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    • 100. 发明申请
    • Modifying Polyoxymethylene Imidized Acrylic Resins
    • 改性聚甲醛酰亚胺树脂
    • US20130137811A1
    • 2013-05-30
    • US13306806
    • 2011-11-29
    • Xiyun Serene FanRamabhadra Ratnagiri
    • Xiyun Serene FanRamabhadra Ratnagiri
    • C08L59/02C08L59/04C08L33/12
    • C08L59/02C08F8/48C08L59/04C08L33/24C08F8/32C08F8/12C08F120/14C08F8/14
    • Described herein are compositions comprising (a) 92 to 99 weight percent, of polyoxymethylene with number average molecular weight from 65,000 to 250,000 g/mole; and (b) 1 to 8 weight percent of an imidized acrylic resin obtained by treating an acrylic polymer with a monoalkyl amine, wherein the weight percents of a and b are based on their combined weight, and monoalkyl group has from one to five carbon atoms, the degree of imidization is 20% to 100% and the acid level is from 0 to about 2 weight percent of the imidized acrylic resin. The composition has significantly higher heat deflection temperature than the neat polyoxymethylene.Processes of increasing heat deflection temperature of POM compositions described herein by blending (a) and (b), wherein the resultant melt-mixed composition has a 200% increase or greater in time to 5% creep strain relative to the same melt-mixed composition lacking (b).
    • 本文描述的是包含(a)92至99重量%的数均分子量为65,000至250,000g /摩尔的聚甲醛的组合物; 和(b)1至8重量%的通过用单烷基胺处理丙烯酸类聚合物而得到的酰亚胺化丙烯酸树脂,其中a和b的重量百分比基于其组合重量,单烷基具有1至5个碳原子 酰亚胺化度为20%〜100%,酸度为酰亚胺化丙烯酸树脂的0〜2%。 该组合物具有比纯聚甲醛显着更高的热变形温度。 通过混合(a)和(b),增加本文所述的POM组合物的热变形温度的方法,其中所得熔体混合组合物相对于相同的熔融混合组合物在5%蠕变应变时间上具有200%增加或更大 缺乏(b)。