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    • 1. 发明授权
    • Substrate processing method and substrate processing apparatus
    • 基板处理方法和基板处理装置
    • US06632476B2
    • 2003-10-14
    • US09805034
    • 2001-03-14
    • Hiroko NakamuraHisashi KanekoTetsuo Matsuda
    • Hiroko NakamuraHisashi KanekoTetsuo Matsuda
    • B05D118
    • H01L21/6715B05C9/02B05D1/286
    • After a thin liquid agent film is formed by supplying a liquid agent onto a plate-like developer holder, this liquid agent film and the surface of a substrate are opposed. The liquid agent film and the substrate are brought into contact with each other at a point by declining the substrate and moving it close to the liquid agent film, or by curving the substrate toward the liquid agent film. Then, the substrate is made parallel to the liquid agent film, and the liquid agent is supplied such that the contact area of the liquid agent film spreads over the entire surface by the interfacial tension between the liquid agent film and the substrate. Since a thin liquid agent film can be uniformly formed below the substrate, processing can be performed with a small consumption amount. Additionally, the liquid agent can be supplied to the substrate without holding air.
    • 在通过将液体试剂供应到板状显影剂载体上形成薄液剂剂膜之后,该液体试剂膜和基材的表面相对。 通过使基板下降并使其靠近液体试剂膜,或者通过使基板朝向液体试剂膜弯曲而使液体试剂膜和基板彼此接触。 然后,使基板与液体试剂膜平行,并且供给液体试剂,使得液体试剂膜的接触面积通过液体试剂膜和基底之间的界面张力在整个表面上扩散。 由于可以在基板的下方均匀地形成薄的液体试剂膜,因此能够以小的消耗量进行处理。 另外,可以将液体试剂供给到基材而不夹持空气
    • 9. 发明授权
    • Method of manufacturing a copper interconnect
    • 制造铜互连的方法
    • US06348402B1
    • 2002-02-19
    • US09526880
    • 2000-03-16
    • Takashi KawanoueTetsuo MatsudaHisashi KanekoTadashi Iijima
    • Takashi KawanoueTetsuo MatsudaHisashi KanekoTadashi Iijima
    • H01L214763
    • H01L21/76846H01L21/76807H01L21/76831H01L21/76844H01L21/76855H01L21/76856H01L21/76888H01L23/53238H01L2924/0002H01L2924/00
    • A groove or hole is formed in an insulating layer formed on a semiconductor substrate, and a first conductive layer including a first metal element is formed on a surface of the insulating layer. By oxidizing the first conductive layer, an oxide layer of the first metal element is formed on a surface of the first conductive layer. A second conductive layer including a second metal element having a free energy of oxide formation lower than that of the first metal element is deposited thereon. By reducing the oxide layer of the first metal element by the second metal element, an oxide layer of the second metal element is formed at the interface between the first conductive layer and the second conductive layer. Further, an interconnection is buried in the groove or hole of the insulating layer. Thereby, a thin second metal oxide layer having excellent barrier properties against an interconnection material and excellent adhesion to the interconnection material can be selectively formed with a uniform thickness on the surface of the first conductive layer used as a barrier metal layer of the interconnection.
    • 在形成于半导体衬底上的绝缘层中形成沟槽,在绝缘层的表面上形成包括第一金属元件的第一导电层。 通过氧化第一导电层,在第一导电层的表面上形成第一金属元素的氧化物层。 在其上沉积包括具有低于第一金属元素的自由能的氧化物形成的第二金属元素的第二导电层。 通过由第二金属元件还原第一金属元件的氧化物层,在第一导电层和第二导电层之间的界面处形成第二金属元素的氧化物层。 此外,互连被埋在绝缘层的凹槽或孔中。 由此,可以在用作互连的阻挡金属层的第一导电层的表面上选择性地形成具有优良的互连材料阻隔性和对互连材料的优异粘附性的薄的第二金属氧化物层。