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1. 发明申请

US20100155293A1 HYDROCRACKING PROCESS INCLUDING SWITCHABLE REACTORS WITH FEEDSTOCKS CONTAINING 200 PPM BY WEIGHT - 2% BY WEIGHT OF ASPHALTENES 有权
标题翻译：包含可切换反应器的水力加工过程，含有重量为200 PPM的料斗 - 按重量百分比计的2％
公开(公告)号：US20100155293A1
公开(公告)日：2010-06-24
申请号：US12640202
申请日：2009-12-17
申请人： Jan Jeroum Verstraete , Hugues Dulot , Fabrice Bertoncini , Eric Sanchez
发明人： Jan Jeroum Verstraete , Hugues Dulot , Fabrice Bertoncini , Eric Sanchez
IPC分类号： C10G65/12
CPC分类号： C10G65/12 , C10G45/08 , C10G47/12
摘要： The invention relates to a process for hydrocracking hydrocarbon feedstocks having 200 ppm by weight to 2% by weight of asphaltenes and/or more than 10 ppm by weight of metals, comprising a hydrodemetallation treatment in at least 2 switchable reaction zones, containing hydrodemetallation catalyst and optionally hydrodenitrification catalyst, then a hydrorefining treatment to lower the organic nitrogen content, followed by a fixed-bed hydrocracking treatment and a distillation step.
摘要翻译：本发明涉及用于加氢裂化烃原料的方法，其具有200重量ppm至2重量％的沥青质和/或大于10重量ppm的金属，包括在至少2个可切换的反应区中进行加氢脱金属处理，其包含加氢脱金属催化剂和任选加氢脱氮催化剂，然后进行加氢精制处理以降低有机氮含量，随后进行固定床加氢裂化处理和蒸馏步骤。

2. 发明授权

US09523049B2 Hydrocracking process including switchable reactors with feedstocks containing 200 ppm by weight—2% by weight of asphaltenes 有权
标题翻译：加氢裂化过程包括可转换的反应器，原料含有200ppm（重量）-2％（重量）的沥青质
公开(公告)号：US09523049B2
公开(公告)日：2016-12-20
申请号：US12640202
申请日：2009-12-17
申请人： Jan Jeroum Verstraete , Hugues Dulot , Fabrice Bertoncini , Eric Sanchez
发明人： Jan Jeroum Verstraete , Hugues Dulot , Fabrice Bertoncini , Eric Sanchez
IPC分类号： C10G65/12 , C10G45/08 , C10G47/12
CPC分类号： C10G65/12 , C10G45/08 , C10G47/12
摘要： The invention relates to a process for hydrocracking hydrocarbon feedstocks having 200 ppm by weight to 2% by weight of asphaltenes and/or more than 10 ppm by weight of metals, comprising a hydrodemetallation treatment in at least 2 switchable reaction zones, containing hydrodemetallation catalyst and optionally hydrodenitrification catalyst, then a hydrorefining treatment to lower the organic nitrogen content, followed by a fixed-bed hydrocracking treatment and a distillation step.
摘要翻译：本发明涉及用于加氢裂化烃原料的方法，其具有200重量ppm至2重量％的沥青质和/或大于10重量ppm的金属，包括在至少2个可切换的反应区中进行加氢脱金属处理，其包含加氢脱金属催化剂和任选加氢脱氮催化剂，然后进行加氢精制处理以降低有机氮含量，随后进行固定床加氢裂化处理和蒸馏步骤。

3. 发明申请

US20080180447A1 METHOD FOR CARRYING OUT A QUANTITATIVE ANALYSIS OF A MIXTURE OF MOLECULAR COMPOUNDS BY TWO-DIMENSIONAL GAS CHROMATOGRAPHY 失效
标题翻译：通过二维气相色谱法分析化合物混合物的定量分析方法
公开(公告)号：US20080180447A1
公开(公告)日：2008-07-31
申请号：US12022216
申请日：2008-01-30
申请人： Fabrice Bertoncini , Benoit Celse , Laurent Duval
发明人： Fabrice Bertoncini , Benoit Celse , Laurent Duval
IPC分类号： G06T11/00
CPC分类号： G01N30/86 , G01N30/463 , G01N30/8631 , G01N2030/025 , G01N2030/862
摘要： The Invention is a method for quantitative analysis of a mixture of molecular compounds by two-dimensional gas chromatography having application for quantitative analysis of products from the chemical or petroleum industry. A two-dimensional gas chromatography is carried out, during which a chromatographic signal is recorded. A chromatogram in two dimensions on which chromatographic peaks form spots is generated from the signal. These spots are defined by means of polygons. Then, for each polygon, chromatographic signal portions contained between two intersections of the polygon with columns of the chromatogram are extracted. Start and end times are defined for the chromatographic peaks present in these portions and the polygon is adjusted by shifting its intersection points according to the start and end times of the chromatographic peaks. Finally, molecular compound amounts are determined by calculating the surface area of the polygons thus adjusted.
摘要翻译：本发明是通过二维气相色谱法对分子化合物的混合物进行定量分析的方法，其用于定量分析来自化学或石油工业的产物。进行二维气相色谱，在此期间记录色谱信号。从信号中产生色谱峰形成斑点的二维色谱图。这些点是通过多边形定义的。然后，对于每个多边形，提取包含多边形的两个交点与色谱图列之间的色谱信号部分。对这些部分中存在的色谱峰定义开始和结束时间，并根据色谱峰的开始和结束时间移动其交点来调整多边形。最后，通过计算如此调整的多边形的表面积来确定分子化合物量。

4. 发明申请

US20110230691A1 LACUNARY KEGGIN TYPE HETEROPOLYANION BASED ON TUNGSTEN FOR HYDROCRACKING 有权
标题翻译：基于TUNGSTEN用于水力裂化的LACUNICAL KEGGIN类型异构体
公开(公告)号：US20110230691A1
公开(公告)日：2011-09-22
申请号：US13059254
申请日：2009-07-29
申请人： Audrey Bonduelle , Fabrice Bertoncini , Karima Ben Tayeb , Carole Lamonier , Michel Fournier , Edmond Payen
发明人： Audrey Bonduelle , Fabrice Bertoncini , Karima Ben Tayeb , Carole Lamonier , Michel Fournier , Edmond Payen
IPC分类号： C07C5/10 , B01J27/188 , B01J21/06 , B01J21/02 , C01B33/20 , B01J37/30 , C10G11/04
CPC分类号： C01G41/006 , B01J23/002 , B01J23/888 , B01J27/188 , B01J37/0213 , B01J37/20 , B01J37/30 , B01J2523/00 , C01G53/006 , C01P2002/82 , C01P2002/86 , C10G45/08 , C10G47/12 , C10G49/04 , B01J2523/51 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y,zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.
摘要翻译：本发明描述了由其结构中包含钨的缺口Keggin型杂多阴离子的镍盐构成的杂多化合物，其结构为：Nix + y / 2AW11-yO39-5 / 2y，zH2O，其中Ni是镍，A选自磷，硅和硼，W是钨，O是氧，y = 0或2，如果A是磷，x = 3.5，如果A是硅，x = 4，如果A是硅则x = 4.5，如果A是硼则x = 4.5，并且x = m / 2 + 2 其余，z为0〜36的数，其中所述杂多化合物在其结构中不具有取代钨原子的镍原子，所述镍原子位于所述化合物的结构中的反离子位置。

5. 发明授权

US07872165B2 Methods of hydrotreating a mixture made up of oils of animal or vegetable origin and of petroleum cuts with intermediate stripping 有权
标题翻译：将由动物或植物来源的油组成的混合物加氢处理的方法和具有中间剥离的石油馏分
公开(公告)号：US07872165B2
公开(公告)日：2011-01-18
申请号：US11962760
申请日：2007-12-21
申请人： Fabrice Bertoncini , Karin Marchand
发明人： Fabrice Bertoncini , Karin Marchand
IPC分类号： C07C1/00 , C10G49/02
CPC分类号： C10G65/04 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/08 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/42 , Y02P30/20
摘要： A hydrotreating method (HDT) utilizes two plants working under different operating conditions with an intermediate stripping for co-treating a mixture made up of oils of vegetable or animal origin and petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil fuel bases meeting specifications. The first plant (HDT1) is more particularly dedicated to the reactions concerning oils of vegetable or animal origin in comixture while pretreating the hydrocarbon feed, whereas the second plant (HDS2) works under more severe conditions to obtain diesel fuel according to standards, in particular in terms of effluent sulfur content, density and cold properties.
摘要翻译：加氢处理方法（HDT）利用两种在不同操作条件下工作的植物，其中间剥离剂用于共同处理由植物或动物来源的油组成的混合物和石油馏分（瓦斯油馏分（GO油）和中间馏分）），以便生产满足规格的瓦斯油燃料基地。第一种植物（HDT1）更特别致力于在预处理烃类饲料的同时对植物或动物来源的油料进行反应，而第二种植物（HDS2）在更恶劣的条件下工作，以根据标准获得柴油，特别是在流出物硫含量，密度和冷特性方面。

6. 发明申请

US20080173570A1 METHODS OF HYDROTREATING A MIXTURE MADE UP OF OILS OF ANIMAL OR VEGETABLE ORIGIN AND OF PETROLEUM CUTS WITH QUENCH INJECTION OF THE OILS ON THE LAST CATALYST BED 有权
标题翻译：将动物或植物原料油和石油精油混合物加入到最后催化床上油的注入方法
公开(公告)号：US20080173570A1
公开(公告)日：2008-07-24
申请号：US11962770
申请日：2007-12-21
申请人： Karin Marchand , Fabrice Bertoncini
发明人： Karin Marchand , Fabrice Bertoncini
IPC分类号： C10G47/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/54 , C10G45/02 , C10G45/08 , C10G49/002 , C10G65/04 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/42 , Y02P30/20
摘要： A hydrotreating method uses two catalyst beds with the introduction, on the last catalyst bed, of oils of animal or vegetable origin for co-treating a mixture made up of oils of vegetable or animal origin and of petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil effluents meeting specifications with an improved cetane number. The first catalyst bed is dedicated to only the deep desulfurization reactions (HDS1) of a petroleum type feed. The effluents of the first catalyst bed having an effluent sulfur content below or equal to 50 mg/kg are separated into two streams. The first stream, which is predominant, is sent to the gas oil pool. The second stream is mixed with oils of vegetable or animal origin. The resultant oil-petroleum cut mixture is then subjected to a milder hydrotreatment (HDT2). The effluents obtained at the outlet of the second catalyst bed can optionally be mixed with the predominant stream from the first bed. The process economy, the tolerance to the specifications relative to oils of animal or vegetable origin and the quality of the products obtained are thus greatly improved.
摘要翻译：加氢处理方法使用两个催化剂床，在最后的催化剂床上引入动物或植物来源的油，用于共同处理由植物或动物来源的油组成的混合物和油馏分（瓦斯油馏分（GO）和中间馏分），以生产满足具有改进的十六烷值的规格的瓦斯油废水。第一个催化剂床仅用于石油型进料的深度脱硫反应（HDS 1）。流出物硫含量低于或等于50mg / kg的第一催化剂床的流出物被分成两股。主要的第一流被送到瓦斯油池。第二流与植物或动物来源的油混合。然后将所得油 - 石油馏分混合物进行较温和的加氢处理（HDT 2）。在第二催化剂床的出口处获得的流出物可以任选地与来自第一床的主要流混合。因此，过程经济性，相对于动植物来源的油的规格的容忍度和获得的产品的质量大大提高。

7. 发明授权

US08301397B2 Method of determining physico-chemical properties of a petroleum sample from two-dimensional gas chromatography 失效
标题翻译：从二维气相色谱法测定石油样品的物理化学性质的方法
公开(公告)号：US08301397B2
公开(公告)日：2012-10-30
申请号：US12464125
申请日：2009-05-12
申请人： Fabrice Bertoncini , Benoît Celse , Cyril Dartiguelongue
发明人： Fabrice Bertoncini , Benoît Celse , Cyril Dartiguelongue
IPC分类号： G01N31/00
CPC分类号： G01N30/463 , G01N30/8675 , G01N30/8693 , G01N33/2811 , G01N33/2829 , G01N2030/025
摘要： A method of determining physico-chemical properties of a petroleum sample from two-dimensional gas chromatography. The amounts of molecular compounds present in the sample are determined by means of two-dimensional gas chromatography. At least one physical property, such as the octane number, is then determined from these amounts. A previously calibrated relation connecting the physical property to the amounts is used to this end.
摘要翻译：从二维气相色谱法测定石油样品的物理化学性质的方法。存在于样品中的分子化合物的量通过二维气相色谱法测定。然后从这些量确定至少一种物理性质，例如辛烷值。为此，使用了将物理属性与数量相连接的先前校准的关系。

8. 发明授权

US07781629B2 Methods of hydrotreating a mixture made up of oils of animal or vegetable origin and of petroleum cuts with quench injection of the oils on the last catalyst bed 有权
标题翻译：将由动物或植物来源的油组成的混合物加氢处理的方法和在最后一个催化剂床上骤冷注入油的石油馏分
公开(公告)号：US07781629B2
公开(公告)日：2010-08-24
申请号：US11962770
申请日：2007-12-21
申请人： Karin Marchand , Fabrice Bertoncini
发明人： Karin Marchand , Fabrice Bertoncini
IPC分类号： C07C1/00 , C10G25/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/54 , C10G45/02 , C10G45/08 , C10G49/002 , C10G65/04 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/42 , Y02P30/20
摘要： A hydrotreating method uses two catalyst beds with the introduction, on the last catalyst bed, of oils of animal or vegetable origin for co-treating a mixture made up of oils of vegetable or animal origin and of petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil effluents meeting specifications with an improved cetane number. The first catalyst bed is dedicated to only the deep desulfurization reactions (HDS1) of a petroleum type feed. The effluents of the first catalyst bed having an effluent sulfur content below or equal to 50 mg/kg are separated into two streams. The first stream, which is predominant, is sent to the gas oil pool. The second stream is mixed with oils of vegetable or animal origin. The resultant oil-petroleum cut mixture is then subjected to a milder hydrotreatment (HDT2). The effluents obtained at the outlet of the second catalyst bed can optionally be mixed with the predominant stream from the first bed. The process economy, the tolerance to the specifications relative to oils of animal or vegetable origin and the quality of the products obtained are thus greatly improved.
摘要翻译：加氢处理方法使用两个催化剂床，在最后的催化剂床上引入动物或植物来源的油，用于共同处理由植物或动物来源的油组成的混合物和油馏分（瓦斯油馏分（GO）和中间馏分），以生产满足具有改进的十六烷值的规格的瓦斯油废水。第一个催化剂床仅用于石油类饲料的深度脱硫反应（HDS1）。流出物硫含量低于或等于50mg / kg的第一催化剂床的流出物被分成两股。主要的第一流被送到瓦斯油池。第二流与植物或动物来源的油混合。然后将所得油 - 石油馏分混合物进行较温和的加氢处理（HDT2）。在第二催化剂床的出口处获得的流出物可以任选地与来自第一床的主要流混合。因此，过程经济性，相对于动植物来源的油的规格的容忍度和获得的产品的质量大大提高。

9. 发明授权

US08633128B2 Lacunary Keggin type heteropolyanion based on tungsten for hydrocracking 有权
标题翻译：基于钨用于加氢裂化的Lacunary Keggin型杂多阴离子
公开(公告)号：US08633128B2
公开(公告)日：2014-01-21
申请号：US13059254
申请日：2009-07-29
申请人： Audrey Bonduelle , Fabrice Bertoncini , Karima Ben Tayeb , Carole Lamonier , Michel Fournier , Edmond Payen
发明人： Audrey Bonduelle , Fabrice Bertoncini , Karima Ben Tayeb , Carole Lamonier , Michel Fournier , Edmond Payen
IPC分类号： B01J21/02 , B01J27/00 , B01J27/19 , B01J27/185 , B01J27/182 , B01J29/70 , C10G47/00 , C10G47/02 , C10G47/24 , C10G11/00 , C10G11/02 , C10G45/00
CPC分类号： C01G41/006 , B01J23/002 , B01J23/888 , B01J27/188 , B01J37/0213 , B01J37/20 , B01J37/30 , B01J2523/00 , C01G53/006 , C01P2002/82 , C01P2002/86 , C10G45/08 , C10G47/12 , C10G49/04 , B01J2523/51 , B01J2523/69 , B01J2523/847 , B01J2523/41
摘要： The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y, zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.
摘要翻译：本发明描述了由其结构中包含钨的缺口Keggin型杂多阴离子的镍盐构成的杂多化合物，其结构为：Nix + y / 2AW11-yO39-5 / 2y，zH2O，其中Ni是镍，A选自磷，硅和硼，W是钨，O是氧，y = 0或2，如果A是磷，x = 3.5，如果A是硅，x = 4，如果A是硅则x = 4.5，如果A是硼则x = 4.5，并且x = m / 2 + 2 其余，z为0〜36的数，其中所述杂多化合物在其结构中不具有取代钨原子的镍原子，所述镍原子位于所述化合物的结构中的反离子位置。

10. 发明授权

US08027792B2 Method for carrying out a quantitative analysis of a mixture of molecular compounds by two-dimensional gas chromatography 失效
标题翻译：通过二维气相色谱法对分子化合物的混合物进行定量分析的方法
公开(公告)号：US08027792B2
公开(公告)日：2011-09-27
申请号：US12022216
申请日：2008-01-30
申请人： Fabrice Bertoncini , Benoît Celse , Laurent Duval
发明人： Fabrice Bertoncini , Benoît Celse , Laurent Duval
IPC分类号： G01N31/00
CPC分类号： G01N30/86 , G01N30/463 , G01N30/8631 , G01N2030/025 , G01N2030/862
摘要： The Invention is a method for quantitative analysis of a mixture of molecular compounds by two-dimensional gas chromatography having application for quantitative analysis of products from the chemical or petroleum industry. A two-dimensional gas chromatography is carried out, during which a chromatographic signal is recorded. A chromatogram in two dimensions on which chromatographic peaks form spots is generated from the signal. These spots are defined by means of polygons. Then, for each polygon, chromatographic signal portions contained between two intersections of the polygon with columns of the chromatogram are extracted. Start and end times are defined for the chromatographic peaks present in these portions and the polygon is adjusted by shifting its intersection points according to the start and end times of the chromatographic peaks. Finally, molecular compound amounts are determined by calculating the surface area of the polygons thus adjusted.
摘要翻译：本发明是通过二维气相色谱法对分子化合物的混合物进行定量分析的方法，其用于定量分析来自化学或石油工业的产物。进行二维气相色谱，在此期间记录色谱信号。从信号中产生色谱峰形成斑点的二维色谱图。这些点是通过多边形定义的。然后，对于每个多边形，提取包含多边形的两个交点与色谱图列之间的色谱信号部分。对这些部分中存在的色谱峰定义开始和结束时间，并根据色谱峰的开始和结束时间移动其交点来调整多边形。最后，通过计算如此调整的多边形的表面积来确定分子化合物量。

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