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    • 2. 发明申请
    • Aqueous aerosol paints
    • 水性气溶胶涂料
    • US20030100663A1
    • 2003-05-29
    • US10182593
    • 2002-10-11
    • Heinz-Peter RinkWerner-Alfons JungGuido WilkeDieter WeberHans-Joachim Weintz
    • C08L033/06C08K003/00
    • C08F285/00C09D5/021C09D151/00
    • An aqueous spray can coating material comprising at least one water-soluble or water-dispersible copolymer of ethylenically unsaturated monomers, said copolymer being preparable by an at least two-stage free-radical copolymerization, initiated by oil-soluble thermolabile free-radical initiators, in at least one organic solvent, of (A) at least one ethylenically unsaturated monomer containing at least one hydrophilic functional group (a) which renders the copolymer water-soluble or water-dispersible, and (B)at least one ethylenically unsaturated monomer containing no functional group (a), where, in at least one stage, the monomer (A) employed therein or the monomer mixture (A/B) employed therein would per se form a water-soluble or water-dispersible polymer or copolymer, and its use to coat primed and unprimed substrates.
    • 一种含水喷雾剂涂料,其包含至少一种烯属不饱和单体的水溶性或水分散性共聚物,所述共聚物可通过至少两步自由基共聚制备,由油溶性不可溶热自由基引发剂引发, 在至少一种有机溶剂中,(A)至少一种含有至少一种使所述共聚物具有水溶性或水分散性的亲水性官能团(a)的烯属不饱和单体,和(B)至少一种含烯键式不饱和单体 无官能团(a),其中在至少一个阶段中使用的单体(A)或其中使用的单体混合物(A / B)本身将形成水溶性或水分散性聚合物或共聚物,以及 它用于涂底漆和未加底漆。
    • 4. 发明申请
    • Aqueous dispersions of particles of polymers with a glass transition temperature gradient
    • 具有玻璃化转变温度梯度的聚合物颗粒的水分散体
    • US20010034400A1
    • 2001-10-25
    • US09784915
    • 2001-02-16
    • Dirk Emiel Paula Mestach
    • C08K003/00C08L033/06C08L031/00
    • C08F220/06C08F2/22C08F220/34C08F220/58C08F2220/1825C08F2222/145
    • The invention pertains to an aqueous dispersion of particles of a polymer having a functional group for cross-linking, which is obtainable by a free radical emulsion polymerization of at least two different ethylenically unsaturated monomers, a surfactant of the formula Mnull.nullOOCnullCHnullCHCOOR, wherein R is C(6-22) alkyl and Mnullis Nanull, Knull, Linull, NH4null, or a protonated or quaternary amine, and a co-reactive compound having at least two groups capable of reacting with the functional group for cross-linking, characterized in that the glass-transition temperature (Tg) of the polymer at the center of the particle is different from the Tg of the polymer at the surface of the particle, the difference being at least 55null C., and the Tg of the polymer having the highest Tg is at least 40null C.
    • 本发明涉及具有交联官能团的聚合物颗粒的水分散体,其可通过至少两种不同的烯键式不饱和单体的自由基乳液聚合获得,式M +的-OOC-CH = CHCOOR,其中R是C(6-22)烷基,M +是Na +,K +,Li +,NH 4 +或质子化或季胺,以及具有至少两个能够与官能团反应的基团的共反应性化合物 用于交联,其特征在于,在颗粒中心处的聚合物的玻璃化转变温度(Tg)与颗粒表面处的聚合物的Tg不同,差值至少为55℃, Tg最高的聚合物的Tg至少为40℃。
    • 5. 发明申请
    • Aqueous dispersion type fluororesin coating composition
    • 水分散型氟树脂涂料组合物
    • US20040242753A1
    • 2004-12-02
    • US10484965
    • 2004-01-28
    • Nobuyuki TomihashiYoshihiro SodaHiromichi MomoseKoichiro Ogita
    • C08L027/12C08L033/06
    • C09D127/12C08L33/00C08L33/06C09D127/18C08L2666/04
    • The present invention relates to an aqueous dispersion composition of fluororesin for coating comprising (A) fluororesin particles, (B) a nitrogen-free high boiling point polyol having a boiling point of at least 100null C. and containing at least 2 hydroxyl groups, (C) depolymerizable acrylic resin particles having a decomposition and vaporization temperature within a temperature range of up to the decomposition temperature of said fluororesin particles, (D) a nonionic surfactant, and (E) an aqueous medium, wherein the high boiling point polyol (B) and the depolymerizable acrylic resin particles (C) are respectively contained in an amount of 5 to 18 parts by mass and 5 to 25 parts by mass based on 100 parts by mass of fluororesin particles (A) and an oxidant and an amine-type solvent are not contained. This composition is an aqueous dispersion composition of fluororesin for coating, which has favorable storage stability, can be coated thickly, controls development of mud crack and can form a coating film in which cracking and coloring do not occur when baking. Also, the composition controls discharge of endocrine disrupter substances as much as possible.
    • 本发明涉及包含(A)氟树脂颗粒,(B)沸点至少为100℃并含有至少2个羟基的无氮高沸点多元醇的涂料用氟涂料用水分散体组合物, (C)可分解和蒸发温度在所述氟树脂颗粒的分解温度的温度范围内的可解聚丙烯酸树脂颗粒,(D)非离子表面活性剂和(E)水性介质,其中所述高沸点多元醇( B)和可解聚丙烯酸树脂颗粒(C)的含量相对于100质量份的氟树脂粒子(A)和氧化剂和胺类化合物,分别为5〜18质量份,5〜25质量份, 型溶剂不含。 该组合物是涂料用氟树脂的水性分散体组合物,其储存稳定性良好,可以较厚地进行涂布,控制泥浆裂纹的发展,并且可以形成在烘烤时不会发生裂纹和着色的涂膜。 此外,组合物尽可能地控制内分泌干扰物质的排出。
    • 6. 发明申请
    • Continuous process for preparing polymer based pigment preparations
    • 制备聚合物基颜料制剂的连续工艺
    • US20030088015A1
    • 2003-05-08
    • US10216531
    • 2002-08-09
    • Johannes LeugsHarald Marinus Alexander HeereAdrianus Hendrikus Van Rooijen
    • C08L033/06
    • C08F2/44C09B67/0063
    • Preparing pigment preparations by mixing a dyestuff with a monomer and simultaneously polymerizing the monomers in an extruder at elevated temperatures, wherein the following steps are carried out: (A) introducing continuously into an extruder (a) from 40 to 90% by weight of a pigment, (b) from 60 to 10% by weight of a monomer or a monomer mixture, and (c) from 0.01 to 10% by weight, related to the amount of monomer component (b), of an initiator or a mixture of initiators, and (d) from 0 to 10% by weight, related to the amount of monomer component (b), of a chain transfer agent, whereby the amounts of the pigment and the monomer or monomer mixture sum up to 100%, and whereby the monomer component (b) is admixed with either the initiator or mixture of initiators (c), or the chain transfer agent (d), or the initiator or initiator mixture (c) and the chain transfer agent (d), before it is introduced into the extruder, (B) simultaneously mixing the components (a) to (c), as well as (d) if present, and polymerizing the monomer or copolymerizing monomer mixture within the extruder, and (C) withdrawing continuously the obtained reaction mixture from the extruder, pigment preparations, high molecular weight organic material pigmented therewith as well as the use thereof.
    • 通过将染料与单体混合并在高温下在挤出机中同时聚合单体来制备颜料制剂,其中进行以下步骤:(A)连续引入挤出机(a)中40至90重量% 颜料,(b)60至10重量%的单体或单体混合物,和(c)与单体组分(b)的量相关的0.01至10重量%的引发剂或混合物 引发剂,和(d)与链转移剂的单体组分(b)的量相关的0至10重量%,由此颜料和单体或单体混合物的量总计达100%,和 由此将单体组分(b)与引发剂或引发剂(c)或链转移剂(d)的混合物或引发剂或引发剂混合物(c)和链转移剂(d) 引入挤出机中,(B)同时混合组分(a)至(c),以及(d)如果 存在并使单体或共聚单体混合物在挤出机内聚合,(C)从所述挤出机,颜料制剂,着色的高分子量有机材料及其用途连续取出得到的反应混合物。
    • 7. 发明申请
    • Water repellent composition
    • 防水组合物
    • US20020107327A1
    • 2002-08-08
    • US09984401
    • 2001-10-30
    • Asahi Glass Company, Limited
    • Toyomichi ShimadaKyoichi KanekoTakashige Maekawa
    • C08L033/06
    • D06M15/29C08L33/06C08L33/16D06M15/263D06M15/277D06M15/285D06M2200/12C08L2666/04
    • A water repellent composition is provided containing the polymers (A) and (B), wherein polymers (A) and (B) are not present in the same particles, wherein polymer (A) is an addition polymer having at least 60 mass % of polymerized units of a (meth)acrylate (a) having a polyfluoroalkyl group, and 0-40 mass % of a methacrylate (b) having a long chain alkyl group and not a polyfluoroalkyl group, and, if necessary, polymerized units of a polymerizable monomer (x) other than monomers (a) and (b), polymer (B) is an addition polymer having 0-60 mass % of monomer (a), and at least 30 mass % of polymerized units of a polymerizable monomer (c), other than monomers (a) and (b), and, if necessary, polymerized units of a monomer (y) other than monomers (a) and (c), along with an article treated therewith and the method of treating an article with the water repellent composition.
    • 提供含有聚合物(A)和(B)的防水组合物,其中聚合物(A)和(B)不存在于相同的颗粒中,其中聚合物(A)是具有至少60质量% 具有多氟烷基的(甲基)丙烯酸酯(a)和0〜40质量%的具有长链烷基而不是多氟烷基的甲基丙烯酸酯(b)的聚合单元,如果需要,可聚合单元 除单体(a)和(b)以外的单体(x),聚合物(B)是具有0〜60质量%的单体(a)的加成聚合物,和聚合性单体的聚合单元的至少30质量% ),单体(a)和(b)以外,如果需要,除单体(a)和(c)以外的单体(y)的聚合单元以及用其处理的制品以及处理物品的方法 与防水组合物。