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    • 93. 发明申请
    • MERCURY REMOVAL SORBENTS
    • MERCURY移除SORBENTS
    • US20140274667A1
    • 2014-09-18
    • US13834266
    • 2013-03-15
    • TDA Research, Inc.
    • Gokhan Alptekin
    • B01J27/138B01J27/06
    • B01J37/04B01J20/0222B01J20/0237B01J20/041B01J20/046B01J20/08B01J20/103B01J20/12B01J20/28004B01J20/28057B01J27/08B01J27/10B01J27/128B01J27/132B01J35/002B01J35/1014B01J35/1019B01J37/22B01J37/24
    • Sorbents and methods of using them for removing mercury from flue gases over a wide range of temperatures are disclosed. Sorbent materials of this invention comprise oxy- or hydroxyl-halogen (chlorides and bromides) of manganese, copper and calcium as the active phase for Hg0 oxidation, and are dispersed on a high surface porous supports. In addition to the powder activated carbons (PACs), this support material can be comprised of commercial ceramic supports such as silica (SiO2), alumina (Al2O3), zeolites and clays. The support material may also comprise of oxides of various metals such as iron, manganese, and calcium. The non-carbon sorbents of the invention can be easily injected into the flue gas and recovered in the Particulate Control Device (PCD) along with the fly ash without altering the properties of the by-product fly ash enabling its use as a cement additive. Sorbent materials of this invention effectively remove both elemental and oxidized forms of mercury from flue gases and can be used at elevated temperatures. The sorbent combines an oxidation catalyst and a sorbent in the same particle to both oxidize the mercury and then immobilize it.
    • 公开了一种吸附剂和使用它们在宽范围的温度下从烟道气中去除汞的方法。 本发明的吸附剂材料包含锰,铜和钙的氧化或羟基 - 卤素(氯化物和溴化物)作为HgO氧化的活性相,并且分散在高表面多孔载体上。 除了粉末活性炭(PAC)之外,该载体材料可以由市售的陶瓷载体如二氧化硅(SiO 2),氧化铝(Al 2 O 3),沸石和粘土组成。 载体材料还可以包含各种金属如铁,锰和钙的氧化物。 本发明的非碳吸附剂可以容易地注入烟气中并与粉煤灰一起回收到颗粒控制装置(PCD)中,而不改变副产物飞灰的性质,使其能够用作水泥添加剂。 本发明的吸附剂材料有效地从烟道气中除去元素和氧化形式的汞,并且可以在高温下使用。 吸附剂将氧化催化剂和吸附剂结合在相同的颗粒中,以使氧化汞,然后固定。