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1. 发明授权

US5389468A Alkaline storage battery 失效
标题翻译：碱性蓄电池
公开(公告)号：US5389468A
公开(公告)日：1995-02-14
申请号：US29525
申请日：1993-03-11
申请人： Shozo Fujiwara , Yoichi Izumi , Yoshio Moriwaki , Isao Matsumoto
发明人： Shozo Fujiwara , Yoichi Izumi , Yoshio Moriwaki , Isao Matsumoto
IPC分类号： C22C1/00 , B22F9/04 , C22C1/02 , H01M4/24 , H01M4/26 , H01M4/38 , H01M10/24 , H01M10/34 , H01M10/26 , H01M4/36
CPC分类号： H01M4/383 , B22F9/04 , B22F2999/00 , Y10S420/90
摘要： A hydrogen storage alloy particles comprising base particles consisting of hydrogen storage alloy particles and fine particles consisting of at least one of metals, alloys, hydrophobic resins, catalyst materials, metal oxides having a particle size smaller than that of the base particles where the fine particles are very firmly bonded to the base particles are employed as negative electrodes for alkaline storage batteries. The bonding of the fine particles to the base particles is performed by a surface treatment so-called mechanofusion process (one of mechanochemical reaction process) where the base particles and the fine particles are subjected therebetween predominantly to a mechanical energy, practically those derived from the compression and attrition forces simultaneously to emboss the surfaces of the base particles and to allow the fine particles to be extended and bonded firmly under pressure onto the surfaces of the base particles, thereby coating at least a part of the surfaces of the base particles with the fine particles.
摘要翻译：一种储氢合金颗粒，其包含由储氢合金颗粒组成的基础颗粒和由金属，合金，疏水性树脂，催化剂材料，具有比基础颗粒小的颗粒的金属氧化物中的至少一种构成的细颗粒，其中细颗粒非常牢固地结合到基础颗粒上用作碱性蓄电池的负极。通过表面处理所谓的机械融合工艺（机械化学反应过程之一）进行表面处理，其中基体颗粒和细颗粒主要经受机械能，其实际上是从压缩和磨损力同时压印基础颗粒的表面，并允许细颗粒在压力下被牢固地延伸和粘合到基础颗粒的表面上，从而将基体颗粒的至少一部分表面涂覆细颗粒。

2. 发明授权

US06333124B1 Metal outer can for a battery and method of manufacturing same 有权
标题翻译：金属外罐用于电池及其制造方法
公开(公告)号：US06333124B1
公开(公告)日：2001-12-25
申请号：US09254365
申请日：1999-03-04
申请人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Isao Matsumoto
发明人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Isao Matsumoto
IPC分类号： H01M202
CPC分类号： H01M2/0272 , B21D22/28 , H01M2/0202 , H01M2/0217 , H01M2/0225 , H01M2/027 , H01M2/0275 , H01M2/0287 , Y10T29/49108
摘要： A battery has elements for electromotive-force accommodated in a metal outer can which has a bottom having a cylindrical, prismatic or similar shape. The ratio of the bottom thickness (TA) the side thickness (TB) is 1.5-7.0. The metal outer can contains primarily iron and a layer of nickel is provided on at least the inner face of the battery. Shallow grooves are formed on the nickel layer perpendicular to the bottom face. An iron-based metallic sheet formed with a nickel layer on at least one face is subjected to drawing forming into a tubular shape having a bottom, continuous ironing processing being performed such that the side of the can formed in the tubular shape has an ironing ratio in the range of 20% to 90% and a metal outer can is thereby manufactured having a ratio of a bottom thickness to its side thickness from 1.5 to 7.0, having a cylindrical shape, prismatic shape or shape similar thereto, and with shallow longitudinal grooves formed in a nickel layer provided on the battery inside face.
摘要翻译：电池具有容纳在金属外罐中的电动势的元件，其具有圆柱形，棱柱形或类似形状的底部。底部厚度（TA）与侧面厚度（TB）之比为1.5-7.0。金属外壳主要包含铁，并且至少在电池的内表面上设置一层镍。在垂直于底面的镍层上形成浅槽。在至少一个面上形成有镍层的铁基金属片被拉伸成形为具有底部连续熨烫加工的管状，使得形成为管状的罐的侧面具有熨烫比在20％至90％的范围内，并且由此制造具有底部厚度与其侧面厚度的比率为1.5至7.0的金属外罐，其具有圆柱形形状，棱柱形状或类似形状，并且具有浅纵向凹槽形成在设置在电池内侧的镍层中。

3. 发明授权

US06258480B1 Battery and method of manufacturing therefor 有权
标题翻译：电池及其制造方法
公开(公告)号：US06258480B1
公开(公告)日：2001-07-10
申请号：US09284304
申请日：1999-04-09
申请人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Mamoru Iida , Isao Matsumoto
发明人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Mamoru Iida , Isao Matsumoto
IPC分类号： H01M0204
CPC分类号： H01M2/0275 , H01M2/0217 , H01M2/023 , H01M2/0237 , H01M2/0272 , H01M6/10 , H01M10/0525 , Y10T29/49108 , Y10T29/53135
摘要： A battery accommodates elements for electromotive-force within a metal case. This metal case is a metal case having a bottom wherein the bottom thickness/side thickness ratio has a value of 1.2-4.0 and has a cylindrical, prismatic or similar shape. The metal case is constructed of a metal material whose chief constituent is aluminum. Furthermore, it is desirable that a multiplicity of shallow grooves perpendicular to a bottom face are formed in at least a battery inside face of the metal case and moreover that a nickel layer is provided on the battery inside face. The metal case is made by DI processing involving drawing and ironing, to have a value of bottom thickness/side thickness ratio which was hitherto unavailable,i.e., 1.2-4.0 can be obtained.
摘要翻译：电池容纳金属外壳内的电动元件。该金属壳体是具有底部的金属壳体，其中底部厚度/侧壁厚度比值为1.2-4.0，并且具有圆柱形，棱柱形或类似形状。金属外壳由主要成分为铝的金属材料构成。此外，在金属壳体的至少一个电池内表面中形成垂直于底面的多个浅槽，并且还在电池内侧设置有镍层。金属外壳由涉及拉丝和熨烫的DI加工制成，具有迄今为止不能得到的底部厚度/厚度比的值，即可得到1.2-4.0。

4. 发明授权

US06183909B2 Alkaline storage battery 失效
标题翻译：碱性蓄电池
公开(公告)号：US06183909B2
公开(公告)日：2001-02-06
申请号：US09070738
申请日：1998-05-01
申请人： Akihiro Maeda , Hirokazu Kimiya , Yoshio Moriwaki , Isao Matsumoto
发明人： Akihiro Maeda , Hirokazu Kimiya , Yoshio Moriwaki , Isao Matsumoto
IPC分类号： H01M432
CPC分类号： H01M4/52 , H01M4/32 , H01M10/345 , Y02E60/124
摘要： A high energy density alkaline storage battery which uses a positive electrode including mainly nickel oxide is provided by increasing the capacities of the positive electrode and negative electrode. For increasing the capacity density of the positive electrode, the active material is incorporated as a solid solution with at least one element selected from manganese, chromium, aluminum and calcium in the range of from not less than 3 mol % to not more than 15 mol % relative to the active material, and the surface and/or the neighborhood of the surface of the active material are coated with a cobalt oxyhydroxide having a high electric conductivity of a specific resistance of 15 &OHgr;·cm or less and a low crystallinity.
摘要翻译：通过增加正极和负极的容量，提供使用主要包含氧化镍的正极的高能量密度碱性蓄电池。为了提高正极的容量密度，将活性物质作为固溶体结合，其中选自锰，铬，铝和钙中的至少一种元素为不小于3mol％至不大于15mol ％，并且活性材料表面的表面和/或附近涂覆有电阻率高达15欧姆·厘米或更小且结晶度低的高电导率的羟基氧化钴。

5. 发明授权

US6030725A Negative electrode for alkaline storage batteries 失效
标题翻译：碱性蓄电池用负极
公开(公告)号：US6030725A
公开(公告)日：2000-02-29
申请号：US47372
申请日：1998-03-25
申请人： Yoshio Moriwaki , Akihiro Maeda , Hirokazu Kimiya , Isao Matsumoto
发明人： Yoshio Moriwaki , Akihiro Maeda , Hirokazu Kimiya , Isao Matsumoto
IPC分类号： C22C1/04 , H01M4/38 , H01M4/58 , C01B6/24
CPC分类号： H01M4/383 , C22C1/0441 , B22F2998/00 , B22F2999/00 , Y10S420/90
摘要： The present invention provides alkaline storage batteries of which high-rate discharge characteristic at low-temperature, cycle life, and storage performance at high-temperature are improved in good balance and the cost performance is superior even when the content of cobalt is made extremely low by using in the negative electrode consisting of hydrogen absorbing alloy powders based on MmNi system alloys comprising MmNi.sub.5 system alloy which remains mostly crystalline in phase when absorbing hydrogen and Mm.sub.2 Ni.sub.7 system alloy which turns mostly amorphous in phase upon absorbing hydrogen.
摘要翻译：本发明提供了一种碱性蓄电池，其在高温下的高速放电特性，循环寿命和高温下的储存性能得到良好的平衡地提高，并且即使钴的含量极低，成本性能也优异通过使用由吸收合金粉末组成的负极，该吸收合金粉末基于包含MmNi5系统合金的MmNi系合金，其中MmNi5系统合金在吸收氢时保持大部分为晶相，而在吸收氢时大部分变为非晶相的Mm2Ni7系合金。

6. 发明授权

US06444366B1 Non-sintered electrode and method of manufacturing same 失效
标题翻译：非烧结电极及其制造方法
公开(公告)号：US06444366B1
公开(公告)日：2002-09-03
申请号：US09700716
申请日：2000-11-28
申请人： Hiroshi Kawano , Yoshio Moriwaki , Isao Matsumoto
发明人： Hiroshi Kawano , Yoshio Moriwaki , Isao Matsumoto
IPC分类号： H01M430
CPC分类号： H01M4/78 , H01M4/02 , H01M4/043 , H01M4/0433 , H01M4/13 , H01M4/24 , H01M4/242 , H01M4/32 , H01M4/625 , H01M4/626 , H01M4/661 , H01M4/70 , H01M4/74 , H01M4/742 , H01M10/0525 , H01M10/30 , H01M10/345 , H01M2004/021 , Y10T29/10 , Y10T29/49115
摘要： A metal sheet (1) which constitutes a non-sintered type electrode support is processed to have minute irregularities on its surface. The irregularities are formed by a mechanical method such that protrusions (9) and indentations (8) are configured with a center-to-center pitch (P) in the range of from 50 to 300 &mgr;m and such that the apparent thickness after processing is at least three times as large as the unprocessed material thickness.
摘要翻译：构成非烧结型电极载体的金属板（1）在其表面上被加工成具有微小的凹凸。通过机械方法形成凹凸，使得突起（9）和凹陷（8）构造为中心间距（P）在50至300μm的范围内，并且使得加工后的表观厚度为是未加工材料厚度的至少三倍。

7. 发明授权

US06338917B1 Alkaline storage battery 失效
标题翻译：碱性蓄电池
公开(公告)号：US06338917B1
公开(公告)日：2002-01-15
申请号：US09201843
申请日：1998-12-01
申请人： Akihiro Maeda , Hirokazu Kimiya , Yoshio Moriwaki , Isao Matsumoto
发明人： Akihiro Maeda , Hirokazu Kimiya , Yoshio Moriwaki , Isao Matsumoto
IPC分类号： H01M432
CPC分类号： H01M10/345 , H01M4/52 , H01M10/26 , Y02E60/124
摘要： A nickel positive electrode including an active material mixture mainly composed of a nickel oxide and an electrically conductive support, a metal and/or an oxide thereof including elements effective for increasing oxygen overvoltage, preferably at least one element selected from Ca, Ti, Nb, Cr, Y and Yb is contained in a conducting agent such as metallic Co and/or Co oxide added to supplement the electrical conductivity of the active material. By virtue of this construction, the decrease of charging efficiency caused by increase of battery temperature and decrease of the oxygen overvoltage with charging of the battery can be inhibited and the charging efficiency can be improved in a wide temperature atmosphere. Thus, a nickel-metal hydride storage battery of high capacity can be provided.
摘要翻译：包括主要由氧化镍和导电载体组成的活性物质混合物的镍正极，包含有效提高氧过电压的元素的金属和/或氧化物，优选选自Ca，Ti，Nb， Cr，Y和Yb包含在添加的金属Co和/或Co氧化物等导电剂中以补充活性物质的导电性。通过这种结构，可以抑制由于电池温度升高引起的充电效率的降低和电池充电时的氧过电压的降低，并且可以在宽温度的气氛中提高充电效率。因此，可以提供高容量的镍氢蓄电池。

8. 发明授权

US6127064A Jar can for secondary battery 有权
标题翻译：罐可用于二次电池
公开(公告)号：US6127064A
公开(公告)日：2000-10-03
申请号：US138754
申请日：1998-08-24
申请人： Kenichiro Shibata , Yoshio Moriwaki , Isao Matsumoto
发明人： Kenichiro Shibata , Yoshio Moriwaki , Isao Matsumoto
IPC分类号： H01M2/02
CPC分类号： H01M2/0257 , H01M2/0217
摘要： A jar can for a secondary battery is formed by deep-drawing a clad material prepared by bonding an aluminum sheet and an iron sheet to each other. A nickel layer is formed between the iron sheet and the aluminum sheet. Another nickel layer is formed on another surface of the iron sheet. Thus, a lightweight jar can for a secondary battery having high rigidity is obtained.
摘要翻译：二次电池的罐可以通过将通过将铝板和铁板彼此粘合而制备的复合材料进行深冲压来形成。在铁板和铝板之间形成镍层。在铁板的另一个表面上形成另一个镍层。因此，获得了具有高刚度的二次电池的轻质罐罐。

9. 发明授权

US6153334A Active materials for the positive electrode in alkaline storage battery and the manufacturing method of them 有权
标题翻译：碱性蓄电池正极活性物质及其制备方法
公开(公告)号：US6153334A
公开(公告)日：2000-11-28
申请号：US129956
申请日：1998-08-06
申请人： Hiroyuki Sakamoto , Hidekatsu Izumi , Yoichi Izumi , Isao Matsumoto
发明人： Hiroyuki Sakamoto , Hidekatsu Izumi , Yoichi Izumi , Isao Matsumoto
IPC分类号： C01G53/00 , H01M4/52 , H01M4/32 , C01G1/00
CPC分类号： H01M4/52 , C01G53/00 , C01G53/006 , C01P2002/52 , C01P2002/72 , C01P2002/74 , C01P2004/84 , C01P2006/11 , C01P2006/14 , C01P2006/16 , C01P2006/40 , Y10T29/49108 , Y10T428/12007
摘要： The energy density of active materials for a positive electrode comprising an oxide containing Ni as a main metallic element is enhanced, and, moreover, a method for manufacturing them is provided. The oxide includes Ni as a main metallic element and contains at least Mn in the state of solid solution or eutectic mixture, wherein the average valence of Mn is 3.3 valences or more, the tap density is 1.7 g/cc or more, the half width of a peak at around 2.theta.=37-40.degree. of X-ray diffraction using CuK.alpha. ray is 1.2 deg or less, the ratio B/A of integrated intensity B of a peak at around 2.theta.=18-21.degree. to integrated intensity A of a peak at around 2.theta.=37-40.degree. is 1.25 or less, and the volume of pores having a pore radius of 40 .ANG. or less is 60% or more of the total pore volume. The oxide is obtained by growing in the state of keeping the dissolved oxygen concentration in the aqueous solution in the reaction vessel and then oxidizing the oxide.
摘要翻译：包含含有Ni作为主要金属元素的氧化物的正极活性物质的能量密度提高，而且还提供了制造它们的方法。氧化物包括Ni作为主要金属元素，并且至少包含处于固溶体或共晶混合物状态的Mn，其中Mn的平均价数为3.3以上，振实密度为1.7g / cc以上，半值宽度在使用CuKα射线的X射线衍射的2θ= 37-40°附近的峰为1.2度或更小，在2θ= 18-21度处的峰的积分强度B的比B / A与积分在大约2θ= 37-40°处的峰的强度A为1.25或更小，并且孔半径为40安培或更小的孔的体积为总孔体积的60％或更多。通过在保持反应容器中的水溶液中的溶解氧浓度，然后氧化氧化物的状态下生长而获得氧化物。

10. 发明授权

US6129902A Manufacturing method of active materials for the positive electrode in alkaline storage batteries 失效
标题翻译：碱性蓄电池正极活性物质的制造方法
公开(公告)号：US6129902A
公开(公告)日：2000-10-10
申请号：US17029
申请日：1998-02-02
申请人： Hiroyuki Sakamoto , Hidekatsu Izumi , Hirokazu Kimiya , Yoichi Izumi , Isao Matsumoto
发明人： Hiroyuki Sakamoto , Hidekatsu Izumi , Hirokazu Kimiya , Yoichi Izumi , Isao Matsumoto
IPC分类号： H01M4/52 , C01G49/00 , H01M4/36
CPC分类号： H01M4/52
摘要： A process for producing positive electrode active material includes feeding an aqueous nickel salt solution, aqueous solutions of different kinds of metals, aqueous solution containing ammonium ions and aqueous alkali solution each independently and simultaneously into a reaction vessel such that the amount of alkali metal is 1.9-2.3 moles relative to 1 mole of the total amount of nickel and different kinds of metals and the amount of ammonium ions is 2 moles or more relative to 1 mole of the total amount of nickel and different kinds of metals, the pH in the vessel is 11-13, the temperature in the vessel is 30-60.degree. C. and the average residence time is 20-50 hours. Further, in the process step of continuously growing the complex metal oxide particles from the salts of a plurality of metal elements through a plurality of successive reaction-deposition stages, the compositions and/or the kinds of the salts of metal element groups used for forming the oxide in the reaction-deposition stages adjacent to each other are made to be different from each other.
摘要翻译：制造正极活性物质的方法包括将镍盐水溶液，不同种类金属的水溶液，含有铵离子的水溶液和碱水溶液各自独立同时投入到反应容器中，使得碱金属的量为1.9 相对于1摩尔镍的总量和不同种类的金属，相对于1摩尔镍和不同种类的金属，铵离子的量为2摩尔或更大，相对于1摩尔的-2.3摩尔，容器中的pH 为11-13，容器中的温度为30-60℃，平均停留时间为20-50小时。此外，在通过多个连续反应沉积阶段从多个金属元素的盐连续生长复合金属氧化物颗粒的工艺步骤中，用于形成的金属元素基团的盐的组成和/或种类使彼此相邻的反应沉积阶段中的氧化物彼此不同。

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