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    • 3. 发明授权
    • Thermally stable, highly conductive salt
    • 热稳定,高导电性盐
    • US6015639A
    • 2000-01-18
    • US16608
    • 1998-01-30
    • Feng GaoJeremy BarkerPeikang Liu
    • Feng GaoJeremy BarkerPeikang Liu
    • H01B1/12H01M10/0525H01M10/0568H01M6/18
    • H01M10/0568H01B1/122H01M10/0525
    • The invention provides a new family of compounds and a method of making the compounds. The new compounds are useful as ion conductive salts, and particularly useful as salts for batteries. The compounds of the invention are prepared from three principal reagents, bis (trifluoromethanesufonyl) methane (CF.sub.3 SO.sub.2).sub.2 CH.sub.2 ; benzoyl chloride; and pyridine which facilitates reaction and then is removed. A precursor sodium salt (CF.sub.3 SO.sub.2).sub.2 CHNa is first prepared. Then, equimolar amounts of the precursor sodium salt and pyridine are dissolved in anhydrous acetonitrile. A stoichiometric amount of the selected substitute benzoyl chloride is then added drop by drop. After addition of Li.sub.3 PO.sub.4, there is pyridine release and formation of the product of the aforesaid two reagents. In the benzene ring, R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are each identical or different and are each independently selected from hydrogen and an electron withdrawing substituent.
    • 本发明提供一种新的化合物族和一种制备该化合物的方法。 新化合物可用作离子导电盐,并且特别用作电池的盐。 本发明的化合物由三种主要试剂,二(三氟甲磺酰基)甲烷(CF 3 SO 2)2 CH 2; 苯甲酰氯; 和吡啶,这有助于反应然后被除去。 首先制备前体钠盐(CF 3 SO 2)2 CHNa。 然后将等摩尔量的前体钠盐和吡啶溶于无水乙腈中。 然后逐滴加入化学计量的所选择的替代苯甲酰氯。 添加Li3PO4后,存在吡啶释放并形成上述两种试剂的产物。 在苯环中,R 1,R 2,R 3,R 4和R 5各自相同或不同,各自独立地选自氢和吸电子取代基。
    • 10. 发明授权
    • Composition for forming electrode active material of lithium secondary battery, composition for forming separator and method of preparing lithium secondary battery using the compositions
    • 用于形成锂二次电池的电极活性材料的组合物,用于形成隔膜的组合物和使用该组合物制备锂二次电池的方法
    • US06692873B1
    • 2004-02-17
    • US09629951
    • 2000-08-01
    • Chi-kyun ParkArchana KakirdePeikang LiuVenkatesan ManivannanChul ChaiDong-joon IhmJon-ha LeeKwon-sun Roh
    • Chi-kyun ParkArchana KakirdePeikang LiuVenkatesan ManivannanChul ChaiDong-joon IhmJon-ha LeeKwon-sun Roh
    • H01M216
    • H01M2/145H01M2/1653H01M2/1673H01M10/04H01M10/052Y10T29/49115
    • An electrode active material forming composition, a separator forming composition and a manufacturing method of a lithium secondary battery using the compositions are provided. The method for manufacturing a lithium secondary battery including the steps of (a) coating electrode active material compositions each comprising a electrode active material, a binder and a solvent on an electrode current collector to form a cathode and an anode, (b) forming a separator on both surfaces of the anode using a composition for forming a separator comprising a polymer resin, a plasticizer, a filler and a solvent; (c) disposing and fixedly adhering the cathode on the separator to form a battery structure, (d) drying the battery structure under a vacuum condition, and (e) impregnating an electrolytic solution into the resultant structure, wherein the plasticizer of the composition for forming the separator is at least one material selected from the group consisting of an ethylene glycol derivative, a cyclic carbonate, a non-cyclic carbonate and propylene glycol carbonate. Therefore, since a plasticizer can be removed under a vacuum condition, the time required for manufacturing a battery can be reduced and the manufacturing process becomes simplified, thereby improving the productivity. Also, since an organic solvent extraction process using an organic solvent is not necessary, unlike in the conventional art, the cost required for a recovery facility of an organic solvent can be reduced. Further, uniform pores are formed in electrodes and a separator, the porosity characteristics are excellent, and adhesion between the separator and the electrodes is excellent, thereby exhibiting excellent high-rate, lifetime, and low-temperature characteristics.
    • 提供电极活性物质形成组合物,隔膜形成用组合物和使用该组合物的锂二次电池的制造方法。 一种锂二次电池的制造方法,包括以下步骤:(a)在电极集电体上涂布均包含电极活性物质,粘合剂和溶剂的电极活性物质组合物,形成阴极和阳极,(b) 使用用于形成包含聚合物树脂,增塑剂,填料和溶剂的隔膜的组合物的阳极的两个表面上的隔板; (c)将阴极设置并固定在隔板上以形成电池结构,(d)在真空条件下干燥电池结构,和(e)将电解液浸渍到所得结构中,其中用于 形成隔膜的是至少一种选自乙二醇衍生物,环状碳酸酯,非环状碳酸酯和丙二醇碳酸酯的材料。 因此,由于可以在真空条件下去除增塑剂,所以可以减少制造电池所需的时间,并且制造过程变得简化,从而提高生产率。 此外,由于不需要使用有机溶剂的有机溶剂萃取方法,与常规技术不同,可以降低有机溶剂的回收设备所需的成本。 此外,在电极和隔膜中形成均匀的孔,孔隙率特性优异,隔板和电极之间的粘附性优异,因此表现出优异的高速率,寿命和低温特性。