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1. 发明授权

US5300568A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5300568A
公开(公告)日：1994-04-05
申请号：US667408
申请日：1991-04-08
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
IPC分类号： C08K5/32 , C08K5/34 , C08L21/00 , C08L23/00 , C08L23/04 , C08L25/00 , C08L51/06 , C08L71/12 , C08L53/00
CPC分类号： C08L23/04 , C08K5/32 , C08K5/34 , C08L71/12 , Y10S525/905
摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5% by weight of at least one polyolefin-resin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95% by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).
摘要翻译： PCT No.PCT / JP90 / 00759 Sec。 371日期：1991年4月8日 102（e）日期1991年4月8日PCT Filed 1990年6月11日PCT公布。 WO91 / 19762 PCT出版物日本1991年12月26日。一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或（α-）α-烯烃或共聚物的均聚物的聚烯烃树脂（A）和由多官能化合物（E）和/或不饱和单体（L）改性的这些均聚物或共聚物和5-95重量％的至少一种选自聚苯醚，改性聚苯醚的聚苯醚树脂（B）与上述（E）和/或（L）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D））。（*化学结构*）（I）（其中X表示可以含有卤素或氧原子的二价链脂肪族基团，环状脂肪族基团或芳香族基团，R 1表示氢原子，链状脂肪族基团，环状脂族基团或芳香族基团，当X和R 1均为链状脂族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地为氢原子或1- 12个碳原子，R2和R3可以键合形成环）。

2. 发明授权

US5428091A Thermoplastic resin compositions comprising polyphenylene ether, polyolefins and dinitrodiamines 失效
标题翻译：包含聚苯醚，聚烯烃和二硝基二胺的热塑性树脂组合物
公开(公告)号：US5428091A
公开(公告)日：1995-06-27
申请号：US171622
申请日：1993-12-22
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinichi Yachigo , Hideo Nagasaki , Naoki Inui
IPC分类号： C08K5/32 , C08K5/34 , C08L21/00 , C08L23/00 , C08L23/04 , C08L25/00 , C08L51/06 , C08L71/12 , C08L53/00
CPC分类号： C08L23/04 , C08K5/32 , C08K5/34 , C08L71/12 , Y10S525/905
摘要： A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5 % by weight of at least one polyolefinresin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95 % by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.1 are chain aliphatic groups, the nitrogen atoms may further bond each other to form a ring through X and R.sup.1 ; R.sup.2 and R.sup.3 are independently a hydrogen atom or an alkyl group of 1-12 carbon atoms and R.sup.2 and R.sup.3 may bond to form a ring).
摘要翻译：一种热塑性树脂组合物，其包含100重量份的组合物，其包含95-5重量％的至少一种选自乙烯或α-烯烃的均聚物或其共聚物的聚烯烃树脂（A），以及这些均聚物或共聚物，其被多官能化合物（E）和/或不饱和单体（L）和5-95重量％的至少一种选自聚苯醚的聚苯醚树脂（B），具有上述（E）和/或（L）的改性聚苯醚）和包含聚亚苯基或改性聚苯醚和芳族乙烯基聚合物树脂（M）的组合物和0.001-10重量份下式（I）的二硝基二胺（D）。（I）（其中X表示二价链脂肪族基团，环状脂肪族基团或可以含有卤素或氧原子的芳香族基团，R 1表示氢原子，链状脂肪族基团，环状脂肪族基团或芳族基团，当X和R 1都是链状脂肪族基团时，氮原子可以进一步通过X和R 1彼此键合形成环; R2和R3独立地是氢原子或1-12个碳原子的烷基并且R 2和R 3可以键合形成环）。

3. 发明授权

US5180764A Stabilized polypropylene resin compositions containing a dinitrodiamine compound 失效
标题翻译：含有DINITRODIAMINE化合物的稳定的聚丙烯树脂组合物
公开(公告)号：US5180764A
公开(公告)日：1993-01-19
申请号：US681363
申请日：1991-04-08
申请人： Hideo Nagasaki , Naoki Inui , Shinichi Yachigo , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
发明人： Hideo Nagasaki , Naoki Inui , Shinichi Yachigo , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
IPC分类号： C08K5/32
CPC分类号： C08K5/32
摘要： A thermoplastic resin is stabilized by incorporating therein a dinitrodiamine compound represented by the formula of ##STR1## wherein X is a divalent aliphatic, alicyclic or aromatic group which may contain halogen or oxygen in the group, R.sup.1 is hydrogen or an aliphatic, alicyclic or aromatic group, provided that two nitrogen atoms linking through X may further link through R.sup.1 when both X and R.sup.1 are the aliphatic groups, and R.sup.2 and R.sup.3 independently of one another are each hydrogen or an alkyl of 1 to 12 carbon atoms, provided that R.sup.2 and R.sup.3 may conjointly form a ring. The composition thus blended is improved in thermal processing stability. Further, a modified polyolefin resin is improved in mechanical properties, particularly in impact strength, by the incorporation of the dinitrodiamine compound.

4. 发明授权

US5385976A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5385976A
公开(公告)日：1995-01-31
申请号：US867191
申请日：1992-07-02
申请人： Motonobu Furuta , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
发明人： Motonobu Furuta , Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto
IPC分类号： C08G65/48 , C08L51/06 , C08L51/08 , C08L67/00 , C08L71/00 , C08L71/02 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00 , C08F255/02
CPC分类号： C08L51/06 , C08G65/485 , C08L51/08 , C08L71/126 , C08L67/00 , C08L71/00 , C08L71/02 , C08L75/00 , C08L77/00 , C08L81/00 , Y10S525/905
摘要： A thermoplastic resin composition comprising a modified polyphenylene ether to which an amino group-containing monomer such as amino styrene is grafted and a propylene polymer which is modified with a compound having a functional group reactive with an amino group in a molecule. This composition is excellent in heat resistance, chemical resistance, impact resistance and appearance and used to produce a part which is required to have strength and heat resistance such as an automobile part.
摘要翻译：包含接枝有氨基单体如氨基苯乙烯的改性聚苯醚的热塑性树脂组合物和在分子内具有与氨基反应的官能团的化合物改性的丙烯聚合物。该组合物的耐热性，耐化学性，耐冲击性和外观优异，并且用于制造要求具有强度和耐热性的部件如汽车部件。

5. 发明授权

US5278233A Thermoplastic resin composition 失效
公开(公告)号：US5278233A
公开(公告)日：1994-01-11
申请号：US713868
申请日：1991-06-12
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
IPC分类号： C08L23/26 , C08F20/32 , C08F220/32 , C08G59/00 , C08K5/17 , C08L23/08 , C08L23/10 , C08L23/16 , C08L33/12 , C08L51/04 , C08L51/06 , C08L63/00 , C08L23/12
CPC分类号： C08L23/10 , C08L23/12 , C08L23/16 , C08L51/06 , C08L63/00 , C08L2205/03 , C08L2205/035 , C08L23/0815 , C08L33/12 , C08L53/02
摘要： The thermoplastic resin composition disclosed herein comprises:(1) a resin composition consisting of(i) at least one member selected from the group consisting of(a) a modified polypropylene to which has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,(b) a modified polypropylene to which have been graft comodified an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,(c) a mixture of the modified polypropylene (a) and a polypropylene,(d) a mixture of the modified polypropylene (b) and a polypropylene,(e) a modified mixture of a polypropylene and a rubbery substance to which mixture has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,(f) a modified mixture of a polypropylene and a rubbery substance to which mixture have been graft copolymerized an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,(g) a mixture of the modified mixture (e) and a polypropylene, and(h) a mixture of the modified mixture (f) and a polypropylene, and(ii) a thermoplastic copolymer (E) containing acid anhydride moiety of six-membered ring, and(2) an epoxy group-containing copolymer (G).The thermoplastic resin composition according to the present invention not only exhibits excellent processability but also produces remarkable advantages in that it gives far better physical properties than those expected from each polymer which constitutes the thermoplastic resin composition of the present invention.The novel resin composition provided by the present invention can be easily processed into molded articles, films and sheets by a molding method generally used for thermoplastic resins such as injection molding, extrusion molding, etc, and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil resistance, chemical resistance, water resistance, etc., and which are excellent in appearance uniformity and smoothness. The thermoplastic resin composition of the present invention is particularly suitable for use where well-balanced properties among heat resistance and impact resistance, low-temperature impact resistance in particular, are required.

6. 发明授权

US5420201A Thermoplastic resin composition comprising modified polypropylene, anhydride containing copolymer and epoxy containing copolymer 失效
标题翻译：包含改性聚丙烯，含酸酐的共聚物和含环氧的共聚物的热塑性树脂组合物
公开(公告)号：US5420201A
公开(公告)日：1995-05-30
申请号：US154533
申请日：1993-11-19
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Shinji Date
IPC分类号： C08L23/26 , C08F20/32 , C08F220/32 , C08G59/00 , C08K5/17 , C08L23/08 , C08L23/10 , C08L23/16 , C08L33/12 , C08L51/04 , C08L51/06 , C08L63/00 , C08L63/08
CPC分类号： C08L23/10 , C08L23/12 , C08L23/16 , C08L51/06 , C08L63/00 , C08L2205/03 , C08L2205/035 , C08L23/0815 , C08L33/12 , C08L53/02
摘要： A thermoplastic resin composition exhibiting excellent processability and producing remarkable advantages in that it gives far better physical properties than that expected from each polymer which constitutes the thermoplastic resin composition. The composition can be easily processed into molded articles, films and sheets and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil-resistance, chemical resistance, water resistance, etc. and which are excellent in appearance, uniformity and smoothness.
摘要翻译：表现出优异的加工性和显着优点的热塑性树脂组合物，其具有比构成热塑性树脂组合物的每种聚合物所预期的更好的物理性能。该组合物可以容易地加工成模塑制品，薄膜和薄片，并且可以得到在刚度，耐热性，耐冲击性，耐刮擦性，涂布性，耐油性，耐化学性，耐水性等方面具有良好平衡性能的产品，其外观，均匀性和平滑性优异。

7. 发明授权

US5484824A Thermoplastic polypropylene resin composition 失效
标题翻译：热塑性聚丙烯树脂组合物
公开(公告)号：US5484824A
公开(公告)日：1996-01-16
申请号：US448188
申请日：1995-05-23
申请人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Takeyoshi Nishio , Takao Nomura
发明人： Hiroomi Abe , Takeshi Fujii , Masashi Yamamoto , Takeyoshi Nishio , Takao Nomura
IPC分类号： C08K3/34 , C08L23/12 , C08L23/16 , C08L53/00 , C08K3/36 , C08L23/08
CPC分类号： C08L53/00
摘要： A thermoplastic resin composition which contains a resin composition containing a crystalline polypropylene component, an ethylene-butene-1 copolymer rubber and an ethylene-propylene copolymer rubber; a modified polypropylene; a saturated polyester resin; and an epoxy group-containing copolymer; and optionally talc exhibits high low-temperature impact strength, stiffness and Rockwell hardness and a small coefficient of linear expansion, which composition gives an injection-molded article suitably used for a bumper for automobile.
摘要翻译：一种热塑性树脂组合物，其含有含有结晶聚丙烯组分，乙烯 - 丁烯-1共聚物橡胶和乙烯 - 丙烯共聚物橡胶的树脂组合物; 改性聚丙烯; 饱和聚酯树脂; 和含环氧基的共聚物; 并且任选的滑石显示出高的低温冲击强度，刚度和洛氏硬度和小的线膨胀系数，该组合物给出适合用于汽车保险杠的注塑制品。

8. 发明授权

US5548013A Thermoplastic resin composition 失效
标题翻译：热塑性树脂组合物
公开(公告)号：US5548013A
公开(公告)日：1996-08-20
申请号：US339667
申请日：1994-11-14
申请人： Takeshi Fujii , Masashi Yamamoto
发明人： Takeshi Fujii , Masashi Yamamoto
IPC分类号： C08L23/10 , C08L51/06 , C08L51/04
CPC分类号： C08L23/10 , C08L51/06 , C08L2205/035 , C08L23/0884 , C08L51/04 , C08L53/00 , C08L53/02 , C08L67/00
摘要： The thermoplastic resin composition of the present invention contains(a) either a graft resin composition (J) obtained by graft polymerizing an unsaturated carboxylic acid or a derivative thereof onto a mixture of a polypropylene (C) and a rubbery substance (H), or a graft resin composition (K) obtained by graft polymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto a mixture of a polypropylene (C) and a rubbery substance (H),(b) a saturated polyester resin (F),(c) an epoxy group-containing copolymer (G), and(d) a polypropylene (C);which thermoplastic resin composition is suitably used in the fields where high level of heat resistance, impact resistance, and especially low-temperature impact resistance are required.
摘要翻译：本发明的热塑性树脂组合物含有（a）通过将不饱和羧酸或其衍生物接枝聚合到聚丙烯（C）和橡胶状物质（H）的混合物上而获得的接枝树脂组合物（J），或通过将不饱和羧酸或其衍生物和不饱和芳族单体接枝聚合到聚丙烯（C）和橡胶状物质（H）的混合物上得到的接枝树脂组合物（K），（b）饱和聚酯树脂），（c）含环氧基的共聚物（G）和（d）聚丙烯（C）; 该热塑性树脂组合物适用于需要高耐热性，耐冲击性，特别是低温耐冲击性的领域。

9. 发明授权

US5081186A Thermoplastic olefin resin composition 失效
标题翻译：热塑性烯烃树脂组合物
公开(公告)号：US5081186A
公开(公告)日：1992-01-14
申请号：US431177
申请日：1989-11-03
申请人： Tatsuyuki Mitsuno , Teruhisa Koyama , Takeshi Fujii , Masashi Yamamoto
发明人： Tatsuyuki Mitsuno , Teruhisa Koyama , Takeshi Fujii , Masashi Yamamoto
IPC分类号： C08K5/17 , C08G59/00 , C08L21/00 , C08L23/02 , C08L23/08 , C08L23/10 , C08L23/16 , C08L23/26 , C08L29/00 , C08L33/04 , C08L33/06 , C08L33/24 , C08L51/06 , C08L63/00 , C08L77/10 , C08L87/00
CPC分类号： C08L23/10 , C08L51/06 , C08L63/00 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L23/0869 , C08L23/16 , C08L77/10
摘要： The thermoplastic olefin resin composition of the present invention comprises: a resin composition consisting of at least one modified polypropylene and a polyglutarimide, and an epoxy group containing copolymer. The modified polypropylene is one in which at least an unsaturated carboxylic acid or a derivative thereof is graft copolymerized onto a polypropylene. This composition has good mold processability and can be used to produce molded products which are superior in mechanical properties to those obtained from the individual polymers of the composition.

10. 发明授权

US5409991A Thermoplastic propylene resin composition 失效
标题翻译：热塑性丙烯树脂组合物
公开(公告)号：US5409991A
公开(公告)日：1995-04-25
申请号：US207097
申请日：1994-03-08
申请人： Tatsuyuki Mitsuno , Takeshi Fujii , Masashi Yamamoto , Kentaro Yamaguchi , Kiyoshi Mitsui
发明人： Tatsuyuki Mitsuno , Takeshi Fujii , Masashi Yamamoto , Kentaro Yamaguchi , Kiyoshi Mitsui
IPC分类号： C08L21/00 , C08G59/00 , C08K3/34 , C08K7/04 , C08L23/08 , C08L23/10 , C08L23/12 , C08L23/16 , C08L23/26 , C08L51/00 , C08L51/04 , C08L51/06 , C08L63/00 , C08L77/00
CPC分类号： C08L23/10 , C08L23/12 , C08L23/16 , C08L51/04 , C08L51/06 , C08L53/00 , C08L77/00 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L23/0853 , C08L23/0869 , C08L23/0884
摘要： A thermoplastic propylene resin composition of the present invention is obtained by blending an epoxy group containing copolymer (G) and a rubber-like material (H) and/or a modified rubber-like material (I) with a resin omposition composed of a polyamide resin (F) and a polypropylene type resin (E).The thermoplastic propylene resin composition can easily be processed into molded products, films or sheets by injection molding, extrusion molding or the like, giving products which have a good balance in various physical properties and a uniform and smooth appearance. It is suitable for purposes in which especially high heat resistance, impact resistance and low-temperature impact resistance are required.
摘要翻译：本发明的热塑性丙烯类树脂组合物通过将含环氧基的共聚物（G）和橡胶状材料（H）和/或改性橡胶状材料（I）与由聚酰胺构成的树脂组合物树脂（F）和聚丙烯类树脂（E）。热塑性丙烯树脂组合物可以通过注射成型，挤出成型等容易地加工成成型品，薄膜或片材，得到各种物理性能均匀平滑的外观良好平衡的产品。适用于需要特别高耐热性，耐冲击性和耐低温冲击性的目的。

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