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    • 96. 发明授权
    • 1-aryltriazolin(ethi)ones
    • 1-芳基三唑啉(ethi)
    • US5476946A
    • 1995-12-19
    • US190813
    • 1994-02-02
    • Karl-Heinz LinkerKurt FindeisenWilhelm HaasOtto SchallnerMarkus DollingerHans-Joachim Santel
    • Karl-Heinz LinkerKurt FindeisenWilhelm HaasOtto SchallnerMarkus DollingerHans-Joachim Santel
    • A01N43/653A01N43/84A01N53/10A01N55/10A01N57/32C07D249/12C07D249/14C07D401/10C07D401/12C07D403/12C07D405/10C07D405/12C07F9/02
    • C07D401/12A01N43/653C07D249/14C07D403/12C07D405/12
    • The invention relates to new 1-aryltriazolin(ethi)ones of the general formula (I) ##STR1## in which R.sup.1 represents nitro or represents a radical --NR.sup.8 R.sup.9,R.sup.2 represents hydrogen, amino or cyano, or represents one of the radicals --R.sup.10, --O--R.sup.10, --S--R.sup.10, --NR.sup.10 R.sup.11, --N(R.sup.11)--CO--R.sup.10 or --N.dbd.CR.sup.10 R.sup.11,R.sup.3, R.sup.6 and R.sup.7 independently of one another each represent hydrogen, halogen or nitro,R.sup.4 represents hydrogen, halogen, cyano or nitro, or represents one of the radicals --R.sup.12, --O--R.sup.12, --S--R.sup.12, --S(O)--R.sup.12, --SO.sub.2 --R.sup.12, --SO--OR.sup.12, --SO--NR.sup.11 R.sup.12, --CO--OR.sup.12, --CO--NR.sup.11 R.sup.12, --O--SO.sub.2 --R.sup.12, --N(R.sup.11)--SO.sub.2 --R.sup.12, --NR.sup.11 R.sup.12, --NH--P(O)(R.sup.11)(OR.sup.12) or --NH--P(O)(OR.sup.11)(OR.sup.12),R.sup.5 represents nitro, cyano, halogen or halogenoalkyl, andX represents oxygen or sulphur, whereR.sup.8 and R.sup.9 independently of one another each represent hydrogen or represent in each case optionally substituted alkyl, alkenyl, alkinyl, alkoxy, cycloalkyl, aryl or heterocyclyl, or represent, together with the nitrogen atom to which they are attached, an optionally substituted heterocycle,R.sup.10 represents in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aryl, arylalkyl or heterocyclyl,R.sup.11 represents hydrogen or represents in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, arylalkyl or aryl, andR.sup.12 represents hydrogen or represents in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, aryl or heterocyclyl,to a number of processes for their preparation, to a number of new intermediates, and to their use as herbicides.
    • 本发明涉及通式(Ⅰ)的新的1-芳基三唑啉(ethi),其中R 1表示硝基或代表基团-NR 8 R 9,R 2代表氢,氨基或氰基,或代表 基团-R 10,-O-R 10,-S-R 10,-NR 10 R 11,-N(R 11)-CO-R 10或-N = CR 10 R 11,R 3,R 6和R 7彼此独立地表示氢,卤素或硝基,R 4 表示氢,卤素,氰基或硝基,或表示基团-R12,-O-R12,-S-R12,-S(O)-R12,-SO2-R12,-SO-OR12,-SO-NR11R12 ,-CO-OR12,-CO-NR11R12,-O-SO2-R12,-N(R11)-SO2-R12,-NR11R12,-NH-P(O)(R11)(OR12)或-NH-P O)(OR 11)(OR 12),R 5表示硝基,氰基,卤素或卤代烷基,X表示氧或硫,其中R 8和R 9彼此独立地表示氢或表示任意取代的烷基,烯基,炔基, 烷氧基,环烷基,芳基或杂环基,或与它们所连接的氮原子一起代表任选的 R 10代表任意取代的烷基,烯基,炔基,环烷基,芳基,芳基烷基或杂环基,R 11表示氢或在各种情况下表示任选取代的烷基,烯基,炔基,环烷基,芳基烷基或芳基,R 12表示氢 或在各种情况下表示任选取代的烷基,烯基,炔基,环烷基,芳基或杂环基,其多种制备方法,多种新中间体及其作为除草剂的用途。
    • 100. 发明授权
    • 1-arylpyrazoles, compositions and use
    • 1-芳基吡唑,组合物和用途
    • US4936892A
    • 1990-06-26
    • US220034
    • 1988-07-15
    • Reinhold GehringOtto SchallnerJorg StetterAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenHarry Strang
    • Reinhold GehringOtto SchallnerJorg StetterAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenHarry Strang
    • A01N43/56A01N47/18A01N47/36C07D231/38C07D231/40
    • C07D231/38A01N43/56A01N47/18A01N47/36C07D231/40
    • A 1-arylpyrazole of the formula (I) ##STR1## in which R.sup.1 stands for hydrogen or nitro,R.sup.2 stands for hydrogen, for a radical ##STR2## or a radical --S(O).sub.n --R.sup.5, R.sup.3 stands for alkyl, for a radical ##STR3## or for a radical --S(O).sub.n --R.sup.5, and, in addition, in the case where R.sup.2 stands for a radical --SO.sub.2 --R.sup.5, R.sup.3 alternatively stands for an inorganic or organic cation bonded in the manner of a salt,whereR.sup.4 stands for hydrogen, alkyl, alkenyl, alkinyl, monohalogenoalkyl, alkoxyalkyl, halogenoalkoxyalkyl, alkylthioalkyl, alkoxy, alkylthio, alkylsulphonylalkyl, alkylsulphinylalkyl, alkylamino, dialkylamino, optionally substituted cycloalkyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, or for optionally substituted arylamino,X stands for oxygen or sulphur,R.sup.5 stands for alkyl, halogenoalkyl or for optionally substituted aryl,n stands for a number 0, 1 or 2, andAr stands for one of the radicals ##STR4## wherein A.sup.1 stands for hydrogen, fluorine or chlorine,A.sup.2 stands for fluorine or chlorine andA.sup.3 stands for hydrogen or fluorine, but excluding the compounds 5-ethoxycarbonylamino-1-(2,3-dichloro-4-trifluoromethylphenyl)-4-nitro- pyrazol and 5-acetamido-1-2,5-difluoro-4-trifluoromethylphenyl)-pyrazole. Such 1-arylpyrazoles are useful as herbicides and as plant growth-regulating agents.
    • 式(I)的1-芳基吡唑其中R1代表氢或硝基,R2代表氢,对于基团“基团”或基团-S(O)n -R5,R3代表 对于烷基,对于基团-Si(O)n -R 5,并且另外,在R 2表示-SO 2 -R 5基团的情况下,R 3代表无机或有机阳离子 其中R4代表氢,烷基,烯基,炔基,一卤代烷基,烷氧基烷基,卤代烷氧基烷基,烷硫基烷基,烷氧基,烷硫基,烷基磺酰基烷基,烷基亚磺酰基烷基,烷基氨基,二烷基氨基,任选取代的环烷基,任选取代的芳基, 芳氧基,任选取代的芳硫基或任选取代的芳基氨基,X代表氧或硫,R5代表烷基,卤代烷基或任选取代的芳基,n代表0,1或2,Ar代表一个基团 其中A1代表氢,氟 ne或氯,A2代表氟或氯,A3代表氢或氟,但不包括5-乙氧基羰基氨基-1-(2,3-二氯-4-三氟甲基苯基)-4-硝基 - 吡唑和5-乙酰胺基 - -1,5-二氟-4-三氟甲基苯基) - 吡唑。 这种1-芳基吡唑可用作除草剂和作为植物生长调节剂。