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    • 5. 发明授权
    • Process for oil recovery employing surfactant gels
    • 使用表面活性剂凝胶的油回收方法
    • US07373977B1
    • 2008-05-20
    • US11081232
    • 2005-03-16
    • Paul Daniel BergerChristie Huimin Berger
    • Paul Daniel BergerChristie Huimin Berger
    • E21B43/20E21B43/22C09K8/584C09K8/588
    • C09K8/584Y10S507/936
    • A process for recovering oil by injecting into a subterranean oil-bearing reservoir through one or more injection wells, an aqueous solution containing one or more amphoteric alkyl amido betaine surfactants that form a viscoelastic gel reducing interfacial tension and increasing the viscosity of the injection fluid simultaneously, displacing the solution into the reservoir, and recovering the oil from one or more production wells. These viscoelastic gels are tolerant to electrolytes and multivalent cations. They are shear reversible and adsorbed little onto the reservoir. Their viscosity is reduced when contacting certain hydrocarbons but remains high when contacting water or brine. This allows the fluid to preferentially penetrate the oil-bearing portions of the formation and resulting additional oil recovery. These viscoelastic surfactant gels are particularly suitable for use with reservoirs and brines characterized by medium to high temperatures, higher salinity, higher concentrations of divalent cations, and low formation porosities.
    • 一种通过一个或多个注入井注入地下含油储层的方法,含有一种或多种两性烷基酰氨基甜菜碱表面活性剂的水溶液,其形成粘弹性凝胶,同时降低界面张力并增加注射液的粘度 将溶液置于储存器中,并从一个或多个生产井回收油。 这些粘弹性凝胶耐电解质和多价阳离子。 它们是剪切可逆的,并且很少吸附到储层上。 当接触某些烃时,它们的粘度降低,而当接触水或盐水时它们的粘度保持较高。 这允许流体优先地穿透地层的含油部分并且导致额外的油回收。 这些粘弹性表面活性剂凝胶特别适用于以中等至高温,较高盐度,较高浓度的二价阳离子和较低的地层孔隙度为特征的储层和盐水。
    • 8. 发明授权
    • Polyalkylated arylalkyl sulfonic acids and their salts
    • 多烷基芳基烷基磺酸及其盐
    • US07605287B2
    • 2009-10-20
    • US11895497
    • 2007-08-24
    • Paul Daniel BergerChristie Huimin BergerGuohua CaoOliver Yehung Hsu
    • Paul Daniel BergerChristie Huimin BergerGuohua CaoOliver Yehung Hsu
    • C07C303/22
    • C07C303/02C07C303/22C07C309/24
    • The present invention discloses a process for producing polyalkylated arylalkyl sulfonic acids by reacting arylalkyl sulfonic acids with olefins. The polyalkylated arylalkyl sulfonic acids may be further neutralized with alkalis or amines to form the corresponding sulfonated salts. The present invention also makes possible manufacture of polyalkylated arylalkyl sulfonic acids as first intent products using an inexpensive and simple reaction. The structure of the polyalkylated arylalkyl sulfonic acids produced using the process described in the present invention is shown below: Where R1, R2 and R3 are each separately and independently H, alkyl (branched or linear C1 to C30), (—CH2CH2O)a, (—CH(CH3)CH2O)b, or (—CH2CH2O)c(—CH2(CH3)CH2O)d, m+n=8 to 28 R4=CH2CH3, CH2CH3Y or Y(CH2)pCH(CH2)qY p+q=0 to 27 a=1 to 30 b=1 to 30 c+d=2 to 30 Y=CH3, COOH, CH2OH, CH2(—CH2CH2O)a, CH2(—CH(CH3)CH2O)b, CH2(—CH2CH2O)c(—CH2(CH3)CH2O)d, aromatic, or substituted aromatic.
    • 本发明公开了一种通过芳基烷基磺酸与烯烃反应制备多烷基化芳基烷基磺酸的方法。 多烷基化芳烷基磺酸可以用碱或胺进一步中和以形成相应的磺化盐。 本发明还可以使用廉价和简单的反应制备多烷基化芳烷基磺酸作为第一意图产品。 使用本发明所述方法制备的多烷基化芳烷基磺酸的结构如下所示:其中R1,R2和R3各自独立地为H,烷基(支链或直链C1至C30),( - CH2CH2O)a, (-CH(CH 3)CH 2 O)b或(-CH 2 CH 2 O)c(-CH 2(CH 3)CH 2 O)d,m + n = 8〜28 R 4 = CH 2 CH 3,CH 2 CH 3 Y或Y(CH 2)p CH(CH 2)q Y p + q = 0至27 a = 1至30 b = 1至30 c + d = 2至30 Y = CH3,COOH,CH2OH,CH2(-CH2CH2O)a,CH2(-CH(CH3)CH2O)b,CH2( -CH 2 CH 2 O)c(-CH 2(CH 3)CH 2 O)d,芳族或取代的芳族。