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91. 发明授权

US3706647A Method of making cyclohexanol and cyclohexanone by oxidation of cyclohexane 失效
标题翻译：通过氧化环己酮制备环己烷和环己酮的方法
公开(公告)号：US3706647A
公开(公告)日：1972-12-19
申请号：US3706647D
申请日：1969-07-14
申请人： VICKERS ZIMMER AG
发明人： HARDUNG-HARDUNG HEIMO , CORSEPIUS HORST , HOFMANN HANSDIETER
IPC分类号： B01J19/08 , B01J19/24 , C07C29/50 , C07C45/33 , B01J1/10
CPC分类号： C07C29/50 , B01J19/081 , B01J19/243 , B01J19/245 , B01J2219/00094 , B01J2219/00159 , C07C45/33 , C07C2601/14 , C07C49/403 , C07C35/08
摘要： PROCESS FOR THE OXIDATION OF CYCLOHEXANE TO CYCLOHEXANOL AND CYCLOHEXANONE WHEREIN THE OXIDATION REACTION TAKES PLACE IN LIQUID PHASE IN THE PRESENCE OF IONIZING RAYS BELOW ABOUT 170*C. AND AT ELEVATED PRESSURE. IMPROVED YIELDS OF 86-88% IN A CONVERSION RANGE OF 5 TO 9% ARE OBTAINED.

92. 发明授权

US3627658A Lead compounds used to promote atomic radiation induced cross-linking in chlorinated olefin polymers 失效
标题翻译：用于促进原子辐射诱导氯化烯烃聚合物交联的铅化合物
公开(公告)号：US3627658A
公开(公告)日：1971-12-14
申请号：US3627658D
申请日：1970-01-09
申请人： DOW CHEMICAL CO
发明人： RYFFEL JAMES R
IPC分类号： B01J19/08 , C08K3/00 , C08K5/098 , B01J1/00 , C08F1/00
CPC分类号： C08K5/098 , B01J19/081 , C08K3/11 , C08L23/28
摘要： This invention pertains to cross-linking chlorinated olefin polymers and sheet materials with atomic radiation and to a means of promoting such cross-linking wherein from about one to 10 parts by weight of a lead compound selected from the group consisting of dibasic phosphites, dibasic phthalates, dibasic stearates, normal stearates, chlorostearates, ortho silicates, tribasic sulfates, tetrabasic fumarates and silicate-sulfates, is blended with the chlorinated olefin polymer prior to exposure thereof to atomic radiation.

93. 发明授权

US3531388A Method for promoting a chemical reaction with radioactive gas 失效
标题翻译：用放射性气体促进化学反应的方法
公开(公告)号：US3531388A
公开(公告)日：1970-09-29
申请号：US3531388D
申请日：1966-01-28
申请人： JAPAN ATOMIC ENERGY RES INST
发明人： KASAMATSU TOMOMICHI
IPC分类号： B01J19/00 , B01J19/08 , C01G49/00 , B01J1/10
CPC分类号： C01G49/00 , B01J19/00 , B01J19/081

94. 发明授权

US3457155A Process for preparing sulfonic acids 失效
公开(公告)号：US3457155A
公开(公告)日：1969-07-22
申请号：US3457155D
申请日：1966-04-28
申请人： HOECHST AG
发明人： ROSINGER SIGURD
IPC分类号： B01J19/08 , C07C309/04 , B01J1/10
CPC分类号： C07C303/14 , B01J19/081 , C07C309/04 , C07C309/25

95. 发明授权

US3228849A Utilization of nuclear fission for chemical reactions 失效
标题翻译：利用核裂变进行化学反应
公开(公告)号：US3228849A
公开(公告)日：1966-01-11
申请号：US2412460
申请日：1960-04-22
申请人： SOCONY MOBIL OIL CO INC
发明人： FELLOWS ALBERT T
IPC分类号： B01J19/08 , B01J37/34 , C01B3/34 , C01B32/40 , C01C1/04 , C07C2/00 , C07C5/27 , C07C51/353 , C10G15/10 , C10G35/16 , C10G49/00 , G21C3/04 , G21C3/06 , G21C3/28 , G21C3/62 , G21C3/64 , G21C9/00 , G21D9/00
CPC分类号： G21D9/00 , B01J19/081 , B01J37/34 , C01B3/342 , C01B32/40 , C01C1/0494 , C07C2/00 , C07C5/27 , C07C51/353 , C10G15/10 , C10G35/16 , C10G49/00 , C10G49/002 , G21C3/044 , G21C3/06 , G21C3/28 , G21C3/626 , G21C3/64 , G21C9/00 , Y02E30/37 , Y02E30/38 , Y02P20/582 , Y10S204/90 , Y10S204/904 , Y10S204/905 , Y10S376/901 , Y10S376/903 , Y10S376/904 , C07C55/02
摘要： 970, 864. Reactors. SOCONY MOBIL OIL CO. Inc. Oct.28, 1960 [Oct.29, 1959; Oct. 30, 1959; April 22, 1960 (3)]. No. 37213/60. Heading G6C. In a nuclear reactor, the recoil energy of nuclear fission fragments is used to effect chemical reactions. The fission process may be either sustained by an external neutron source or be selfsustaining. The fission fragments are retained within the reactor to prevent contamination of the chemical conversion products. Temperature control of the process is effected either by the circulation of a coolent or by the removal of heat by the flow of the chemical reactants. The latter may act as a moderator for the fission process or a solid moderator may be introduced. As shown, Fig. 1, the vessel 10 contains a non-self-sustaining reactor for effecting the required chemical reaction on the fluids passed through the vessel by the pipes 66, 67. To maintain fission reaction, reactors are supplied from an outside source, not shown. Fluid chemical conversion products are passed from separator 68 to heat exchanger 78 to recovery system 83 from which the reactants are recycled by pump 65. The bars 100 in 10 may consist of enriched uranium oxide contained in particles of microporous alumina. Reactant hydrogen and the alumina functions as a moderator but carbon particles may be added. A coolant fluid is circulated round the space 25, for example, heavy water, molten bismuth or sodium, biphenyl, or a mixture of sodium nitrate, sodium nitrite and potassium nitrate. The fluid is passed through the heat exchanger 29 by the pump 28. The fission material is supplied from hopper 35 and passes the concrete shield 23, steel sheet 22 and graphite blocks 12 by conduit 34. Discharge is effected through 46 to the tank 47. Lock chambers 53, 90 are filled with an inert gas such as helium, carbon dioxide. The neutron flux in vessel 10 is controllable by the rods 111, 112 of boron or cadmium. The alumina particles are arranged so as to retain the fission fragments within the body of each particle and the gaseous fragments diffuse out. The particles are porous and may also be formed of siliceous earth, ceramic materials in gels of silica..The capture cross-section of the particles for thermal neutrons is below 10 barns and a catalyst may be added such as platinum or nickel. In a second embodiment, not shown, the fission reaction is self sustaining. The fluids to be reacted upon by the neutron flux pass downwards through the fission material to permit a higher velocity through the device without disturbance of the fission material. Control may be effected by adjustable rods of fissionable material. Examples of the chemical reactions effected by the arrangement and the conversion of methanol to diethylene glycol, ethanolhexane to butanediols, nitrogen and oxygen to their oxides, nitrogen and hydrogen to ammonia, carbon monoxide and hydrogen to methane, methane to hydrogen. In addition dehydrogenation, aromatization and dealkylation of hydrocarbons may be effected. U.S.A Specifications 2,384,941, 2,580,429, 2,580,806 and 2,856,367 are referred to.

96. 发明授权

US3130067A Process for electrostatically coating nonconductive articles 失效
标题翻译：用于静电涂覆非导电制品的方法
公开(公告)号：US3130067A
公开(公告)日：1964-04-21
申请号：US82376959
申请日：1959-06-29
申请人： DUNLOP RUBBER CO
发明人： DOUGLAS BULGIN
IPC分类号： B01J19/08 , B05B5/025 , B05B5/08 , B05D1/04 , B05D5/06 , C08F2/54
CPC分类号： B05D5/061 , B01J19/081 , B05B5/025 , B05B5/08 , B05D1/045

97. 发明授权

US3071524A Reaction of olefins by radiation 失效
标题翻译：通过辐射反应烯烃
公开(公告)号：US3071524A
公开(公告)日：1963-01-01
申请号：US64964557
申请日：1957-04-01
申请人： EXXON RESEARCH ENGINEERING CO
发明人： SCHUTZE HENRY G , SUTTLE JR ANDREW D
IPC分类号： B01J19/08 , C07C5/25 , C07C209/02
CPC分类号： C07C209/02 , B01J19/081 , C07C5/25 , Y02P20/582 , C07C11/08

98. 发明授权

US3006833A Process for the photochemical chlorination of benzene 失效
标题翻译：苯的光化学氯化方法
公开(公告)号：US3006833A
公开(公告)日：1961-10-31
申请号：US37796353
申请日：1953-09-01
申请人： HOOKER CHEMICAL CORP
发明人： MAUDE AYLMER H , BHAGWAT MADHAV R , LISMAN CARSON E , ROSENBERG DAVID S
IPC分类号： B01J19/08 , B01J19/12 , C07C17/02
CPC分类号： B01J19/122 , B01J19/081 , C07C17/02 , C07C23/12

99. 发明授权

US3003964A Radiochemical production of phosphosulfurized hydrocarbons 失效
标题翻译：磷硫化烃的放射化学生产
公开(公告)号：US3003964A
公开(公告)日：1961-10-10
申请号：US41347854
申请日：1954-03-01
申请人： EXXON RESEARCH ENGINEERING CO
发明人： GUTHRIE DONALD A , KNAPP JR CARROLL L
IPC分类号： B01J19/08 , C07F9/04
CPC分类号： C07F9/04 , B01J19/081

100. 发明授权

US2976422A Apparatus for irradiating chemical reactions 失效
标题翻译：用于照射化学反应的装置
公开(公告)号：US2976422A
公开(公告)日：1961-03-21
申请号：US36897253
申请日：1953-07-20
申请人： EXXON RESEARCH ENGINEERING CO
发明人： HILL MAX W , BLACK JAMES F
IPC分类号： B01J19/08
CPC分类号： B01J19/081 , Y10S204/90

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