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91. 发明授权

US06737556B2 Method and system for reducing decomposition byproducts in a methanol to olefin reactor system 有权
公开(公告)号：US06737556B2
公开(公告)日：2004-05-18
申请号：US10274739
申请日：2002-10-21
申请人： Jeffrey P. Jones , Kenneth Ray Clem , Stephen N. Vaughn , Teng Xu , Jeffrey L. White
发明人： Jeffrey P. Jones , Kenneth Ray Clem , Stephen N. Vaughn , Teng Xu , Jeffrey L. White
IPC分类号： C07C1207
CPC分类号： C22C19/05 , B01J4/002 , B01J19/02 , B01J19/26 , B01J2219/00119 , B01J2219/00155 , B01J2219/00252 , B01J2219/0218 , B01J2219/0236 , C07C1/20 , C22C19/058 , C22C30/00 , C22C38/02 , C22C38/04 , C22C38/06 , C22C38/50 , Y02P30/42 , Y10S585/92 , Y10S585/923 , C07C11/02
摘要： Disclosed is a method and system for reducing the formation of metal catalyzed side-reaction byproducts formed in the feed vaporization and introduction system of a methanol to olefin reactor system by forming and/or coating one or more of the heating devices, feed lines or feed introduction nozzles of/with a material that is resistant to the formation of metal catalyzed side reaction byproducts. The invention also may include monitoring and/or maintaining the temperature of at least a portion of the feed vaporization and introduction system and/or of the feedstock contained therein below about 400° C., 350° C., 300° C., 250° C., 200° C. or below about 150° C. The temperature can be maintained in the desired range by jacketing at least a portion of the feed vaporization and introduction system, such as at least a portion of the feed introduction nozzle, with a thermally insulating material or by implementing a cooling system.

92. 发明授权

US06552240B1 Method for converting oxygenates to olefins 有权
标题翻译：将含氧物转化为烯烃的方法
公开(公告)号：US06552240B1
公开(公告)日：2003-04-22
申请号：US09708753
申请日：2000-11-08
申请人： James R. Lattner , Stephen N. Vaughn , Keith H. Kuechler , David C. Skouby , Hsiang-Ning Sun
发明人： James R. Lattner , Stephen N. Vaughn , Keith H. Kuechler , David C. Skouby , Hsiang-Ning Sun
IPC分类号： C07C170
CPC分类号： C10G3/60 , B01J29/85 , B01J29/90 , B01J38/30 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/62 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/20 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention provides a method for converting a feed containing oxygenates to olefins and comprises the following steps: providing a feed including an oxygenate; contacting the feed in a reactor apparatus with a catalyst including a molecular sieve, the contacting taking place under conditions effective to convert the oxygenate to a product including a light olefin, the conditions including a gas superficial velocity of at least two meters per second at least one point in the reaction zone; and recirculating a first portion of the catalyst to recontact the feed.
摘要翻译：本发明提供一种将含有含氧物的进料转化为烯烃的方法，包括以下步骤：提供包含含氧化合物的进料; 使反应器装置中的进料与包含分子筛的催化剂接触，在有效地将含氧化合物转化为包含轻质烯烃的产物的条件下进行接触，所述条件至少包括至少两米/秒的气体表观速度至少反应区一点; 并再循环催化剂的第一部分以重新进料。

93. 发明授权

US06482999B2 Method for improving light olefin selectivity in an oxygenate conversion reaction 有权
标题翻译：改善含氧化合物转化反应中轻烯烃选择性的方法
公开(公告)号：US06482999B2
公开(公告)日：2002-11-19
申请号：US09251142
申请日：1999-02-17
申请人： Shun C. Fung , James R. Lattner , Stephen N. Vaughn , Richard B. Hall , Hsiang-Ning Sun , Ron G. Searle , Luc R. M. Martens
发明人： Shun C. Fung , James R. Lattner , Stephen N. Vaughn , Richard B. Hall , Hsiang-Ning Sun , Ron G. Searle , Luc R. M. Martens
IPC分类号： C07C1207
CPC分类号： B01J38/12 , B01J29/04 , B01J29/85 , B01J29/90 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/50 , C10G3/57 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y10S585/905 , Y10S585/906 , C07C11/02
摘要： A method for converting oxygenates to light olefins. The method comprises contacting, in a reactor, a feedstock comprising oxygenates with a molecular sieve catalyst under conditions effective to convert the feedstock to a product including light olefins and by-products, the contacting causing carbonaceous deposits to form on at least a portion of the molecular sieve catalyst producing deactivated catalyst; removing a portion of the deactivated catalyst from the reactor; regenerating the portion of the deactivated catalyst under conditions effective to remove at least a portion of the carbonaceous deposits from the deactivated catalyst to form an at least partially regenerated catalyst; exposing at least a portion of the at least partially regenerated catalyst to at least a portion of the by-products to selectivate the portion of the at least partially regenerated catalyst to form light olefins; and contacting the selectivated portion of the at least partially regenerated catalyst with the feedstock to form the product.
摘要翻译：将含氧物转化为轻质烯烃的方法。该方法包括在反应器中将包含含氧化合物的原料与分子筛催化剂在有效将原料转化为包含轻质烯烃和副产物的产物的条件下接触，使得碳质沉积物形成在至少一部分分子筛催化剂产生失活催化剂; 从反应器中除去一部分失活的催化剂; 在有效地从失活的催化剂除去至少一部分碳质沉积物以形成至少部分再生的催化剂的条件下，使失活催化剂的部分再生; 将所述至少部分再生的催化剂的至少一部分暴露于所述副产物的至少一部分以选择所述至少部分再生催化剂的所述部分以形成轻质烯烃; 并使至少部分再生的催化剂的选定部分与原料接触以形成产物。

94. 发明授权

US06395674B1 Heat treating a molecular sieve and catalyst 有权
公开(公告)号：US06395674B1
公开(公告)日：2002-05-28
申请号：US09399675
申请日：1999-09-21
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
IPC分类号： B01J27182
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.

95. 发明授权

US5453561A Reactive separation process 失效
标题翻译：反应分离过程
公开(公告)号：US5453561A
公开(公告)日：1995-09-26
申请号：US187673
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
发明人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
IPC分类号： B01D17/025 , C07C7/148 , C07C11/02 , C07C29/10 , C10G50/00 , C07C7/00
CPC分类号： C07C29/10 , C07C7/148
摘要： The invention concerns a method for reactive separation of mixtures containing hydrocarbons and oxygenated hydrocarbons, by contacting a mixture of hydrocarbons such as C.sub.2 to C.sub.26 hydrocarbons and mixtures thereof and oxygenated hydrocarbons, such as C.sub.2 to C.sub.40 oxygenated hydrocarbons and mixtures thereof to form a mixture of hydrocarbons and lower molecular weight oxygenated hydrocarbons and heating the mixture in water at temperature typically from about and pressure sufficient to cleave the oxygenated hydrocarbons to lower molecular weight products to form a liquid layer containing water soluble reaction products and an organic layer containing primarily hydrocarbons.
摘要翻译：本发明涉及通过使烃类混合物例如C 2至C 26烃及其混合物和含氧烃如C2至C40含氧烃及其混合物的混合物与烃和氧化烃的混合物进行反应分离的方法，以形成混合物碳氢化合物和较低分子量的氧化烃，并将混合物在水中加热，其温度通常为足以将氧化烃切割成较低分子量产物的温度，形成含有水溶性反应产物和主要含有烃的有机层的液体层。

96. 发明授权

US5043486A Aquathermolytic cleavage of ethers 失效
标题翻译：醚水解裂解
公开(公告)号：US5043486A
公开(公告)日：1991-08-27
申请号：US572485
申请日：1990-08-23
申请人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
发明人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
IPC分类号： C07C29/10 , C07C31/02 , C07C31/10 , C07C31/12
CPC分类号： C07C29/10
摘要： The present invention provides for a simplified process for converting ethers into their corresponding alcohols comprising forming an aqueous mixture of the ether and at least about 50% by weight water and heating the mixture under autogeneous pressure at a temperature of from about 250.degree. to 450.degree. C., more preferably from about 250.degree. C. up to the critical temperature of water which is about 374.degree. C. Heating is continued for a period of time sufficient to convert at least about 20% by weight of the ether, usually from about 5 up to about 120 minutes, depending on temperature and the amount of water present, and the identity of the starting ether feedstock.The process may be characterized as an aquathermolysis reaction wherein the reaction proceeds in water primarily through ionic routes rather than through free radical routes. Accordingly, relatively high conversion rates and good yields of alcohol and other reaction by-products may be obtained without the necessity of using a catalyst in the process.
摘要翻译：本发明提供了将醚转化成其相应的醇的简化方法，包括形成醚的水性混合物和至少约50重量％的水，并在约250-450℃的温度下在自主压力下加热混合物更优选约250℃至约374℃的水的临界温度。继续加热足够的时间以使至少约20重量％的乙醚转化成通常为约 5至约120分钟，这取决于温度和存在的水的量以及起始醚原料的特性。该方法可以表征为水解溶解反应，其中反应在水中主要通过离子路线而不是通过自由基途径进行。因此，可以获得醇和其它反应副产物的相对高的转化率和良好的产率，而不需要在该方法中使用催化剂。

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