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    • 97. 发明授权
    • Coarse particle size kaolin clay and method
    • 粗粒度高岭土和方法
    • US5846309A
    • 1998-12-08
    • US803349
    • 1997-02-20
    • Gary M. FreemanJohn M. M. HarrisonKenneth B. Files
    • Gary M. FreemanJohn M. M. HarrisonKenneth B. Files
    • C08K3/34C09C1/00C09C1/42C09C1/02
    • C09C1/42C08K3/346C09C1/0081C01P2004/20C01P2004/51C01P2004/54C01P2004/61C01P2006/12C01P2006/22C01P2006/60C01P2006/80C08K2201/016
    • A coarse particle kaolin clay is provided having an average Stokes equivalent particle diameter of about 4.5-6.0 microns, a BET surface area of about 8-11 m.sup.2 /g, and preferably having a median Malvern particle size of about 9.0-10.5 microns as determined by laser light-scattering measurement and a high aspect ratio preferably of about 12-14 as determined by Sphericity Model calculations. The coarse particle kaolin clay provides low viscosity build, good reinforcement properties and excellent surface finish qualities as a filler in thermoset composite materials, such as polyester molding compounds, and also provides excellent pigmenting properties in paints and industrial coatings. Preparation of the coarse particle clay involves blunging and degritting a crude kaolin clay, conducting three separate centrifugation steps with the desired product stream being, in sequence, the coarse underflow clay from the primary centrifuge, the coarse underflow from the secondary centrifuge, and then the fine overflow from the tertiary centrifuge, followed by magnetic separation, screening, chemical leaching, drying and milling to produce a kaolin clay product having the above-described physical properties and performance characteristics.
    • 提供粗颗粒高岭土,其平均斯托克斯当量粒径为约4.5-6.0微米,BET表面积为约8-11m 2 / g,优选具有约9.0-10.5微米的中值Malvern粒径,如所确定的 通过激光光散射测量和通过球形度计算确定的优选约12-14的高纵横比。 粗颗粒高岭土在热固性复合材料如聚酯模塑料中提供低粘度构造,良好的增强性能和优异的表面光洁度作为填料,并且还在油漆和工业涂料中提供优异的着色性能。 粗颗粒粘土的制备涉及对粗高岭土进行白化和碾磨,进行三个单独的离心步骤,其中所需产物流依次是来自主离心机的粗下游粘土,来自二次离心机的粗下游,然后是 来自三级离心机的细溢出,然后进行磁选,筛分,化学浸出,干燥和研磨以制备具有上述物理性能和性能特征的高岭土产品。