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    • 1. 发明授权
    • Heat-sensitive recording material
    • 感应记录材料
    • US5240897A
    • 1993-08-31
    • US612751
    • 1990-11-13
    • Rosalinde BraunRudolf Zink
    • Rosalinde BraunRudolf Zink
    • B41M5/28B41M5/32B41M5/323B41M5/327
    • B41M5/32B41M5/323B41M5/327
    • A heat-sensitive recording material which contains(A) a polycyclic compound of the formula ##STR1## in which X is a monocyclic or polycyclic aromatic or heteroaromatic radical,Y is a substituent detachable as an anion,Q.sub.1 is --O--, --S--, >N--R or >N--NH--R,Q.sub.2 is --CH.sub.2 --, --CO--, --CS-- or --SO.sub.2 -- andR is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.10 cycloalkyl, aryl such as phenyl or aralkyl such as benzyl, andring A is an aromatic or heterocyclic radical having 6 ring atoms, which can have an aromatic fused ring, it being possible for both ring A and the fused ring to be substituted, and(B) an organic condensable complex compound of a zinc salt.
    • 一种热敏记录材料,其包含(A)式(1)的多环化合物,其中X为单环或多环芳族或杂芳族基团,Y为可作为阴离子取代的取代基,Q 1为-O- ,-S-,> NR或> N-NH-R,Q 2是-CH 2 - , - CO - , - CS-或-SO 2 - ,R 2是氢,C 1 -C 12烷基,C 5 -C 10环烷基,芳基如苯基或 芳烷基如苄基,环A是具有6个环原子的芳族或杂环基,其可以具有芳香稠环,环A和稠环都可以被取代,和(B)有机可冷凝络合物 锌盐的化合物。
    • 3. 发明授权
    • Bisphthalide lactones, their preparation and the use thereof in
recording materials
    • 二硫化IDE ES,S S S S S S S S S S S S S S S S S S S S S
    • US5162550A
    • 1992-11-10
    • US572929
    • 1990-08-24
    • Rudolf ZinkIan J. Fletcher
    • Rudolf ZinkIan J. Fletcher
    • B41M5/145B41M5/327C07D493/20C09B11/00C09B11/26
    • C07D493/20B41M5/145B41M5/327
    • Bisphthalide lactones of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, alkyl of at most 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxy, cyano, tetrahydrofuryl or lower alkoxy; or are acyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 10 carbon atoms or unsubstituted aralkyl or aryl, or aralkyl or aryl each substituted by halogen, cyano, nitro, trifluormethyl, lower alkyl, lower alkoxy, lower alkoxycarbonyl, --NX'X"-- or 4--NX'X--"phenylamino, wherein X' and X" are each independently of the other hydrogen, lower alkyl, cyclohexyl, benzyl or phenyl, or the pairs of substituents --NR.sub.1 R.sub.2 and --NR.sub.3 R.sub.4 are each a 5- or 6-membered, preferably saturated, heterocyclic radical, V.sub.1 and V.sub.2 are hydrogen, halogen, lower alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 -acyloxy, benzyl, phenyl, benzyloxy, phenyloxy, or benzyl or benzyloxy, each substituted by halogen, cyano, lower alkyl or lower alkoxy, or are the group --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.2 are each independently of the other hydrogen, lower alkyl, C.sub.5 -C.sub.10 cycloalkyl, unsubstituted benzyl or benzyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy, or are acyl of 1 to 8 carbon atoms, and T.sub.1 is also unsubstituted phenyl or phenyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy, and the rings A.sub.1 and A.sub.2 are each independently of the other an aromatic or heterocyclic radical of 6 ring atoms which may contain an aromatic fused ring, which rings A.sub.1 and A.sub.2 as well as the fused rings may be substituted.These bisphthalide lactones can be used as color forming components in pressure-sensitive or heat-sensitive recording materials and, when used in conjunction with a condensation component and an acid developer, form intense colored images.
    • 式(1)的双苯二酮内酯,其中R 1,R 2,R 3和R 4各自独立地为氢,至多12个碳原子的烷基,其未被取代或被卤素,羟基,氰基,四氢呋喃基或低级烷氧基取代; 或者是具有1至12个碳原子的酰基,5至10个碳原子的环烷基或未取代的芳烷基或芳基,或各自被卤素,氰基,硝基,三氟甲基,低级烷基,低级烷氧基,低级烷氧基羰基,-NX' X“ - 或4-NX'X - ”苯基氨基,其中X'和X“各自独立于另一个氢,低级烷基,环己基,苄基或苯基,或取代基-NR1R2和-NR3R4的对是 每个5-或6-元,优选饱和的杂环基,V1和V2是氢,卤素,低级烷基,C1-C12烷氧基,C1-C12-酰氧基,苄基,苯基,苄氧基,苯氧基或苄基或苄氧基, 被卤素,氰基,低级烷基或低级烷氧基取代,或是-NT1T2基团,其中T1和T2各自独立地为氢,低级烷基,C5-C10环烷基,未取代的苄基或被卤素取代的苄基,氰基 ,低级烷基或低级烷氧基,或为1至8个碳原子的酰基,且T1也为未取代的苯基或苯基 其被卤素,氰基,低级烷基或低级烷氧基取代,并且环A1和A2各自独立地为可以含有芳环的芳环或芳环稠合环的芳环或杂环基,其也环A1和A2 因为稠环可以被取代。 这些双苯酞内酯可用作压敏或热敏记录材料中的成色组分,并且当与缩合组分和酸显影剂结合使用时,形成强烈的彩色图像。
    • 4. 发明授权
    • Chromogenic quinazolines
    • 显色喹唑啉
    • US4766211A
    • 1988-08-23
    • US901090
    • 1986-08-27
    • Rudolf ZinkIan J. Fletcher
    • Rudolf ZinkIan J. Fletcher
    • B41M5/136B41M5/323C07D239/91C07D239/93C07D401/04C07D413/04C07D237/26
    • C07D239/91B41M5/136B41M5/323C07D401/04C07D413/04
    • Chromogenic quinazolines of formula ##STR1## wherein R is an aryl radical or a heterocyclic radical,Z.sub.1 is oxygen or sulfur,Z.sub.2 is oxygen, sulfur or ##STR2## R' is hydrogen, alkyl which is unsubstituted or substituted by halogen, cyano or lower alkoxy, or is cycloalkyl, phenyl, benzyl, phenethyl or acyl, or --NRR' is a 5- or 6-membered heterocyclic radical,Q is an aliphatic radical which may be interrupted by a further member Z.sub.2,Y is the radical of a couplable compound, and the ringA is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy or lower alkoxycarbonyl.These quinazolines are exceedingly fast to sublimation and are particularly suitable color formers in pressure-sensitive or heat-sensitive recording materials and give strong and lightfast yellow and orange colorations.
    • 式(1)的显色喹唑啉其中R是芳基或杂环基,Z 1是氧或硫,Z 2是氧,硫或R 3是氢,未被取代或被卤素取代的烷基, 氰基或低级烷氧基,或是环烷基,苯基,苄基,苯乙基或酰基,或-NRR'是5-或6-元杂环基,Q是可被另外的成员Z2中断的脂族基团,Y是 可结合的化合物的基团,并且环A是未取代的或被卤素,氰基,硝基,低级烷基,低级烷氧基或低级烷氧基羰基取代。 这些喹唑啉非常快速升华,特别适用于压敏或热敏记录材料中的成色剂,并提供强烈和耐光的黄色和橙色着色。
    • 6. 发明授权
    • Process for the preparation of 4,4′-dihalogen-o-hydroxydiphenyl compounds
    • 制备4,4'-二卤代-O-羟基二苯基化合物的方法
    • US06596907B1
    • 2003-07-22
    • US09806668
    • 2001-04-03
    • Armando Di TeodoroWerner HölzlDieter ReinehrRudolf Zink
    • Armando Di TeodoroWerner HölzlDieter ReinehrRudolf Zink
    • C07C4100
    • C07C41/16C07C41/22C07C41/26C07C43/23C07C43/29C07C43/295
    • A description is given of a three-step process for the preparation of 4,4′-dihalogen-o-hydroxydiphenyl compounds of formula (1) which comprises: a) hologenating an alkoxyphenol of formula (6) (=a1), reacting the resulting halogenated phenol compound of formula (5) with p-dihalobenzene of formula (4a) in the presence of copper and/or copper salts to the diphenyl ether compound of formula (2) (=a2) and subsequent ether fission to the diphenyl ether compound of formula (1) (=a3); or b) reacting an alkoxyphenol of formula (6) with the halophenol of formula (4b) to the compound of formula (3) (=b1), then halogenating this compound (=b2) and subsequent ether fission of the resulting compound of formula (2) to the diphenyl ether compound of formula (1) (=b3). The compounds of formula (1) are used for protecting organic materials and objects against microorganisms.
    • 给出了制备式(1)的4​​,4'-二卤代邻羟基二苯基化合物的三步法,其包括:a)使式(6)的烷氧基​​酚(= a1)氢化,使 得到式(5)的卤代酚化合物与式(4a)的对二卤苯在铜和/或铜盐存在下与式(2)(= a2)的二苯基醚化合物反应,随后醚裂解成二苯基醚 式(1)化合物(= a3); 或b)使式(6)的烷氧基​​酚与式(4b)的卤代酚反应到式(3)的化合物(= b1),然后将该化合物(= b2)卤化,随后将所得的式 (2)到式(1)的二苯醚化合物(= b3)。 式(1)化合物用于保护有机材料和物体免受微生物侵害。
    • 7. 发明授权
    • Chromogenic phthalides
    • 显色酞菁
    • US5143892A
    • 1992-09-01
    • US700002
    • 1991-05-14
    • Rudolf Zink
    • Rudolf Zink
    • B41M5/145B41M5/327C07D405/04C09B11/26
    • C09B11/26B41M5/145B41M5/327
    • Chromogenic phthalides of formula ##STR1## wherein X, R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.6 alkyl,Y.sub.1 is hydrogen, alkyl or not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or is acyl of 1 to 12 carbon atoms, benzyl or benzyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy,Y.sub.2 is hydrogen, lower alkyl or phenyl, andthe benzene rings A and B are each independently of the other unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkoxycarbonyl, amino, mono-lower alkylamino, di-lower alkylamino or lower alkanoylamino.These phthalides are particularly suitable for use as color formers in pressure-sensitive or heat-sensitive recording materials and give intense blue or violet blue colored images.
    • 式(1)的显色酞化物,其中X,R 1和R 2各自独立于其它C 3 -C 6烷基,Y 1是氢,烷基或不超过12个碳原子,未被取代或被卤素,羟基,氰基 或低级烷氧基,或为1至12个碳原子的酰基,被卤素,氰基,低级烷基或低级烷氧基取代的苄基或苄基,Y2为氢,低级烷基或苯基,苯环A和B各自独立地为 硝基,低级烷基,低级烷氧基,低级烷硫基,低级烷氧基羰基,氨基,单低级烷基氨基,二低级烷基氨基或低级烷酰基氨基取代。 这些苯酞特别适合用作压敏或热敏记录材料中的成色剂,并产生强烈的蓝色或紫色蓝色图像。
    • 8. 发明授权
    • Chromogenic phthalides
    • 显色酞菁
    • US5039822A
    • 1991-08-13
    • US395639
    • 1989-08-16
    • Rudolf Zink
    • Rudolf Zink
    • B41M5/145B41M5/327C07D405/04C09B11/26
    • C09B11/26B41M5/145B41M5/327
    • Chromogenic phthalides of formula ##STR1## wherein X, R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.6 alkyl,Y.sub.1 is hydrogen, alkyl of not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy, or is acyl or 1 of 12 carbon atoms, benzyl or benzyl which is substituted by halogen, cyano, lower alkyl or lower alkoxy,Y.sub.2 is hydrogen, lower alkyl or phenyl, andthe benzene rings A and B are each independently of the other unsubstituted or substituted by halogen, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkoxycarbonyl, amino, mono-lower alkylamino, di-lower alkylamino or lower alkanoylamino.These phthalides are particularly suitable for use as color formers in pressure-sensitive or heat-sensitive recording materials and give intense blue or violet blue colored images.
    • 式(1)的显色酞化物,其中X,R 1和R 2各自独立地为C 3 -C 6烷基,Y 1为氢,不超过12个碳原子的烷基,其未被取代或被卤素,羟基,氰基或 低级烷氧基,或是酰基或12个碳原子中的1个,被卤素,氰基,低级烷基或低级烷氧基取代的苄基或苄基,Y2是氢,低级烷基或苯基,苯环A和B各自独立地为 另一个未被取代或被卤素,硝基,低级烷基,低级烷氧基,低级烷硫基,低级烷氧基羰基,氨基,单低级烷基氨基,二低级烷基氨基或低级烷酰氨基取代。 这些苯酞特别适合用作压敏或热敏记录材料中的成色剂,并产生强烈的蓝色或紫色蓝色图像。