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    • 92. 发明授权
    • Anionic bituminous emulsions with improved adhesion
    • 具有改善附着力的阴离子烟煤乳液
    • US5772749A
    • 1998-06-30
    • US929837
    • 1997-09-15
    • Peter SchillingEverett Crews
    • Peter SchillingEverett Crews
    • C08G73/02C08L95/00
    • C08L95/005C08G73/028
    • This invention relates to rapid set, medium set, and slow set anionic emulsions prepared from straight bitumen or bitumen modified by the incorporation of polymers such as styrene butadiene rubbers (SBR), styrene block copolymers (SBS), ethylene vinyl acetate copolymers (EVA), and other suitable modifiers. The invention also relates to emulsions modified by the incorporation of solvents (such as diesel oil or kerosene) or by the addition of polymer latices (such as SBR-latex or natural rubber latex). More particularly, the invention relates to improved methods for enhancing adhesion between asphalt and aggregate in anionic solventless and solvent-containing bituminous emulsions wherein the emulsifiers are alkali earth salts of tall oil fatty acids, fortified tall oil fatty acids, tall oil rosins, and fortified rosins as well as combinations of kraft lignins and nonionic emulsifiers. The adhesion promoting compositions utilized in these improved methods are produced by reacting tall oil fatty acid and/or modified tall oil fatty acid to yield a polyalkylene amine, then blending the polyamidoamine with Bis-hexamethylenetriamine to produce the adhesion promoter.
    • 本发明涉及通过掺入聚合物如苯乙烯丁二烯橡胶(SBR),苯乙烯嵌段共聚物(SBS),乙烯乙酸乙烯酯共聚物(EVA)等改性的直沥青或沥青制备的快速固化, ,和其他合适的改性剂。 本发明还涉及通过引入溶剂(例如柴油或煤油)或通过加入聚合物胶乳(例如SBR胶乳或天然橡胶胶乳)而改性的乳液。 更具体地说,本发明涉及在阴离子无溶剂和含溶剂的沥青乳液中增强沥青和骨料之间的粘合性的改进方法,其中乳化剂是妥尔油脂肪酸的碱土金属盐,强化妥尔油脂肪酸,妥尔油松香和强化油 松香以及牛皮纸木质素和非离子乳化剂的组合。 在这些改进方法中使用的粘附促进组合物通过使妥尔油脂肪酸和/或改性妥尔油脂肪酸反应得到聚亚烷基胺,然后将聚酰胺胺与双 - 六亚甲基三胺混合以产生粘合促进剂来制备。
    • 96. 发明授权
    • Anionic bituminous emulsions
    • 阴离子沥青乳液
    • US5668197A
    • 1997-09-16
    • US694452
    • 1996-08-12
    • Peter Schilling
    • Peter Schilling
    • C08L25/08C08F8/32C08G69/34C08K3/00C08L33/02C08L33/06C08L77/06C08L95/00
    • C08L95/005
    • This invention relates to rapid set, medium set, and slow set anionic emulsions prepared from straight bitumen or bitumen modified by the incorporation of polymers, solvents, or polymer latices. Particularly, the invention relates to improved methods for enhancing adhesion between the asphalt and the aggregate in avionic solventless and solvent-containing bituminous emulsions wherein the emulsifiers are alkali earth salts of tall oil fatty acids, fortified tall oil fatty acids, tall oil rosin and fortified rosin as well as combinations of kraft lignin and nonionic emulsifiers. The adhesion promoters utilized in these improved methods are the reaction products of styrene (.alpha.-methyl styrene)-acrylic (metacrylic) acid polymers with polyalkylene amines. Further improvement can be obtained by using tall oil fatty acid or fortified tall oil fatty acids as co-reactants in the production of the polyamidoamine products.
    • 本发明涉及由通过掺入聚合物,溶剂或聚合物胶乳改性的直沥青或沥青制备的快速凝固,中等凝固和慢速组合的阴离子乳液。 特别地,本发明涉及用于增强沥青和聚集体之间在航空电子无溶剂和含溶剂的沥青乳液中的粘附性的改进方法,其中乳化剂是妥尔油脂肪酸的碱土金属盐,强化的妥尔油脂肪酸,妥尔油松香和强化的 松香以及牛皮纸木质素和非离子乳化剂的组合。 在这些改进方法中使用的粘合促进剂是苯乙烯(α-甲基苯乙烯) - 丙烯酸(甲基丙烯酸)酸聚合物与聚亚烷基胺的反应产物。 通过使用妥尔油脂肪酸或强化妥尔油脂肪酸作为聚酰胺胺产物生产中的共反应物,可以进一步改善。