | N = N |（CH2）pH | CqH2qNHNCl角度角CC | PARALLEL NN ANGLE C | NH | Q | NH | C ANGLE NN | PARALLEL CC | PARALLEL | | CqH2qNHNCl | N = N|（CH2）pH | CH3（HO3S）n | | SO3H其中N IS 0，1 OR 2 P IS 0,1或2 Q IS 2 OR 3，Q是由 4,6-二磺基-1,3-亚苯基，2,5-二磺基-1,4-亚苯基，SO 3 HHO 3 S || NHCONH-和（2）SO 3 H | -Q1-- | HO 3 S（3）其中Q1是直链或-CH = CH-，-NH-CONH-，-S-，-OCH 2 CH 2 O-，-CH 2 - 或-CH 2 CH 2 - 。

96. 发明授权

US3843624A Mono or disazo dyestuffs containing a diamino,halotriazinyl or pyrimidinyl substituent 失效
标题翻译：含有二氨基，羟丙基或吡啶基取代基的单取代或二取代DYESTUFFS
公开(公告)号：US3843624A
公开(公告)日：1974-10-22
申请号：US842270
申请日：1970-02-03
申请人： CIBA GEIGY AG
发明人： SEILER H , DUSSY P
IPC分类号： C09B62/022 , C09B62/02 , C09B62/04 , C09B62/08 , C09B62/085 , D06P1/90 , D06P1/92 , D06P3/10 , C09B62/24 , D06P1/38
CPC分类号： C09B62/02 , D06P1/908 , D06P1/924 , D06P1/928 , D06P3/10 , Y10S534/02
摘要： Valuable reactive dyestuffs containing no acid, salt-forming, water-solubilizing groups and which, among others, can be applied to hydrophobic fibers especially polyamide fibers from organic solvents, especially aprotic solvents correspond to the formula

WHEREIN D represents the radical of an organic dyestuff, Q represents the bridging member -NX3-, -O-, -S- or -NX3CO-, whereby X3 denotes hydrogen or a lower alkyl group, R represents the radical of a nitrogen heterocycle containing at least one substitutent which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom, X1 represents hydrogen, an alkyl or an alkoxyalkyl group and X2 represents an alkyl or an alkoxyalkyl group having in all at least 4 carbon atoms, whereby X1 and X2 must together contain, when X1 denotes an alkyl or an alkoxyalkyl group, at least 8 carbon atoms, or X1 represents a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms, and X2 represents an unsubstituted or substituted alkyl group having at most 18 carbon atoms, a lower alkenyl group having preferably 1 to 4 carbon atoms or a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms. Fiber materials dyed with these dyestuffs exhibit very good fastness properties, especially fastness to wet processing, rubbing and dry-cleaning.

97. 发明授权

US3803121A Copper complex reactive monochloro-s-triazine azo dyestuff 失效
标题翻译：铜复合反应性单氯化-S-三嗪AZO DYESTUFF
公开(公告)号：US3803121A
公开(公告)日：1974-04-09
申请号：US21795172
申请日：1972-01-14
申请人： ICI LTD
发明人： GREGORY P
IPC分类号： C09B62/095 , C09B62/08 , D06P1/38 , D06P3/66
CPC分类号： C09B62/095
摘要： A DISAZO DYESTUFF OF THE FORMULA

1-((-)O-),2-((2-((-)O-),3-R1,5-R2-PHENYL)-N=N-),3-(HO3S-),

5-Z,6-Y,8-X-NAPHTHALENE CU(++)

WHEREIN R1 IS H, CI, NO2 OR SO3H AND R2 IS CI, NO2 OR SO3H, AT LEAST OONE OF R1 AND R2 BEING SO3H, AND EITHER X IS H, Z IS SO3 AND Y IS

(((2-X1,3-(R4-N=N-),5-X2-PHENYL)-N(-R3)-),CL-1,3,5-

TRIAZINYL)-NH-

WHEREIN R3 IS H OR CH3, R4 IS 4''-NITRO-2,2''-DISULPHOSTILBENE-4-YL OR DISULPHONAPHTHYL, X1 IS H, CH3 OR OCH3 AND X2 IS H, CH3, OCH3, NHCOCH3 OR NHCONH2, OR X IS FORMULA 2, ONE OF Y AND Z IS H AND THE OTHER IS SO3H. THESE DYES ARE BROWN REACTIVE DYES OF VERY GOOD LIGHT FASTNESS AND CAN BE USED TO DYE CELLULOSE TEXTILE MATERIALS.

98. 发明授权

US3752801A Fiber reactive phthalocyanine sulfonamido azo pyridone dyestuffs 失效
标题翻译：纤维反应性羟基苯胺磺酰胺
公开(公告)号：US3752801A
公开(公告)日：1973-08-14
申请号：US3752801D
申请日：1970-06-04
申请人： CIBA GEIGY AG
发明人： HOELZLE G , FASCIATI A
IPC分类号： C09B62/006 , C09B29/36 , C09B62/02 , C09B62/08
CPC分类号： C09B62/0068
摘要： PHTHALOCYANINESULFONAMIDO AZO-PYRIDONE DYESTUFFS OF THE GENERAL FORMULA

(HO3S)A-PC(-SO2-N(-A3)-B)C-(SO2-N(-A1)-R-N(-A2)-Z)B

IN WHICH PC IS NICKEL OR COPPER PHTHALOCYANINE A1, A2 AND A3 EACH INDEPENDENTLY IS HYDROGEN, LOWER ALKYL OR HYDROXYETHYL R IS PHENYLENE, METHYLENEPHENYLENE, ETHYLENEPHENYLENE OR DIPHENYLENE, EACH OF WHICH IS UNSUBSTITUTED OR SUBSTITUTED IN THE PHENYLENE MOIETY BY ONE OR MORE OF CHLORO, C1-C2 ALKOXY, C1-C2 ALKYL OR SULFONIC ACID, OR ALKYLENE OR CYCLOALKYLENE OF 2 TO 6 CARBON ATOMS, EACH OF WHICH IS UNSUBSTITUTED OR SUBSTITUTED BY B-HYDROXYETHYL, ACETYL OR CARBAMYL, ETHYLENEPIPERAZINYLENE OR R TOGETHER WITH A1 AND A2 FORMS PIPERAZINYLENE OR PIPERIDNYLENE, Z IS-A FIBRE-REACTIVE GROUP CAPABLE OF REACTING WITH THE HYDROXYL GROUPS OF CELLULOSE TO FORM A COVALENT BOND B IS A GROUP OF THE FORMULA

2-(O=),1-X,3-S,4-V,5-((-)R1-N=N-),6-HO-1,2-DIHYDROPYRIDINE

, OR 1-((-)R2-),2-(O=),3-S,4-V,5-(D-N=N-),6-HO-1,2-

DIHYDROPYRIDINE

IN WHICH R1 IS PHENYLENE, METHYLENEPHENYLENE OR ETHYLENEPHENYLENE WHERE THE PHENYLENE MOIETY IS SUBSTITUTED BY ONE OR MORE OF CHLORO, C1-C2 ALKOXY, C1-C2 ALKYL OR SULFONIC ACID AND WHEREIN THE PHENYL MOIETY IS BOUND TO THE AZO GROUP V IS LOWER ALKYL, PHENYL, TOLYL, CARBOXYLIC ACID ETHYL ESTER, CARBOXYLIC ACID BENZYL ESTER, METHYLENE CARBOXYLIC ACID ETHYL ESTER, CARBAMYL, N-ETHYL CARBAMYL, OR B-CYANOETHYLENE S IS NITRILE, CARBOXYLIC ACID ETHYL ESTER, CARBAMYL, N,NDIMETHYLSULFAMYL, METHYLSULFONYL OR PHENYLSULFONYL X IS HYDROGEN, LOWER ALKYL WHICH IS UNSUBSTITUTED OR SUBSTITUTED BY AMINO, HYDROXYL, SULFONIC ACID OR B-HYDROXYETHYLENEAMINE, PHENYL, BENZYL, CYCLOHEXYL, EACH OF WHICH CAN BE SUBSTITUTED BY AMINO, OR X IS A GROUP OF THE FORMULA

-R''-N(-Z)-A4

WHERE R'' IS ALKYLENE OF 1 TO 6 CARBON ATOMS, CYCLOHEXYLENE, PHENYLENE OR METHYLENEPHENYLENE A4 IS HYDROGEN OR LOWER ALKYL, AND Z IS A FIBER-REACTIVE GROUP R2 IS C1-C6 ALKYLENE D IS BENZENESLFONATE CONTAINING ONE OR MORE SULFONIC ACID GROUPS AND SUBSTITUTED BY ONE OR MORE OR CHLORO, HYDROXY, METHOXY, METHYL, CARBOXY, ACETAMIDO, BENZAMIDO, NITRO, SULPHOACETYLAMINO, TRIFLUOROMETHYL OR AMINOBENZOYL, OR NAPHTHALENESULFONATE CONTAINING ONE OR MORE SULFONIC ACID GROUPS AND D CAN ADDITIONALLY BE SUBSTUTITED BY A FIBER-REACTIVE GROUP, AND A, B AND C EACH, INDEPENDENTLY IS AN INTEGER OR FRACTIONAL NUMBER PROVIDED THAT B AND C IS EACH AT LEAST 1.0 AND THE SUM OF A+B+C IS AN INTEGER OR FRACTIONAL NUMBER BETWEEN 3.0 AND 4.0, ARE USEFUL AS COTTON DYES YIELDING GREEN SHADES OF GOOD GENERAL FASTNESS PROPERTIES.

99. 发明授权

US3725383A 2-hydroxy-pyrid-6-one azo dyestuffs containing a cellulose fiber reactive substituent 失效
标题翻译：含有纤维素纤维反应性替代物的2-羟基 - 吡啶-6-酮AZO脱水酶
公开(公告)号：US3725383A
公开(公告)日：1973-04-03
申请号：US3725383D
申请日：1971-05-20
申请人： ICI LTD
发明人： AUSTIN P , YOUNG E , LENG J , RIDYARD D
IPC分类号： C09B29/15 , C09B29/42 , C09B31/153 , C09B45/02 , C09B62/006 , C09B29/36 , C09B62/08 , C09B62/24
CPC分类号： C09B62/0067 , C09B29/10 , C09B29/3621 , C09B31/153 , C09B45/025
摘要： Azo dyestuffs of the general formula:

D R A W I N G
WHEREIN R represents an aromatic radical which may contain one or more further azo groups, M represents H or a metal atom forming part of a metal-complex system in the dyestuff, R1 represents an alkyl group or a phenyl radical which may be substituted, e.g., by lower alkyl, lower alkoxy or chlorine, R2 represents a hydrogen atom, an alkyl, aralkyl or cycloalkyl group or a phenyl radical which may be substituted, e.g., by lower alkyl, lower alkoxy or halogen, and R3 represents a hydrogen atom, a heterocyclic radical containing a cellulose-reactive substituent, or the acyl radical of an organic carboxylic or sulphonic acid which may or may not contain a cellulose-reactive substituent are valuable dyestuffs for a variety of substrates. For example those containing SO3H groups and a fiber-reactive group are valuable for dyeing and printing of cellulose polyamide and wool textile materials while those which are free from complex metal groups and sulphonic acid groups may be used as disperse dyestuffs.
摘要翻译：偶氮染料的通式如下：

100. 发明授权

US3668211A Certain 6-hydroxy 2-(1h) pyridones 失效
标题翻译：某些6-羟基2-（1H）吡啶
公开(公告)号：US3668211A
公开(公告)日：1972-06-06
申请号：US3668211D
申请日：1969-10-30
申请人： ICI LTD
发明人： CRABTREE ALLEN
IPC分类号： C07D213/81 , C09B62/006 , C09B62/08 , C07D31/46
CPC分类号： C07D213/81 , C09B62/0067 , C09B62/08
摘要： Compounds of the formula

WHEREIN T1 represents a hydrogen atom or a group of the formula -COOR1 or CONR1R2, or an aliphatic, araliphatic, homocyclic or heterocyclic radical, T2 represents a group of the formula -CN, -COOR1 or CONR1R2, R1 and R2 each independently represents a hydrogen atom or an aliphatic, araliphatic, homocyclic or heterocyclic radical or NR1R2 represents a heterocyclic radical, and Z represents an aliphatic radical having a primary or secondary amono group substituted therein, are valuable dyestuff intermediates being useful as coupling components for the manufacture of a wide variety of azo compounds.
摘要翻译：式WHEREIN T1的化合物表示氢原子或式-COOR1或CONR1R2的基团，或脂族，芳脂族，双环或杂环基团，T2表示式-CN，-COOR1或CONR1R2，R1和R2的基团每个独立地表示氢原子或脂族，芳脂族，双环或杂环基，或-NR 1 R 2表示杂环基，Z表示其中被取代的伯或仲氨基的脂族基团，是有价值的染料中间体，可用作偶联组分制造各种各样的偶氮化合物。

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