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    • 3. 发明申请
    • THERMOPLASTIC COMPOSITION HAVING IMPROVED SCRATCH RESISTANCE, AND ARTICLES FORMED THEREFROM
    • 具有改进的耐刮擦性的热塑性组合物及其形成的制品
    • US20080004404A1
    • 2008-01-03
    • US11427102
    • 2006-06-28
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • C08L69/00C08L53/00C08L67/00
    • C08L69/00C08L69/005C08L2666/18
    • A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
    • 热塑性组合物包含A)25至95重量份的第一聚碳酸酯,其基本上由以下组成:i)25至100摩尔%的包含烷基取代的双酚碳酸酯单元的第一碳酸酯单元,ii)0至75摩尔%的第二 碳酸酯单元,其中第一和第二碳酸酯单元不相同,第一和第二碳酸酯单元在第一聚碳酸酯中的摩尔百分比之和为100摩尔%; B)5〜75重量份碳酸酯单元与芳基酯单元的摩尔比为95:5〜10:90的聚酯 - 聚碳酸酯; 和C)0至65重量份的第二聚碳酸酯,其中第一聚碳酸酯和第二聚碳酸酯不相同,并且第一聚碳酸酯,聚酯 - 聚碳酸酯和第二聚碳酸酯的重量份之和为100份 重量。
    • 4. 发明授权
    • Polycarbonate composition having improved scratch resistance, and articles formed therefrom
    • 具有改进的耐刮擦性的聚碳酸酯组合物和由其形成的制品
    • US07700696B2
    • 2010-04-20
    • US11427102
    • 2006-06-28
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • C08L69/00
    • C08L69/00C08L69/005C08L2666/18
    • A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
    • 热塑性组合物包含A)25至95重量份的第一聚碳酸酯,其基本上由以下组成:i)25至100摩尔%的包含烷基取代的双酚碳酸酯单元的第一碳酸酯单元,ii)0至75摩尔%的第二 碳酸酯单元,其中第一和第二碳酸酯单元不相同,第一和第二碳酸酯单元在第一聚碳酸酯中的摩尔百分比之和为100摩尔%; B)5〜75重量份碳酸酯单元与芳基酯单元的摩尔比为95:5〜10:90的聚酯 - 聚碳酸酯; 和C)0至65重量份的第二聚碳酸酯,其中第一聚碳酸酯和第二聚碳酸酯不相同,并且第一聚碳酸酯,聚酯 - 聚碳酸酯和第二聚碳酸酯的重量份之和为100份 重量。
    • 6. 发明授权
    • Method of making a thermoplastic composition containing an antistatic agent
    • 制备含有抗静电剂的热塑性组合物的方法
    • US07309735B2
    • 2007-12-18
    • US11674373
    • 2007-02-13
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • C08J7/00
    • C07C303/32C08K5/50Y10S524/912C07C309/06
    • A method for preparing a thermoplastic composition containing an antistatic agent is described. The antistatic agent is a phosphonium sulfonate salt of generic formula (1) wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms. The phosphonium sulfonate salt is prepared by a method that includes combining in an aqueous medium a compound of generic formula (2) wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3) (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium. The phosphonium sulfonate salt is then combined with a thermoplastic resin.
    • 描述了制备含有抗静电剂的热塑性组合物的方法。 抗静电剂是通式(1)的鏻磺酸盐,其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p不为零,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基。 鏻磺酸盐的制备方法包括在水性介质中将通式(2)的化合物(其中M为Li或Na,X,q,p和r如上定义)与化学计量过量的 通式(3)的化合物<?in-line-formula description =“In-line Formulas”end =“lead”?(R)4 PZ(3) line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上定义; 和将式(1)的产物与介质分离。 然后将鏻磺酸盐与热塑性树脂组合。
    • 7. 发明申请
    • METHODS OF MAKING AN ANTISTATIC AGENT
    • 制造抗静电剂的方法
    • US20080269526A1
    • 2008-10-30
    • US12170097
    • 2008-07-09
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • C07F9/54
    • C07C303/32C07F9/5407C07C309/06C07C309/10
    • Disclosed are methods for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is 1 then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising the steps of combining in an aqueous medium, a compound of the generic formula (2): wherein M is K, and X, q, p, and r are as defined above, with a compound of the generic formula (3): (R)4P-Z   (3) wherein Z is a halogen and R is as defined above; and separating the phosphonium sulfonate of formula (1) from the aqueous medium. Also disclosed is an antistatic composition comprising phosphonium sulfonate (1), and articles prepared therefrom.
    • 公开了制备通式(1)的鏻磺酸盐的方法:其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p为1,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基,该方法包括以下步骤:在水性介质中混合通式(2)的化合物:其中M是K,X,q, p和r如上所定义,与通式(3)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?(R) PZ(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上所定义; 并将式(1)的磺酸鏻与水性介质分离。 还公开了包含磺酸鏻(1)和由其制备的制品的抗静电组合物。
    • 9. 发明授权
    • Methods of making an antistatic agent
    • 制造抗静电剂的方法
    • US07211690B2
    • 2007-05-01
    • US10966774
    • 2004-10-15
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • C07C313/00C07C309/00
    • C07C303/32C08K5/50Y10S524/912C07C309/06
    • A method for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising combining in an aqueous medium a compound of generic formula (2): wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3): (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium.
    • 制备通式(1)的鏻磺酸盐的方法:其中每个X独立地为卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p不为零,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基,该方法包括在水性介质中混合通式(2)的化合物:其中M是Li或Na,X,q,p和 r如上所定义,化学计量过量的通式(3)的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”→(R) PZ(3)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上定义; 和将式(1)的产物与介质分离。