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91. 发明授权

US06720461B2 Removal of salts in the manufacture of phenolic compound 失效
标题翻译：去除酚类化合物制造中的盐
公开(公告)号：US06720461B2
公开(公告)日：2004-04-13
申请号：US09728275
申请日：2000-12-01
申请人： Austin Dale Taggart, II , Edgar Donald Allan , Roberto Carlos Longoria , David Werner Daum , Robert Lawrence Blackbourn
发明人： Austin Dale Taggart, II , Edgar Donald Allan , Roberto Carlos Longoria , David Werner Daum , Robert Lawrence Blackbourn
IPC分类号： C07C3768
CPC分类号： C07C37/685 , C07C37/08 , C07C39/04
摘要： There is provided a process for the manufacture of phenolic compounds by separating a neutralized aralkyl hydroperoxide cleavage mass stream containing salts of neutralization into a crude ketone stream and a crude phenolic stream containing the salts of neutralization; separating the crude phenolic stream into a concentrated phenolic-rich stream, enriched in phenolic compounds, and a crude phenolic bottoms stream enriched in tars and alpha methyl styrene dimers, each compared to the crude phenolic stream, said crude phenolic bottoms stream containing salts of neutralization; to the crude phenolic bottoms stream, adding water and a diluent composition, thereby forming a phase separable crude phenolic bottoms stream, said diluent composition comprised of hydrocarbons phase compatible with the crude phenolic bottoms stream and having a combined density lower than the density of the crude phenolic bottoms stream; separating the separable crude phenolic bottoms stream into a hydrocarbon phase and an aqueous phase containing salts of neutralization; whereby the amount of salts of neutralization in the hydrocarbon phase is reduced compared to the amount of salts of neutralization present prior to separation.
摘要翻译：提供了一种通过将含有中和盐的中和的芳烷基氢过氧化物切割质量流分离成粗酮物流和含有中和盐的粗酚物流来制备酚类化合物的方法; 将粗酚流分离成富含酚类化合物的富含浓酚的料流，以及富含焦油和α-甲基苯乙烯二聚体的粗酚底物流，其与粗酚流相比，所述粗酚底物流含有中和盐 ; 加入水和稀释剂组合物，从而形成可分离的粗酚底物流，所述稀释剂组合物由与粗酚底物流相容的烃相组成，并且具有低于粗制酚底物流密度的组合密度酚底物流; 将可分离的粗酚底物流分离成烃相和含有中和盐的水相; 由此与分离前存在的中和盐的量相比，烃相中的中和盐的量减少。

92. 发明申请

US20040063568A1 Method for the production of form-selective catalysts and use thereof 审中-公开
标题翻译：生产形式选择性催化剂的方法及其用途
公开(公告)号：US20040063568A1
公开(公告)日：2004-04-01
申请号：US10399781
申请日：2003-10-23
发明人： Adolf Kuhnle , Mark Duda , Karsten Seelbach , Steffen Hasenzahl , Uwe Tanger , Carsten Jost , Elias Klemm , Andreas Reitzmann
IPC分类号： B01J029/04 , B01J029/87
CPC分类号： C07D301/12 , B01D53/8628 , B01D53/8668 , B01J29/061 , C07C37/60 , C07C213/00 , Y02P20/52 , C07C215/76 , C07C39/04
摘要： The invention relates to a process for manufacturing zeolite catalysts containing subgroup metals by hydrothermal synthesis with subsequent calcination, which is characterized in that the subgroup metals are used in hydrothermal synthesis in the form of carbonyl, isonitrile or cyanocomplexes. The catalysts thus produced can be used as a catalyst for removing nitrogen or for oxidizing organic compounds.
摘要翻译：本发明涉及通过随后的煅烧水热合成制备含亚金属的沸石催化剂的方法，其特征在于亚组金属以羰基，异腈或氰基络合物的形式用于水热合成。由此生产的催化剂可用作除去氮气或氧化有机化合物的催化剂。

93. 发明授权

US06680413B2 Process for the recovery of phenol and biphenols 有权
标题翻译：苯酚和联苯酚的回收方法
公开(公告)号：US06680413B2
公开(公告)日：2004-01-20
申请号：US10442089
申请日：2003-05-21
申请人： Rossella Bortolo , Lino Carnelli , Daniele Moscotti , Daniele Bianchi
发明人： Rossella Bortolo , Lino Carnelli , Daniele Moscotti , Daniele Bianchi
IPC分类号： C07C3768
CPC分类号： C07C37/74 , C07C37/685 , C07C37/72 , C07C37/78 , C07C37/86 , Y02P20/582 , C07C39/04 , C07C39/15 , C07C39/235
摘要： A process is described for the recovery of phenol and biphenols from their homogeneous mixtures containing benzene, sulfolane and water, which is based on the use of an alkaline solution and benzene for the separation of biphenols from sulfolane, after removing the benzene, H2O and phenol contained in the reaction effluent. The process allows the recovery of phenol and biphenol by-products dissolved in sulfolane, directly obtaining the purified solvent containing the benzene necessary for the feeding to the reactor for the direct oxidation of benzene, as well as the biphenols dissolved in water and pure phenol.
摘要翻译：描述了一种从含有苯，环丁砜和水的均匀混合物中回收苯酚和联苯酚的方法，其基于在除去苯，H 2 O和苯酚之后使用碱性溶液和苯来分离联苯酚与环丁砜分离反应流出物中含有的苯酚和联苯酚副产物的回收，直接得到含有苯进行反应器所需的苯的纯化溶剂直接氧化苯，以及溶解的联苯酚在水和纯苯酚中。

94. 发明授权

US06630608B2 Process for preparing phenols 失效
标题翻译：酚类制备方法
公开(公告)号：US06630608B2
公开(公告)日：2003-10-07
申请号：US10090475
申请日：2002-03-04
申请人： Uwe Tanger , Reinhard Sigg , Siegmund Greschek , Manfred Weber
发明人： Uwe Tanger , Reinhard Sigg , Siegmund Greschek , Manfred Weber
IPC分类号： C07C3768
CPC分类号： C07C37/08 , C07C39/04
摘要： The present invention relates to a process for preparing phenols, in which the pH of the reaction product from the acid-catalyzed cleavage of alkylaryl hydroperoxides is set to a value of at least 8 at a temperature of at least 100° C. prior to the work-up of the product. This measure enables the content of undesirable by-products, e.g. hydroxyacetone, in the cleavage product to be significantly reduced. This procedure is particularly advantageously integrated into a process for preparing phenols by: a) acid-catalyzed cleavage of alkylaryl hydroperoxides and b) thermal after-treatment of the cleavage product from step a), with the temperature in step b) being higher than in step a) and is at least 100° C., wherein the adjustment to a pH of at least 8 is carried out after the thermal after-treatment and prior to cooling of the cleavage product.
摘要翻译：本发明涉及一种制备酚的方法，其中来自烷基芳基氢过氧化物的酸催化裂解的反应产物的pH在至少100℃的温度之前设定为至少8的值产品的后处理。该措施使得不期望的副产物的含量，例如羟基丙酮，在裂解产物中显着降低。该方法特别有利地整合到通过以下步骤制备酚的方法中：a）烷基芳基氢过氧化物的酸催化裂解和b）来自步骤a）的裂解产物的热后处理，步骤b）中的温度高于步骤 a）并且至少为100℃，其中调节至少8的pH在热后处理之后和在冷却切割产物之前进行。

95. 发明申请

US20030163007A1 Process and catalyst for purifying phenol 有权
标题翻译：苯酚纯化方法及催化剂
公开(公告)号：US20030163007A1
公开(公告)日：2003-08-28
申请号：US10354270
申请日：2003-01-30
发明人： Arkady Samuilovich Dyckman , John William Fulmer , Boris V. Krasy , Viktor Vladimirovich Pinson , Yury Alekseevich Shavandin , Genrikh Petrovich Yavshits , Andrey Vladimirovich Zinenkov
IPC分类号： C07C037/68 , B01J023/00
CPC分类号： B01J27/053 , B01J37/0018 , B01J37/0036 , B01J37/03 , C07C37/86 , Y02P20/52 , C07C39/04
摘要： The goal of this invention is to produce phenol of high purity by conversion of impurities that are present in the starting phenol, which is produced by the decomposition of cumyl hydroperoxide. The indicated goal is achieved by purifying the phenol containing admixtures of aliphatic and aromatic carbonyl compounds with an aluminum zirconium catalyst.
摘要翻译：本发明的目的是通过转化通过氢过氧化枯烯的分解产生的起始苯酚中存在的杂质来生产高纯度的苯酚。指出的目标是通过用铝锆催化剂纯化含酚的脂族和芳族羰基化合物的混合物来实现。

96. 发明授权

US06583326B2 Process for separating phenol from a mixture comprising at least hydroxyacetone, cumene, water and phenol 有权
公开(公告)号：US06583326B2
公开(公告)日：2003-06-24
申请号：US09970856
申请日：2001-10-05
申请人： Christoph Schwarz , Markus Weber , Uwe Tanger , Hermann-Josef Korte , Jochen Ullrich
发明人： Christoph Schwarz , Markus Weber , Uwe Tanger , Hermann-Josef Korte , Jochen Ullrich
IPC分类号： C07C3768
CPC分类号： C07C37/74 , C07C39/04
摘要： Phenol is separated from a mixture containing hydroxyacetone, cumene, water and phenol, by fractionating the mixture in a process with a fractional distillation step and a phase separation step to provide a single phenol fraction containing less than 300 ppm of hydroxyacetone. In the work-up by distillation of cleavage product mixtures, the hydroxyacetone can be removed from the cleavage product mixture together with a phenol fraction from which the hydroxyacetone has to be removed. A process can be used for purifying cleavage product mixtures obtained in the cleavage of alkylaryl hydroperoxides such as cumene hydroperoxide. The process allows separation of phenol and acetone from mixtures obtained in the cleavage of cumene hydroperoxide.

97. 发明申请

US20030100800A1 SYSTEM AND METHOD FOR PURIFYING CUMENE HYDROPEROXIDE CLEAVAGE PRODUCTS 有权
标题翻译：净化水合氧化丙烯酰胆碱产品的系统和方法
公开(公告)号：US20030100800A1
公开(公告)日：2003-05-29
申请号：US09683190
申请日：2001-11-29
发明人： John William Fulmer , Pramod S. Kumbhar , Marakani Venkata Ramani , Bharat Singh
IPC分类号： C07C045/80 , C07C037/72 , B01J008/04 , B01J010/00
CPC分类号： C07C37/86 , B01J19/0086 , B01J2219/00006 , C07C45/85 , C07C39/04
摘要： A system for purifying a cumene hydroperoxide cleavage product mixture comprises a cumene hydroperoxide cleavage product mixture feed containing impurities in fluid communication with an aqueous alkaline solution feed; the cumene hydroperoxide cleavage product mixture and aqueous alkaline solution feeds are in fluid communication with a neutralization drum having an aqueous salt phase outlet; an aqueous salt phase feed containing impurities in fluid communication with a heat treatment vessel having a heat-treated aqueous salt phase outlet; and a heat-treated aqueous salt phase feed containing water-soluble derivatives of the impurities in fluid communication with the cumene hydroperoxide cleavage product mixture prior to the neutralization drum.
摘要翻译：用于纯化氢过氧化枯烯裂解产物混合物的系统包括含有与碱性水溶液进料流体连通的杂质的枯烯氢过氧化物裂解产物混合物进料; 氢过氧化枯烯裂解产物混合物和碱性水溶液进料与具有盐水相出口的中和鼓流体连通; 含有与具有热处理的盐水相出口的热处理容器流体连通的杂质的含水盐相进料; 和热处理的含水盐相进料，其含有在中和鼓之前与氢过氧化枯烯裂解产物混合物流体连通的杂质的水溶性衍生物。

98. 发明申请

US20030050513A1 Decomposition of organic hydroperoxides in the presence of a particulate catalyst containing fluorinated polymer having sulfonic acid groups and process for the manufacture of bisphenol A 失效
标题翻译：在含有具有磺酸基的氟化聚合物的颗粒催化剂存在下分解有机氢过氧化物和制备双酚A的方法
公开(公告)号：US20030050513A1
公开(公告)日：2003-03-13
申请号：US10177853
申请日：2002-06-20
发明人： Ralph Birchard Lloyd , Qun Sun , Mark Andrew Harmer , Edward George Howard JR.
IPC分类号： C07C039/16 , C07C037/08
CPC分类号： C07C37/08 , B01J31/06 , C07C37/20 , C07C2527/03 , Y02P20/52 , C07C39/04 , C07C39/16
摘要： A process for the manufacture of a hydroxy-substituted organic compound comprising decomposing an organic hydroperoxide, preferably a compound of the formula ArnullC(CH3)2O2H, wherein Ar is a substituted or unsubstituted mononuclear or polynuclear aromatic group. The decomposition is carried out in the presence of a catalyst comprising highly fluorinated polymer having sulfonic acid groups with the catalyst being in the form of particles of which at least about 20 weight % have a particle size less than about 300 nullm. Cumene hydroperoxide can be decomposed in the process to phenol and acetone which can be reacted to form bisphenol A in the presence of the same catalyst that was used for the decomposition.
摘要翻译：一种制备羟基取代的有机化合物的方法，包括分解有机氢过氧化物，优选式Ar-C（CH 3）2 O 2 H的化合物，其中Ar是取代或未取代的单核或多核芳族基团。分解是在催化剂存在下进行的，该催化剂包含具有磺酸基的高度氟化聚合物，催化剂的颗粒形式为至少约20重量％，其颗粒尺寸小于约300μm。叔丁醇氢过氧化物可以在该方法中分解成苯酚和丙酮，其可以在与用于分解的相同催化剂存在下反应形成双酚A。

99. 发明授权

US06512153B1 Process for the alkylation of aromatic compounds 有权
标题翻译：芳族化合物的烷基化方法
公开(公告)号：US06512153B1
公开(公告)日：2003-01-28
申请号：US09612256
申请日：2000-07-07
申请人： Oscar Cappellazzo , Gianni Girotti , Massimiliano Pollastri , Sergio Lombardini , Domenico Piccininno
发明人： Oscar Cappellazzo , Gianni Girotti , Massimiliano Pollastri , Sergio Lombardini , Domenico Piccininno
IPC分类号： C07C266
CPC分类号： C07C409/10 , C07C2/864 , C07C39/04 , C07C45/53 , C07C407/00 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C15/02 , C07C49/08
摘要： Process for the alkylation of aromatic compounds by the reaction of the aromatic compound of interest with isopropanol, alone or mixed with propylene, wherein the reaction is carried out in the presence of a catalytic composition based on zeolite, under mixed gas-liquid phase conditions or under completely liquid phase conditions, at such temperature and pressures that the concentration of water in the reaction liquid phase is not higher than 8,000 ppm w/w, regardless of the total water content present in the reaction mixture.
摘要翻译：通过芳香族化合物与单独或与丙烯混合的异丙醇的反应使芳族化合物烷基化的方法，其中该反应在基于沸石的催化剂组合物存在下，在混合的气 - 液相条件下进行，或在完全液相条件下，在反应液相中水的浓度不高于8,000ppm w / w的温度和压力下，与反应混合物中存在的总水分无关。

100. 发明申请

US20030013837A1 Method for producing phosphonium phenolates 失效
标题翻译：苯酚酚盐生产方法
公开(公告)号：US20030013837A1
公开(公告)日：2003-01-16
申请号：US10168166
申请日：2002-06-17
发明人： Lothar Bunzel , Uwe Hucks , Annett Konig , Silke Kratschmer
IPC分类号： C08G002/00
CPC分类号： C08G64/30 , C07C37/00 , C07F9/54 , C07C39/04
摘要： The invention relates to a method for producing phosphonium phenolates from phosphonium halogenides and phenols.
摘要翻译：本发明涉及一种由卤化鏻和苯酚生产鏻苯酚盐的方法。

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