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    • 97. 发明申请
    • LUMINESCENT SILICON NANOPARTICLE-POLYMER COMPOSITES, COMPOSITE WAVELENGTH CONVERTER AND WHITE LED
    • 发光硅纳米聚合物复合材料,复合波长转换器和白光LED
    • US20090102353A1
    • 2009-04-23
    • US12241870
    • 2008-09-30
    • Munir H. Nayfeh
    • Munir H. Nayfeh
    • H01L51/50C09K11/02
    • C09K11/02C09K11/59H01L33/502
    • An embodiment of the invention is luminescent silicon nanoparticle polymer composite that can serve as a wavelength converter or a UV absorber. The composite includes a polymer or an organosilicon compound; and within, the polymer or organosilicon compound, a dispersion of luminescent silicon nanoparticles. In a preferred composite, the silicon nanoparticles having a multiple Si—H termination sites, the silicon nanoparticles being linked to a C cite to produce a silicon carbide bond (Si—C). In a preferred embodiment, the polymer comprises polyurethane. A composite of the invention can perform wavelength conversion. In a wavelength converted film of the invention, the silicon nanoparticles are incorporated into the polymer or organosilicon compound in a quantity sufficient for wavelength conversion but small enough to have no or an insubstantial affect on the properties of the polymer or the organosilicon compound. A white LED of the invention includes a light emitting diode having a narrow band wavelength output. A luminescent silicon wavelength converter includes a composite film as described above for converting the narrow band wavelength output into wide band wavelength output. In a preferred embodiment, the LED comprises a GaN LED, and the wavelength converter film is disposed on an active region of the LED.
    • 本发明的一个实施方案是可用作波长转换器或UV吸收剂的发光硅纳米颗粒聚合物复合材料。 复合材料包括聚合物或有机硅化合物; 在聚合物或有机硅化合物内,发光硅纳米颗粒的分散体。 在优选的复合材料中,具有多个Si-H终止位点的硅纳米颗粒,硅纳米颗粒与C引物连接以产生碳化硅键(Si-C)。 在优选的实施方案中,聚合物包含聚氨酯。 本发明的复合物可以进行波长转换。 在本发明的波长转换膜中,将硅纳米颗粒掺入到聚合物或有机硅化合物中,其量足够于波长转换,但足够小以致对聚合物或有机硅化合物的性质没有或没有实质的影响。 本发明的白色LED包括具有窄带波长输出的发光二极管。 发光硅波长转换器包括如上所述的用于将窄带波长输出转换成宽带波长输出的复合膜。 在优选实施例中,LED包括GaN LED,并且波长转换器膜设置在LED的有源区上。
    • 98. 发明申请
    • NANOSILICON-BASED ROOM TEMPERATURE PAINTS AND ADHESIVE COATINGS
    • 基于纳米硅基的室温涂料和胶粘涂料
    • US20090090893A1
    • 2009-04-09
    • US12241881
    • 2008-09-30
    • Munir H. Nayfeh
    • Munir H. Nayfeh
    • C09K11/59
    • C09K11/59B82Y30/00C01B33/02C01P2004/64C09D5/22
    • A composite of the invention is a homogenous mixture of room temperature vulcanizing material or polymer and luminescent silicon nanoparticles. The composite can be formed into a film and can serve as a paint, adhesive, or coating, depending upon the material or polymer used. A preferred polymer is polyurethane. A method for forming a silicon nanoparticle and room temperature vulcanizing (RTV) material or polymer composite of the invention includes steps providing silicon nanoparticles that were prepared in a solvent. The solvent is mixed with RTV or polymer precursors. The RTV or polymer components are permitted to cure. A preferred solvent is isopropynol alcohol.
    • 本发明的复合材料是室温硫化材料或聚合物和发光硅纳米颗粒的均匀混合物。 根据所使用的材料或聚合物,复合材料可以形成膜并且可以用作涂料,粘合剂或涂层。 优选的聚合物是聚氨酯。 本发明的硅纳米颗粒和室温硫化(RTV)材料或聚合物复合材料的形成方法包括提供在溶剂中制备的硅纳米颗粒的步骤。 将溶剂与RTV或聚合物前体混合。 允许RTV或聚合物组分固化。 优选的溶剂是异丙醇。