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    • 92. 发明授权
    • Dry low k film application for interlevel dielectric and method of cleaning etched features
    • 干燥低k膜应用于层间电介质和清洗蚀刻特征的方法
    • US06573175B1
    • 2003-06-03
    • US09998729
    • 2001-11-30
    • Zhiping YinGary Chen
    • Zhiping YinGary Chen
    • H01L214763
    • H01L21/76814H01L21/02063H01L21/0276H01L21/31111H01L21/31116H01L21/31633H01L21/76802H01L21/76807
    • Methods of selectively removing post-etch polymer material and dielectric antireflective coatings (DARC) without substantially etching an underlying carbon-doped low k dielectric layer, and compositions for the selective removal of a DARC layer and post-etch polymer material are provided. A composition comprising trimethylammonium fluoride is used to selectively etch a dielectric antireflective coating layer overlying a low k dielectric layer at an etch rate of the antireflective coating layer to the low k dielectric layer that is greater than the etch rate of the antireflective coating to a TEOS layer. The method and composition are useful, for example, in the formation of high aspect ratio openings in low k (carbon doped) silicon oxide dielectric layers and maintaining the integrity of the dimensions of the formed openings during a cleaning step to remove a post-etch polymer and antireflective coating.
    • 提供了选择性地去除蚀刻后聚合物材料和介电抗反射涂层(DARC)而不基本上蚀刻下面的掺碳低k电介质层的方法,以及用于选择性去除DARC层和蚀刻后聚合物材料的组合物。 使用包含三甲基氟化铵的组合物以抗反射涂层到低k电介质层的蚀刻速率选择性地蚀刻覆盖低k电介质层的电介质抗反射涂层,其大于抗反射涂层对TEOS的蚀刻速率 层。 该方法和组合物可用于例如在低k(碳掺杂)氧化硅介电层中形成高纵横比的开口,并且在清洁步骤期间保持形成的开口的尺寸的完整性以去除蚀刻后 聚合物和抗反射涂层。
    • 93. 发明授权
    • Method of reducing defects in anti-reflective coatings and semiconductor structures fabricated thereby
    • 减少由此制成的抗反射涂层和半导体结构中的缺陷的方法
    • US06461970B1
    • 2002-10-08
    • US09095477
    • 1998-06-10
    • Zhiping Yin
    • Zhiping Yin
    • H01L21302
    • H01L23/5329H01L21/0276H01L21/3145H01L2924/0002Y10S438/905H01L2924/00
    • A method of fabricating a substantially smooth-surfaced anti-reflective coating on a semiconductor device structure including generating a plasma from an inert gas in a process chamber in which the substantially smooth anti-reflective coating is to be deposited. The anti-reflective coating may be a dielectric anti-reflective coating (DARC) which includes silicon, oxygen and nitrogen, and is preferably of the general formula SixOyNz, where x equals 0.40 to 0.65, y equals 0.02 to 0.56 and z equals 0.05 to 0.33. Preferably, x+y+z equals one. The method may also include fabricating a silicon nitride layer over the anti-reflective coating. A semiconductor device which includes a silicon nitride layer over an anti-reflective coating that has been fabricated in accordance with the inventive method has a density of less than about 40,000 particles or surface roughness features in the silicon nitride of about 120-150 nanometers dimension per eight inch wafer. Accordingly, a mask that is subsequently formed over the silicon nitride layer has a substantially uniform thickness and is substantially distortion-free.
    • 一种在半导体器件结构上制造基本上光滑表面的抗反射涂层的方法,包括在其中沉积基本上平滑的抗反射涂层的处理室中的惰性气体产生等离子体。 抗反射涂层可以是包括硅,氧和氮的电介质抗反射涂层(DARC),并且优选为通式SixOyNz,其中x等于0.40至0.65,y等于0.02至0.56,z等于0.05至 0.33。 优选地,x + y + z等于1。 该方法还可以包括在抗反射涂层上制造氮化硅层。 在根据本发明方法制造的抗反射涂层上包括氮化硅层的半导体器件具有小于约40,000个颗粒的密度或氮化硅中的表面粗糙度特征,其尺寸为约120-150纳米 八寸晶圆。 因此,随后在氮化硅层上形成的掩模具有基本均匀的厚度并且基本上无变形。
    • 96. 发明授权
    • Semiconductor devices having antireflective material
    • 具有抗反射材料的半导体器件
    • US07626238B2
    • 2009-12-01
    • US11218045
    • 2005-08-31
    • Richard HolscherZhiping YinTom Glass
    • Richard HolscherZhiping YinTom Glass
    • H01L31/0232
    • H01L21/0276G03F7/091H01L21/3086Y10S430/151
    • In one aspect, the invention includes a semiconductor processing method. An antireflective material layer is formed over a substrate. At least a portion of the antireflective material layer is annealed at a temperature of greater than about 400° C. A layer of photoresist is formed over the annealed antireflective material layer. The layer of photoresist is patterned. A portion of the antireflective material layer unmasked by the patterned layer of photoresist is removed. In another aspect, the invention includes the following semiconductor processing. An antireflective material layer is formed over a substrate. The antireflective material layer is annealed at a temperature of greater than about 400° C. A layer of photoresist is formed over the annealed antireflective material layer. Portions of the layer of photoresist are exposed to radiation waves. Some of the radiation waves are absorbed by the antireflective material during the exposing.
    • 一方面,本发明包括半导体处理方法。 在基板上形成防反射材料层。 抗反射材料层的至少一部分在大于约400℃的温度下退火。在退火的抗反射材料层上形成一层光致抗蚀剂。 图案化光刻胶层。 除去由图案化的光致抗蚀剂层掩蔽的抗反射材料层的一部分。 另一方面,本发明包括以下半导体处理。 在基板上形成防反射材料层。 抗反射材料层在大于约400℃的温度下退火。在退火的抗反射材料层上形成一层光致抗蚀剂。 光致抗蚀剂层的一部分暴露于辐射波。 一些辐射波在曝光期间被抗反射材料吸收。
    • 99. 发明申请
    • PREVENTION OF PHOTORESIST SCUMMING
    • 防止光电子扫描
    • US20080008942A1
    • 2008-01-10
    • US11856556
    • 2007-09-17
    • Zhiping YinJingyi Bai
    • Zhiping YinJingyi Bai
    • G03F1/00
    • G03F7/11G03F7/0045G03F7/091
    • A photo acid generator (PAG) or an acid is used to reduce resist scumming and footing. Diffusion of acid from photoresist into neighbors causes a decreased acid level, and thus causes resist scumming. An increased acid layer beneath the resist prevents acid diffusion. In one embodiment, the increased acid layer is a layer of spun-on acid or PAG dissolved in aqueous solution. In another embodiment, the increased acid layer is a hard mask material with a PAG or an acid mixed into the material. The high acid content inhibits the diffusion of acid from the photoresist into neighboring layers, and thus substantially reduces photoresist scumming and footing.
    • 使用光酸产生剂(PAG)或酸来降低抗污垢和基底。 酸从光致抗蚀剂扩散到邻居会导致酸水平降低,从而导致抗污垢浮渣。 抗蚀剂下面的增加的酸层防止酸扩散。 在一个实施方案中,增加的酸层是溶解在水溶液中的纺丝酸或PAG层。 在另一个实施方案中,增加的酸层是具有混合到该材料中的PAG或酸的硬掩模材料。 高酸含量抑制酸从光致抗蚀剂扩散到相邻层中,从而基本上减少光致抗蚀剂的浮渣和基底。