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1. 发明授权

US4292201A Preparation of vanadium(IV)bis(metaphosphate) hydrocarbon oxidation catalyst containing an actinide or lanthanide series metal 失效
标题翻译：含有锕系元素或镧系金属的钒（Ⅳ）双（偏磷酸）烃氧化催化剂的制备
公开(公告)号：US4292201A
公开(公告)日：1981-09-29
申请号：US105364
申请日：1979-12-19
申请人： James C. Vartuli , Lee R. Zehner
发明人： James C. Vartuli , Lee R. Zehner
IPC分类号： B01J23/22 , B01J27/198 , C07C51/25 , B01J27/14 , B01J31/02 , C07D307/60
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J27/198 , C07C51/25 , B01J2523/00
摘要： A method for the preparation of a cerium or thorium (lanthanide or actinide metal) promoted single phase vanadium(IV)bis(metaphosphate) catalyst useful for the vapor phase oxidation of hydrocarbons and particularly the oxidation of linear C.sub.4 unsaturated olefins to prepare maleic anhydride.
摘要翻译：用于制备铈或钍（镧系元素或锕系金属）的方法促进用于烃的气相氧化的单相钒（Ⅳ）双（偏磷酸盐）催化剂，特别是线性C 4不饱和烯烃的氧化以制备马来酸酐。

2. 发明授权

US4276197A Preparation of a titanium promoted VO(PO.sub.3).sub.2 oxidation catalyst 失效
标题翻译：制备钛促进的VO（PO3）2氧化催化剂
公开(公告)号：US4276197A
公开(公告)日：1981-06-30
申请号：US105365
申请日：1979-12-19
申请人： James C. Vartuli , Lee R. Zehner
发明人： James C. Vartuli , Lee R. Zehner
IPC分类号： B01J23/22 , B01J27/198 , C07C51/25 , B01J27/14 , B01J31/02
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J27/198 , C07C51/25 , B01J2523/00
摘要： A method for the preparation of a titanium promoted single phase vanadium(IV)bis(metaphosphate) catalyst useful for the vapor phase oxidation of a linear C.sub.4 unsaturated olefins to prepare maleic anhydride.
摘要翻译：一种用于制备钛促进的单相钒（Ⅳ）双（偏磷酸盐）催化剂的方法，该催化剂可用于气相氧化线性C 4不饱和烯烃以制备马来酸酐。

3. 发明授权

US4292202A Preparation of a vanadium(IV)bis(metaphosphate) hydrocarbon oxidation catalyst containing a group VIB metal promoter 失效
标题翻译：制备含有VIB族金属促进剂的钒（Ⅳ）双（偏磷酸）烃氧化催化剂
公开(公告)号：US4292202A
公开(公告)日：1981-09-29
申请号：US105366
申请日：1979-12-19
申请人： James C. Vartuli , Lee R. Zehner
发明人： James C. Vartuli , Lee R. Zehner
IPC分类号： B01J27/199 , C07C51/25 , B01J27/14 , B01J31/02 , C07D307/60
CPC分类号： C07C51/252 , B01J23/002 , B01J27/199 , C07C51/25 , B01J2523/00
摘要： A method for the preparation of a chromium, molybdenum or tungsten (Group VIB metal) promoted single phase vanadium(IV)bis(metaphosphate) catalyst useful for the vapor phase oxidation of hydrocarbons and particularly the oxidation of linear C.sub.4 unsaturated olefins to prepare maleic anhydride.
摘要翻译：用于制备铬，钼或钨（VIB族金属）的方法促进用于烃的气相氧化的单相钒（IV）双（偏磷酸盐）催化剂，特别是线性C 4不饱和烯烃的氧化以制备马来酸酐。

4. 发明授权

US4273677A Preparation of thallium promoted VO(PO.sub.3).sub.2 oxidation catalyst 失效
标题翻译：铊促进VO（PO3）2氧化催化剂的制备
公开(公告)号：US4273677A
公开(公告)日：1981-06-16
申请号：US105367
申请日：1979-12-19
申请人： James C. Vartuli , Lee R. Zehner
发明人： James C. Vartuli , Lee R. Zehner
IPC分类号： B01J27/198 , C07C51/25 , B01J27/14 , B01J31/02
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J2523/00
摘要： A method for the preparation of a thallium promoted single phase vanadium(IV)bis(metaphosphate) catalyst useful for the vapor phase oxidation of linear C.sub.4 unsaturated olefins to prepare maleic anhydride.
摘要翻译：一种用于制备铊促进的单相钒（Ⅳ）双（偏磷酸盐）催化剂的方法，该催化剂可用于线性C 4不饱和烯烃的气相氧化以制备马来酸酐。

5. 发明授权

US4247419A Single phase vanadium(IV)bis(metaphosphate) oxidation catalyst with improved intrinsic surface area 失效
标题翻译：单相钒（IV）双（偏磷酸）氧化催化剂具有改善的固有表面积
公开(公告)号：US4247419A
公开(公告)日：1981-01-27
申请号：US102818
申请日：1979-12-13
申请人： James C. Vartuli , Lee R. Zehner
发明人： James C. Vartuli , Lee R. Zehner
IPC分类号： B01J27/198 , B01J29/076 , C07C51/25 , B01J27/14 , B01J27/02 , B01J31/02 , C01B15/16
CPC分类号： C07C51/252 , B01J23/002 , B01J27/198 , B01J29/076 , B01J2523/00
摘要： A method for the preparation of a single phase crystalline vanadium(IV)bis(metaphosphate), VO(PO.sub.3).sub.2, catalyst having an improved intrinsic surface area of from about 5 to 15 m.sup.2 /g. and useful for the vapor phase oxidation of linear C.sub.4 unsaturated olefins, such as n-butenes, to prepare maleic anhydride.
摘要翻译：制备单相结晶钒（Ⅳ）双（偏磷酸盐），VO（PO3）2）的催化剂，其具有改善的本征表面积为约5至15m2 / g。并且可用于线性C 4不饱和烯烃如正丁烯的气相氧化以制备马来酸酐。

6. 发明授权

US4236023A Preparation of unsaturated monoesters by the catalytic oxidative carbonylation of diolefins with an enol ether or 1-alkoxycycloalkene 失效
标题翻译：通过二烯烃与烯醇醚或1-烷氧基环烯烃的催化氧化羰基化制备不饱和单酯
公开(公告)号：US4236023A
公开(公告)日：1980-11-25
申请号：US52272
申请日：1979-06-26
申请人： Haven S. Kesling, Jr. , Lee R. Zehner
发明人： Haven S. Kesling, Jr. , Lee R. Zehner
IPC分类号： C07C45/51 , C07C67/36
CPC分类号： C07C45/513
摘要： A process for the preparation of an unsaturated monoester having the formula ##STR1## wherein R is an alkyl group of from 1 to 4 carbon atoms and R' is hydrogen, a halogen or a methyl group, by reacting carbon monoxide, oxygen, and at least a stoichiometric amount of an enol ether, or a 1-alkoxycycloalkene dehydrating agent with a diolefin having the formula ##STR2## wherein R' is as hereinabove described, in the presence of a catalytic amount of a platinum group metal compound and a copper or iron oxidant salt compound.Alternatively, a ligand or coordination complex compound of the metal salt compound and catalytic quantitites of an alcohol may be employed.
摘要翻译：制备具有式“IMAGE”的不饱和单酯的方法，其中R是1至4个碳原子的烷基，R'是氢，卤素或甲基，通过使一氧化碳，氧气和在催化量的铂族金属化合物和铜的存在下，至少一种化学计量量的烯醇醚或具有式“IMAGE”的二烯烃的1-烷氧基环烯烃脱水剂，其中R'如上所述，铁氧化剂盐化合物。或者，可以使用金属盐化合物的配体或配位络合物和醇的催化量。

7. 发明授权

US4005130A Preparation of oxalate esters from carbon monoxide and alcohol over a metal catalyst and a dione oxidant 失效
标题翻译：从一氧化碳和醇在金属催化剂和二酮氧化剂上制备草酸酯
公开(公告)号：US4005130A
公开(公告)日：1977-01-25
申请号：US590527
申请日：1975-06-26
申请人： Lee R. Zehner
发明人： Lee R. Zehner
IPC分类号： C07C69/36
CPC分类号： C07C69/36
摘要： A process for the preparation of oxalate esters by the oxidative carbonylation of alcohols with carbon monoxide in the presence of a catalytic amount of copper, nickel, cadmium, cobalt or zinc metal salt catalyst and at least a stoichiometric amount of an unsubstituted or halogen substituted 2,5-cyclohexadiene-1,4-dione. High yields and selectivity of the oxalate ester, over the carbonate ester and CO.sub.2, are obtained and maximized by regulating temperature, carbon monoxide pressure and metal salt catalyst and by maintaining substantially anhydrous conditions.
摘要翻译：一种通过在催化量的铜，镍，镉，钴或锌金属盐催化剂存在下用一氧化碳氧化羰基化醇和至少化学计量的未取代或卤素取代的2位的草酸酯的制备方法，5-环己二烯-1,4-二酮。通过调节温度，一氧化碳压力和金属盐催化剂以及维持基本上无水的条件，可以获得草酸酯与碳酸酯和CO 2的高产率和选择性。

8. 发明授权

US5690950A Insecticidal aliphatic carboxylic acid compositons 失效
标题翻译：杀虫脂肪族羧酸组合物
公开(公告)号：US5690950A
公开(公告)日：1997-11-25
申请号：US725982
申请日：1996-10-04
申请人： James R. Beadle , Lee R. Zehner , Gilbert V. Levin , James P. Saunders , Robert C. Bozsa
发明人： James R. Beadle , Lee R. Zehner , Gilbert V. Levin , James P. Saunders , Robert C. Bozsa
IPC分类号： A01N37/02 , A01N37/04 , A01N37/06 , A01N37/36 , A01N37/42 , A01N33/12 , A01N25/06 , A01N25/12
CPC分类号： A01N37/02 , A01N37/04 , A01N37/06 , A01N37/36 , A01N37/42 , Y10S514/919
摘要： A composition and method for killing insect larvae, in particular, fly larvae, in poultry houses, manure piles, or other sites of habitation are disclosed. The composition consists of one or more C.sub.2 to C.sub.6 aliphatic carboxylic acids or alkali metal, alkaline earth, ammonia, primary, secondary, tertiary, or quaternary ammonium salts in an acceptable formulation for larvacides. The formulation may be applied dry, as an aerosol, or in aqueous or organic solvents.
摘要翻译：公开了一种杀虫昆虫幼虫特别是飞禽幼虫在家禽舍，粪堆或其他栖息地的杀虫剂的组合物和方法。组合物由一种或多种C2-C6脂族羧酸或碱金属，碱土金属，氨，一级，二级，三价或季铵盐组成，用于幼虫的可接受制剂。制剂可以干燥，作为气雾剂，或在水溶液或有机溶剂中使用。

9. 发明授权

US4166913A Preparation of unsaturated diesters by the catalytic oxidative carbonylation of diolefins with an enol ether and an alcohol 失效
标题翻译：通过二烯烃与烯醇醚和醇的催化氧化羰基化制备不饱和二酯
公开(公告)号：US4166913A
公开(公告)日：1979-09-04
申请号：US814012
申请日：1977-07-08
申请人： Haven S. Kesling, Jr. , Lee R. Zehner
发明人： Haven S. Kesling, Jr. , Lee R. Zehner
IPC分类号： B01J31/04 , C07C69/593 , C07C69/52
CPC分类号： C07C69/593
摘要： A process for the preparation of an unsaturated diester having the formula ##STR1## wherein R is an alkyl group of from 1 to 8 carbon atoms or an aralkyl group containing 6 carbon atoms in the ring and from 1 to 4 carbon atoms in the alkyl substituent and R.sub.1 to R.sub.4 is hydrogen, a halogen, an alkyl group of from 1 to 4 carbon atoms or an aryl group containing 6 carbon atoms in the ring, by reacting carbon monoxide, oxygen, at least a stoichiometric amount of an enol ether or alkoxycycloalkene and at least an equal molar quantity of an alcohol based on the enol ether or alkoxycycloalkene, with a diolefin having the formula ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 which may be the same or different is as hereinabove described, in the presence of a catalytic amount of a platinum group metal compound and a copper or iron oxidant salt compound.Alternatively, a ligand or coordination complex compound of the metal salt compound may be employed as a co-catalyst.
摘要翻译：一种制备具有下式的不饱和二酯的方法，其中R是1至8个碳原子的烷基或在该环中含有6个碳原子和在烷基取代基中具有1至4个碳原子的芳烷基 R 1至R 4为氢，卤素，具有1至4个碳原子的烷基或环中含有6个碳原子的芳基，通过使一氧化碳，氧，至少化学计量的烯醇醚或烷氧基环烯烃和至少相等摩尔量的基于烯醇醚或烷氧基环烯烃的醇与具有下式的二烯烃：其中R1，R2，R3和R4可以相同或不同，如上所述，在存在下的催化量的铂族金属化合物和铜或铁氧化剂盐化合物。

10. 发明授权

US4112245A Process for the preparation of ethylene glycol 失效
标题翻译：制备乙二醇的方法
公开(公告)号：US4112245A
公开(公告)日：1978-09-05
申请号：US715747
申请日：1976-08-18
申请人： Lee R. Zehner , R. Warren Lenton
发明人： Lee R. Zehner , R. Warren Lenton
IPC分类号： C07C29/136 , B01J23/00 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/20 , C07C67/00 , C07C29/00
CPC分类号： C07C29/149 , Y02P20/52
摘要： A process for the preparation of ethylene glycol by the vapor phase hydrogenation of oxalate esters, such as a dibutyl oxalate, at elevated temperatures and at relatively low hydrogen pressures in the presence of a suitable hydrogenation catalyst, such as a copper chromite catalyst, while minimizing the hydrogenolysis of the glycol and other side reactions and maximizing the hydrogenation catalyst activity.
摘要翻译：通过在合适的氢化催化剂如亚铬酸铜催化剂的存在下，在升高的温度和相对低的氢气压力下，草酸酯如草酸二丁酯的气相氢化制备乙二醇的方法，同时最小化二醇的氢解和其他副反应，并使氢化催化剂活性最大化。

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