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91. 发明授权

US07271259B1 Solid phase host compositions 有权
标题翻译：固相主体组合物
公开(公告)号：US07271259B1
公开(公告)日：2007-09-18
申请号：US10430702
申请日：2003-05-06
申请人： Joseph B. Lambert , Chunqing Liu
发明人： Joseph B. Lambert , Chunqing Liu
IPC分类号： C08B37/16
CPC分类号： C08B37/0012 , C08G77/48 , C08G77/50 , C08G77/52 , C08L83/06 , C08L83/14
摘要： A new family of silicon-based polymers has been prepared in which organic host components are bound covalently. The polymer is a polysilsesquioxane matrix comprising, for example, hosts such as cyclodextrins (CD) or calixarenes (CX).
摘要翻译：已经制备了新的硅基聚合物系列，其中有机主体组分共价键合。聚合物是包括例如主体如环糊精（CD）或杯芳烃（CX））的倍半硅氧烷基质。

92. 发明申请

US20070209505A1 High Flux Mixed Matrix Membranes for Separations 审中-公开
标题翻译：用于分离的高通量混合基质膜
公开(公告)号：US20070209505A1
公开(公告)日：2007-09-13
申请号：US11679142
申请日：2007-02-26
申请人： Chunqing Liu , Santi Kulprathipanja , Stephen T. Wilson
发明人： Chunqing Liu , Santi Kulprathipanja , Stephen T. Wilson
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0079 , B01D69/141 , B01D69/147 , B01D71/028 , B01D71/72
摘要： The present invention discloses a new class of high flux mixed matrix membranes that are made by incorporating porous inorganic fillers (e.g. microporous and mesoporous molecular sieves, carbon molecular sieves, porous metal-organic frameworks) into a high flux high surface area microporous organic polymer matrix. These microporous organic polymers are referred to as “polymers of intrinsic microporosity” or PIMs. The high flux membranes are promising for a wide range of separations including liquid separations such as pervaporation of phenol/water and also gas separations in the petrochemical, refinery, and natural gas industries such as methane/carbon dioxide, olefin/paraffin and iso/normal paraffins separations.
摘要翻译：本发明公开了一种新型高通量混合基质膜，其通过将多孔无机填料（例如微孔和介孔分子筛，碳分子筛，多孔金属 - 有机骨架）并入高通量高表面积微孔有机聚合物基体。这些微孔有机聚合物被称为“内在微孔聚合物”或PIM。高通量膜对于广泛的分离是有希望的，包括液体分离，例如苯酚/水的渗透蒸发，以及在石化，炼油和天然气工业中的气体分离，例如甲烷/二氧化碳，烯烃/石蜡和异/正常石蜡分离。

93. 发明申请

US20050221087A1 Nanoporous chelating fibers 审中-公开
标题翻译：纳米多孔螯合纤维
公开(公告)号：US20050221087A1
公开(公告)日：2005-10-06
申请号：US11057698
申请日：2005-02-14
申请人： James Economy , Chunqing Liu
发明人： James Economy , Chunqing Liu
IPC分类号： B01J45/00 , B01J47/12 , C03C25/24 , D06L1/00 , D06M11/79 , D06M15/643
CPC分类号： B01J45/00 , B01J20/2808 , B01J47/127 , C03C25/24 , D06M11/79 , D06M15/643 , D06M2400/02 , Y10T428/2933
摘要： A composite includes substrate fibers, and an organosilica coating including a structure-directing template, on the substrate fibers. The composite may be formed by coating substrate fibers with an organosilica sol containing a structure-directing template, and curing the organosilica sol to form an organosilica coating. A nanoporous chelating fiber includes a substrate fiber and a nanoporous chelating coating, on the substrate fiber. Nanoporous chelating fibers may be formed by removing the structure-directing template from a composite to form a nanoporous chelating coating on the substrate fibers. Contaminants may be removed from a fluid by contacting nanoporous chelating fibers with a fluid containing at least one contaminant.
摘要翻译：复合材料包括基材纤维和包含结构导向模板的有机二氧化硅涂层。可以通过用含有结构导向模板的有机二氧化硅溶胶涂布基材纤维，并固化有机硅溶胶以形成有机二氧化硅涂层来形成复合材料。纳米多孔螯合纤维包括基材纤维和纳米多孔螯合涂层。可以通过从复合材料中除去结构导向模板以在基底纤维上形成纳米多孔螯合涂层来形成纳米多孔螯合纤维。通过使纳米多孔螯合纤维与含有至少一种污染物的流体接触，可以从流体中除去污染物。

94. 发明授权

US06423772B1 Organo-bridged ladderlike polysiloxane, tube-like organosilicon polymers, complexes thereof, and the method for producing the same 失效
标题翻译：有机桥状梯状聚硅氧烷，管状有机硅聚合物及其络合物及其制造方法
公开(公告)号：US06423772B1
公开(公告)日：2002-07-23
申请号：US09616338
申请日：2000-07-14
申请人： Rongben Zhang , Chunqing Liu , Ping Xie , Huadong Tang
发明人： Rongben Zhang , Chunqing Liu , Ping Xie , Huadong Tang
IPC分类号： G77
CPC分类号： C08G77/52 , C08G77/50
摘要： The present invention provides to an organo-bridged ladderlike polysiloxane having the following formula: and a tube-like organosilicon polymer, complexes thereof and the method for producing the same.
摘要翻译：本发明提供具有下式的有机桥状梯状聚硅氧烷和管状有机硅聚合物及其络合物及其制备方法。

95. 发明授权

US08816003B2 High plasticization-resistant cross-linked polymeric membranes for separations 有权
标题翻译：用于分离的高增塑抗性交联聚合物膜
公开(公告)号：US08816003B2
公开(公告)日：2014-08-26
申请号：US12145153
申请日：2008-06-24
申请人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
发明人： Chunqing Liu , Stephen T. Wilson , David A. Lesch
IPC分类号： C08F12/22
CPC分类号： C08B15/10 , B01D53/228 , B01D67/0093 , B01D71/16 , B01D2323/30 , B01D2325/30 , C08G18/6484 , C08L71/02 , C08L81/06 , Y02P20/152
摘要： This invention involves a composition, a method of making, and an application of high plasticization-resistant chemically cross-linked polymeric membranes such as cross-linked cellulose acetate (CA) membrane. These cross-linked polymeric membranes with covalently interpolymer-chain-connected rigid networks showed no decrease in CO2/CH4 ideal selectivity under 690 kPa (100 psig) pure CO2 pressure and also no CO2 plasticization up to 3447 kPa (500 psig) pure CO2 pressure. By using the method of chemical cross-linking as described in this invention, the separation characteristics of the polymeric membranes can be decisively improved. These new cross-linked polymeric membranes can be used not only for gas separations such as CO2/CH4 and CO2/N2 separations, O2/N2 separation, olefin/paraffin separations (e.g. propylene/propane separation), iso/normal paraffins separations, but also for liquid separations such as pervaporation and desalination.
摘要翻译：本发明涉及一种组合物，制备方法，以及应用高耐增塑作用的化学交联聚合物膜，例如交联乙酸纤维素（CA）膜。这些具有共价互聚链连接的刚性网络的交联聚合物膜在690kPa（100psig）纯二氧化碳压力下没有显示CO 2 / CH 4理想选择性的降低，并且也没有CO2增塑达3447kPa（500psig）纯二氧化碳压力。通过使用如本发明所述的化学交联方法，可以确定地提高聚合物膜的分离特性。这些新的交联聚合物膜不仅可用于气体分离，如CO2 / CH4和CO2 / N2分离，O2 / N2分离，烯烃/石蜡分离（如丙烯/丙烷分离），异/正链烷烃分离，但还用于液体分离，例如渗透蒸发和脱盐。

96. 发明申请

US20140020557A1 METHODS AND APPARATUSES FOR GENERATING NITROGEN 审中-公开
标题翻译：用于产生氮的方法和装置
公开(公告)号：US20140020557A1
公开(公告)日：2014-01-23
申请号：US13554671
申请日：2012-07-20
申请人： Lubo Zhou , Chunqing Liu , Mark E. Schott , David W. Greer
发明人： Lubo Zhou , Chunqing Liu , Mark E. Schott , David W. Greer
IPC分类号： B01D53/22
CPC分类号： B01D53/265 , B01D53/229 , B01D2256/10 , B01D2257/504 , B01D2257/80 , B01D2258/0283 , Y02C10/10
摘要： Embodiments of methods and apparatuses for generating nitrogen are provided. In one example, a method comprises the steps of contacting at least a portion of a flue gas stream with a CO2/N2 separation membrane at conditions effective to form a N2-rich retentate stream and a CO2-rich permeate stream. Liquid hydrocarbons are covered with the N2-rich retentate stream to form a blanket of nitrogen.
摘要翻译：提供了用于产生氮气的方法和装置的实施例。在一个实例中，方法包括以下步骤：在有效形成富N2的滞留物流和富二氧化碳的渗透物流的条件下使至少一部分烟道气流与CO 2 / N 2分离膜接触。用富氮的滞留物流覆盖液体烃以形成氮气覆盖层。

97. 发明授权

US08613362B2 Polymer membranes derived from aromatic polyimide membranes 有权
标题翻译：衍生自芳族聚酰亚胺膜的聚合物膜
公开(公告)号：US08613362B2
公开(公告)日：2013-12-24
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
IPC分类号： B01D71/64 , B01D71/28 , B01D69/00
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

98. 发明授权

US08540800B2 Microporous UZM-5 inorganic zeolite membranes for gas, vapor, and liquid separations 失效
标题翻译：用于气体，蒸汽和液体分离的微孔UZM-5无机沸石膜
公开(公告)号：US08540800B2
公开(公告)日：2013-09-24
申请号：US13052720
申请日：2011-03-21
申请人： Chunqing Liu , Jaime G. Moscoso , Stephen T. Wilson
发明人： Chunqing Liu , Jaime G. Moscoso , Stephen T. Wilson
IPC分类号： B01D53/22 , B01D71/02
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0048 , B01D67/0051 , B01D67/0088 , B01D69/10 , B01D2323/14 , B01J20/186 , B01J20/28007 , B01J20/28035 , B01J20/3057 , B01J20/3078 , B01J20/3085 , B01J20/3238 , B01J20/3272 , B82Y30/00
摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.
摘要翻译：本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。

99. 发明申请

US20120240763A1 MICROPOROUS UZM-5 INORGANIC ZEOLITE MEMBRANES FOR GAS, VAPOR, AND LIQUID SEPARATIONS 失效
标题翻译：用于气体，蒸气和液体分离的微波UZM-5无机沸石膜
公开(公告)号：US20120240763A1
公开(公告)日：2012-09-27
申请号：US13052720
申请日：2011-03-21
申请人： Chunqing Liu , Jaime G. Moscoso , Stephen T. Wilson
发明人： Chunqing Liu , Jaime G. Moscoso , Stephen T. Wilson
IPC分类号： B01D53/22 , B01J20/32
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0048 , B01D67/0051 , B01D67/0088 , B01D69/10 , B01D2323/14 , B01J20/186 , B01J20/28007 , B01J20/28035 , B01J20/3057 , B01J20/3078 , B01J20/3085 , B01J20/3238 , B01J20/3272 , B82Y30/00
摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.
摘要翻译：本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。

100. 发明授权

US08132678B2 Polybenzoxazole polymer-based mixed matrix membranes 有权
标题翻译：聚苯并恶唑聚合物基混合基质膜
公开(公告)号：US08132678B2
公开(公告)日：2012-03-13
申请号：US12412647
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
IPC分类号： B01D71/02 , B01D71/40 , B01D71/64 , B01D71/82 , B01D59/12 , B01D69/00
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , B01D71/62 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/06 , H01M8/1048 , H01M2300/0082 , Y02C10/10 , Y02C20/20
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

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