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    • 92. 发明申请
    • SYSTEMS, METHODS, AND COMPOSITIONS FOR PRODUCTION OF SYNTHETIC HYDROCARBON COMPOUNDS
    • 用于生产合成碳氢化合物的系统,方法和组合物
    • US20100113623A1
    • 2010-05-06
    • US12647121
    • 2009-12-24
    • Alexander J. SEVERINSKY
    • Alexander J. SEVERINSKY
    • C07C1/12
    • C10G2/32C10G2/30C10G2300/1022C10J3/18C10J2300/093C10J2300/1238C10J2300/1659C25B1/04C25B15/08Y02E60/364Y02E60/366Y02E70/10Y02P20/128Y02P20/129Y02P20/133
    • A process and system for producing hydrocarbon compounds or fuels that recycle products of hydrocarbon compound combustion—carbon dioxide or carbon monoxide, or both, and water. The energy for recycling is electricity derived from preferably not fossil based fuels, like from nuclear fuels or from renewable energy. The process comprises electrolysing water, and then using hydrogen to reduce externally supplied carbon dioxide to carbon monoxide, then using so produced carbon monoxide together with any externally supplied carbon monoxide and hydrogen in Fischer-Tropsch reactors, with upstream upgrading to desired specification fuels—for example, gasoline, jet fuel, kerosene, diesel fuel, and others. Energy released in some of these processes is used by other processes. Using adiabatic temperature changes and isothermal pressure changes for gas processing and separation, large amounts of required energy are internally recycled using electric and heat distribution lines. Phase conversion of working fluid is used in heat distribution lines for increased energy efficiency. The resulting use of electric energy is less than 1.4 times the amount of the high heating value of combustion of so produced hydrocarbon compounds when carbon dioxide is converted to carbon monoxide in the invention, and less than 0.84 when carbon monoxide is the source.
    • 用于生产烃化合物燃烧二氧化碳或一氧化碳或二氧化碳或水的产物的烃化合物或燃料的方法和系统。 回收利用的能源是优选不是以化石为基础的燃料,如核燃料或可再生能源。 该方法包括电解水,然后使用氢气将外部供应的二氧化碳减少到一氧化碳,然后在费 - 托反应器中使用这样生产的一氧化碳和任何外部提供的一氧化碳和氢气,并将其上游升级为所需规格的燃料 - 用于 例如汽油,喷气燃料,煤油,柴油等。 在其中一些过程中释放的能量被其他过程所使用。 使用绝热温度变化和气体处理和分离的等温压力变化,使用电力和热分配管线在内部回收大量所需的能量。 工作流体的相转化用于配电线路,以提高能源效率。 所得到的电能的使用量小于本发明中二氧化碳转化成一氧化碳时所产生的碳氢化合物燃烧的高热值的量的1.4倍,当一氧化碳为源时小于0.84。
    • 94. 发明申请
    • Zero Steam Export With CO2 Recovery In A High Thermal Efficiency Hydrogen Plant
    • 零蒸汽出口在高热效率氢厂的二氧化碳回收
    • US20100104499A1
    • 2010-04-29
    • US12608573
    • 2009-10-29
    • Bhadra S. Grover
    • Bhadra S. Grover
    • C01B3/26C01B3/24
    • C01B3/38C01B3/48C01B3/56C01B2203/0233C01B2203/0283C01B2203/0288C01B2203/043C01B2203/047C01B2203/0475C01B2203/0816C01B2203/0822C01B2203/0827C01B2203/0894C01B2203/1047C01B2203/1076C01B2203/1241C01B2203/1247C01B2203/1258C01B2203/1294C01B2203/148C01B2203/86Y02P20/128Y02P30/30
    • A high thermal efficiency process for hydrogen recovery is provided. The present invention includes combusting a first fuel stream to a reforming furnace, producing reforming heat and a hot exhaust stream. Then exchanging heat indirectly between the hot exhaust stream and a first feed water stream, producing a first steam stream. Then providing a hydrocarbon containing stream and a feed steam stream to the reforming furnace, utilizing the reforming heat and producing a hot raw syngas stream. Then exchanging heat indirectly between the hot raw syngas stream and second feedwater stream, producing a second steam stream and a cooled, raw syngas stream. Then introducing the cooled, raw syngas stream to a CO shift converter, producing a shifted syngas stream. Then introducing the shifted syngas stream into a pressure swing adsorption unit, producing a hydrogen product stream and a tail gas stream. Then introducing the tail gas stream to a CO2 removal unit, producing a CO2 stream and a recycle stream; compressing the recycle stream, producing a compressed recycle stream. Then combining the compressed recycle stream with at least one stream selected from the group consisting of the hydrocarbon containing stream, the cooled raw syngas stream, the shifted syngas stream, and the tail gas stream. Then combining the first steam stream and the second steam stream, producing the feed steam stream.
    • 提供了用于氢回收的高热效率方法。 本发明包括将第一燃料流燃烧到重整炉,产生重整热和热排气流。 然后间接地在热排气流和第一给水流之间进行热交换,产生第一蒸汽流。 然后向重整炉提供含烃流和进料蒸汽流,利用重整热并产生热原始合成气流。 然后间接地在热原料合成气流和第二给水流之间进行热交换,产生第二蒸汽流和冷却的原始合成气流。 然后将冷却的原始合成气流引入CO移位转换器,产生位移合成气流。 然后将转换的合成气流引入变压吸附单元,产生氢产物流和尾气流。 然后将尾气流引入CO 2去除单元,产生CO 2流和再循环流; 压缩循环流,产生压缩的再循环流。 然后将压缩的再循环料流与选自含烃的料流,冷却的原料合成气物流,转换的合成气物流和尾气流中的至少一种物流组合。 然后组合第一蒸汽流和第二蒸汽流,产生进料蒸汽流。