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91. 发明授权

US06399739B1 Preparation of polycarbonate having a predetermined molecular weight and level of endcapping 有权
标题翻译：具有预定分子量和封端水平的聚碳酸酯的制备
公开(公告)号：US06399739B1
公开(公告)日：2002-06-04
申请号：US09934929
申请日：2001-08-22
申请人： Patrick Joseph McCloskey , Alberto Nisoli , Warren William Reilly
发明人： Patrick Joseph McCloskey , Alberto Nisoli , Warren William Reilly
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： A melt method of preparing polycarbonate having a predetermined number average molecular weight and percent endcapping is described. A computerized process model is used to determine the reaction parameters to be employed in order to furnish the product polycarbonate possessing the desired Mn and %EC. Reaction parameters of importance include a suitable starting molar ratio of diaryl carbonate to dihydroxy aromatic compound, the most appropriate reaction time, reaction temperature and pressure ranges. The target polycarbonate is then prepared using reaction parameters indicated by the process model in a reactor which forms an element of the process model. Characteristics of the reactor which may be included in the process model include agitation rate and reflux ratio during the distillative removal of hydroxy aromatic compound formed as a by-product during the polymerization.
摘要翻译：描述了制备具有预定数均分子量和百分比封端的聚碳酸酯的熔融方法。使用计算机化过程模型来确定要使用的反应参数，以便提供具有期望的Mn和％EC的产物聚碳酸酯。重要的反应参数包括碳酸二芳基酯与二羟基芳族化合物的合适起始摩尔比，最合适的反应时间，反应温度和压力范围。然后使用形成过程模型元素的反应器中由过程模型指示的反应参数制备目标聚碳酸酯。可以包括在过程模型中的反应器的特征包括在蒸馏除去在聚合期间作为副产物形成的羟基芳族化合物的搅拌速率和回流比。

92. 发明授权

US06376640B1 Melt polycarbonate catalyst systems 失效
标题翻译：熔融聚碳酸酯催化剂体系
公开(公告)号：US06376640B1
公开(公告)日：2002-04-23
申请号：US09760100
申请日：2001-01-12
申请人： John Patrick Lemmon , Patrick Joseph McCloskey , Oltea Puica Siclovan
发明人： John Patrick Lemmon , Patrick Joseph McCloskey , Oltea Puica Siclovan
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： This invention provides a method for preparing polycarbonates, which utilizes polycondensation catalysts of the formula Cs+An−, wherein An− represents anions such as CH3SO3−, NH2SO3−, C2H2O4−, BF4−, B(C6H5CH3)4−, and CH3C6H4SO3−. We have found that this new class of catalysts provides excellent polymerization rates for the preparation of Bisphenol A polycarbonate from the melt polymerization of diphenyl carbonate and Bisphenol A. Moreover, the catalysts of the invention were found to be very selective in substantially reducing the level of branching side reaction, i.e., formation of Fries product, normally associated with the melt polycarbonate process.
摘要翻译：本发明提供一种制备聚碳酸酯的方法，该方法采用式为Cs + An-的缩聚催化剂，其中An-表示阴离子如CH 3 SO 3 - ，NH 2 SO 3 - ，C 2 H 2 O 4 - ，BF 4 - ，B（C 6 H 5 CH 3）4 - 和CH 3 C 6 H 4 SO 3 - 。我们已经发现，这种新型催化剂由于碳酸二苯酯和双酚A的熔融聚合而提供了用于制备双酚A聚碳酸酯的优异的聚合速率。此外，发现本发明的催化剂在显着降低分支侧反应，即通常与熔融聚碳酸酯方法相关的Fries产物的形成。

93. 发明授权

US06323304B1 Melt polycarbonate catalyst systems 有权
标题翻译：熔融聚碳酸酯催化剂体系
公开(公告)号：US06323304B1
公开(公告)日：2001-11-27
申请号：US09760086
申请日：2001-01-12
申请人： John Patrick Lemmon , Patrick Joseph McCloskey , Oltea Puica Siclovan
发明人： John Patrick Lemmon , Patrick Joseph McCloskey , Oltea Puica Siclovan
IPC分类号： C08G6378
CPC分类号： C08G64/307
摘要： This invention provides a method for preparing polycarbonates, which utilizes polycondensation catalysts of the formula Ax+MF6−x, wherein A is an alkali metal or alkaline earth cation; M is a transition metal of group IVA or VA, or M is a p-block metal of group IIIB, IVB or VB; and x is 1, 2, or 3. We have found that this new class of catalysts provide excellent polymerization rates for the preparation of Bisphenol A polycarbonate from the melt polymerization of diphenyl carbonate and Bisphenol A. Moreover, the catalysts of the invention were found to be very selective in substantially reducing the level of branching side reaction, i.e., formation of Fries product, normally associated with the melt polycarbonate process.
摘要翻译：本发明提供一种制备聚碳酸酯的方法，其使用式Ax + MF6-x的缩聚催化剂，其中A为碱金属或碱土金属阳离子; M是IVA或VA族的过渡金属，或M是IIIB，IVB或VB族的p型金属; 我们已经发现，这种新型催化剂从碳酸二苯酯和双酚A的熔融聚合制备双酚A聚碳酸酯提供了极好的聚合速率。此外，发现了本发明的催化剂在大大降低支化反应的水平方面非常有选择性，即通常与熔融聚碳酸酯方法相关的Fries产物的形成。

94. 发明授权

US06303737B1 Melt polycarbonate catalyst systems 有权
标题翻译：熔融聚碳酸酯催化剂体系
公开(公告)号：US06303737B1
公开(公告)日：2001-10-16
申请号：US09760101
申请日：2001-01-12
申请人： John Patrick Lemmon , Patrick Joseph McCloskey , Ronald James Wroczynski
发明人： John Patrick Lemmon , Patrick Joseph McCloskey , Ronald James Wroczynski
IPC分类号： C08G6302
CPC分类号： C08G64/307
摘要： This invention provides a method for preparing polycarbonates, which utilizes polycondensation catalysts which are salts of certain phenanthroline compounds. We have found that this new class of catalysts provide excellent polymerization rates for the preparation of Bisphenol A polycarbonate from the melt polymerization of diphenyl carbonate and Bisphenol A. Moreover, the catalysts of the invention were found to be very selective in substantially reducing the level of branching side reaction, i.e., formation of Fries product, normally associated with the melt polycarbonate process.
摘要翻译：本发明提供一种制备聚碳酸酯的方法，该方法利用作为某些菲咯啉化合物的盐的缩聚催化剂。我们已经发现，这种新类型的催化剂从碳酸二苯酯和双酚A的熔融聚合制备双酚A聚碳酸酯提供了极好的聚合速率。此外，发现本发明的催化剂在显着降低分枝反应，即通常与熔融聚碳酸酯工艺相关的Fries产品的形成。

95. 发明授权

US06300460B1 Mixed dialkali metal salts of sulfuric acid containing at least one cesium equivalent as polymerization catalysts 有权
标题翻译：含有至少一种铯当量的硫酸的混合二碱金属盐作为聚合催化剂
公开(公告)号：US06300460B1
公开(公告)日：2001-10-09
申请号：US09612652
申请日：2000-07-06
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr. , Alberto Nisoli
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr. , Alberto Nisoli
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： This invention relates to mixed dialkali metal salts of sulfuric acid containing at least one cesium equivalent useful in catalyst systems in melt polymerizations. The catalysts provide product with low branching side reaction products and good properties.
摘要翻译：本发明涉及在熔融聚合中含有可用于催化剂体系的至少一种铯当量的硫酸混合二碱金属盐。催化剂提供具有低支化反应产物和良好性能的产物。

96. 发明授权

US06228973B1 Method for preparing high molecular weight polycarbonate 有权
标题翻译：制备高分子量聚碳酸酯的方法
公开(公告)号：US06228973B1
公开(公告)日：2001-05-08
申请号：US09584984
申请日：2000-06-02
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr. , Johan Pieter Anna Heuts , Hendricus Franciscus Zirkzee
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr. , Johan Pieter Anna Heuts , Hendricus Franciscus Zirkzee
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： A method of preparing polycarbonate by the melt process comprising the steps of: a) melting a dihydric phenol and a diester of carbonic acid for a time and at a temperature sufficient to form a melt; and thereafter introducing a catalyst composition comprising a tetraorganophosphonium salt or a derivative thereof and 1) an alkali and/or alkali earth metal compound or derivative thereof or 2) a less active alkali and/or alkali earth metal derivative thereof into the melt; and b) oligomerizing the product from step a) to a number average molecular weight of from about 3000 to about 7500; and c) polymerizing the product from step b) to a number average molecular weight of from about 16,000 to about 35,000.
摘要翻译：通过熔融法制备聚碳酸酯的方法包括以下步骤：a）在足以形成熔体的时间和温度下熔化二元酚和碳酸二酯; 然后引入含有四有机鏻盐或其衍生物的催化剂组合物，和1）碱金属和/或碱土金属化合物或其衍生物，或2）其活性较低的碱金属和/或碱土金属衍生物; 和b）使来自步骤a）的产物低聚至约3000至约7500的数均分子量; 和c）将来自步骤b）的产物聚合至数均分子量为约16,000至约35,000。

97. 发明授权

US6140457A Static-resistant polycarbonates having DI-t-alkylphenyl end groups 有权
标题翻译：具有DI-t-烷基苯基端基的耐静电聚碳酸酯
公开(公告)号：US6140457A
公开(公告)日：2000-10-31
申请号：US259646
申请日：1999-02-26
申请人： Donald George LeGrand , Patrick Joseph McCloskey
发明人： Donald George LeGrand , Patrick Joseph McCloskey
IPC分类号： C08G64/14 , C08G64/00
CPC分类号： C08G64/14
摘要： Polycarbonates, such as bisphenol A polycarbonates, having end groups derived from a di-t-alkylphenol such as 3,5-di-t-butylphenol have very low electrostatic charges. They are thus useful in applications where static charge is a problem, such as automotive headlamps and optical data recording media.
摘要翻译：具有衍生自二叔烷基酚如3,5-二叔丁基苯酚的端基的聚碳酸酯，例如双酚A聚碳酸酯具有非常低的静电电荷。因此，它们在诸如汽车前照灯和光学数据记录介质之类的静电荷的应用中是有用的。

98. 发明授权

US5977265A Method for preparing brominated polycarbonates, and products obtained thereby 失效
标题翻译：制备溴化聚碳酸酯的方法及由此获得的产物
公开(公告)号：US5977265A
公开(公告)日：1999-11-02
申请号：US922105
申请日：1997-09-02
申请人： Patrick Joseph McCloskey , Gary Charles Davis , David Michel Dardaris , Daniel Joseph Brunelle , Robert Russell Gallucci , Mahari Tjahjadi , David Whalen , Kevin Mitchell Snow
发明人： Patrick Joseph McCloskey , Gary Charles Davis , David Michel Dardaris , Daniel Joseph Brunelle , Robert Russell Gallucci , Mahari Tjahjadi , David Whalen , Kevin Mitchell Snow
IPC分类号： C08L23/00 , C08G64/10 , C08G64/42 , C08L33/06 , C08L67/00 , C08L69/00 , H01R13/46 , H01R13/73 , C08C19/22
CPC分类号： C08G64/42 , C08G64/10
摘要： High flow brominated polycarbonates, useful as flame retardant additives for other polymers such as polyesters, are obtained by equilibration of a brominated aromatic polycarbonate such as a tetrabromobisphenol A homo- or copolycarbonate with a di- or polyhydroxy aromatic compound such as bisphenol A, or a diaryl carbonate, and an equilibration catalyst, under conditions such that the weight average molecular weight of the brominated polycarbonate is reduced by at least 35%. Preferred equilibration catalysts are Group I metal carboxylates, such as sodium stearate, and hexaalkylguanidinium salts.
摘要翻译：通过将溴代芳族聚碳酸酯例如四溴双酚A均聚物或共聚碳酸酯与二羟基芳族化合物或多羟基芳族化合物如双酚A或其混合物平衡，可获得用作其它聚合物如聚酯的阻燃添加剂的高流动溴化聚碳酸酯，碳酸二芳酯和平衡催化剂，使得溴化聚碳酸酯的重均分子量降低至少35％的条件下进行。优选的平衡催化剂是I族金属羧酸盐，例如硬脂酸钠和六烷基胍盐。

99. 发明授权

US5763686A Method for preparing 1,1,1-tris(4-hydroxyphenyl)ethane 失效
标题翻译：制备1,1,1-三（4-羟基苯基）乙烷的方法
公开(公告)号：US5763686A
公开(公告)日：1998-06-09
申请号：US766092
申请日：1996-12-16
申请人： Patrick Joseph McCloskey , Eric James Pressman
发明人： Patrick Joseph McCloskey , Eric James Pressman
IPC分类号： B01J31/12 , C07B61/00 , C07C37/20 , C07C37/70 , C07C37/72 , C07C37/86 , C07C39/16 , C07C39/12
CPC分类号： C07C37/70 , C07C37/20 , Y02P20/52
摘要： 1,1,1-Tris(4-hydroxyphenyl)ethane, a branching agent for polycarbonates, is prepared by the reaction of phenol with 2,4-pentanedione in the presence of sulfuric acid and at least one mercapto sulfonic acid such as 3-mercaptopropanesulfonic acid as promoter. By employing specific proportions of the promoter and sulfuric acid, high product yields can be obtained in relatively short times.
摘要翻译：通过苯酚与2,4-戊二酮在硫酸和至少一种巯基磺酸的存在下的反应制备1,1,1-三（4-羟基苯基）乙烷，用于聚碳酸酯的支化剂，例如3- 巯基丙磺酸作为启动子。通过使用特定比例的助催化剂和硫酸，可以在相对短的时间内获得高产率。

100. 发明授权

US5650470A Polycarbonate redistribution using diethyldimethylammonium hydroxide as catalyst 失效
标题翻译：使用二乙基二甲基氢氧化铵作为催化剂的聚碳酸酯再分布
公开(公告)号：US5650470A
公开(公告)日：1997-07-22
申请号：US660383
申请日：1996-06-07
申请人： Patrick Joseph McCloskey , Eric Thomas Gohr , Timothy Hans Lemmen
发明人： Patrick Joseph McCloskey , Eric Thomas Gohr , Timothy Hans Lemmen
IPC分类号： C08G63/64 , C08G64/42 , C08F283/02
CPC分类号： C08G63/64 , C08G64/42
摘要： Polycarbonate compositions are redistributed by melt equilibration using diethyldimethylammonium hydroxide as the redistribution catalyst. This catalyst affords an odorless polycarbonate product having a very low residual amine level.
摘要翻译：使用二乙基二甲基氢氧化铵作为再分布催化剂，通过熔融平衡重新分布聚碳酸酯组合物。该催化剂提供了具有非常低的残余胺水平的无味聚碳酸酯产物。

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