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    • 3. 发明授权
    • High oil clear emulsion with diene elastomer
    • 高油清乳液与二烯弹性体
    • US06387357B1
    • 2002-05-14
    • US09693229
    • 2000-10-20
    • Suman ChopraJairajh MattaiLin FeiEric GueninXiaozhong TangClaudio Ortiz
    • Suman ChopraJairajh MattaiLin FeiEric GueninXiaozhong TangClaudio Ortiz
    • A61K732
    • A61K8/892A61K8/042A61K8/06A61K8/891A61K2800/262A61Q15/00
    • A clear antiperspirant and/or deodorant composition is disclosed in the form of an emulsion having a refractive index less than 1.42 and comprising: (a) 25-70% of an external phase comprising: (i) 0.1-10%, on an actives basis, of at least one elastomer which is a cyclomethicone (and) dimethicone crosspolymer made with an ≡Si—H containing polysiloxane and an alpha, omega-diene of formula CH2═CH(CH2)xCH═CH2, where x=1-20, to form a gel by crosslinking and addition of ≡Si—H across double bonds in the alpha, omega diene, which crosspolymer has a viscosity in the range of 50,000-3,000,000 centipoise; (ii) 0.1-5% of a silicone copolyol having an HLB value ≦8; (iii) 0.1-68% of a volatile silicone selected in an amount to complete the external phase; (iv) 0-10% of a cosurfactant or emulsifier having an HLB value in the range of 1-15; (v) 0-5% of a non-volatile silicone; and (b) 30-75% of an internal phase which is made with: (i) 7-25% (on an anhydrous actives basis (excluding the waters of hydration) of an antiperspirant active; (ii) 0-10% ethanol; (iii) additional water as required to adjust the refractive index; (iv) 0-5% of an antimicrobial agent; and (v) 0-5% of an ionizable salt; wherein the conductance of a water droplet applied to the surface of a thin film of the antiperspirant and/or deodorant composition is at least 250 micro Siemens/cm/ml as measured by a fixed geometry test at a loading of at least 7% by weight level of antiperspirant active.
    • 透明止汗剂和/或除臭剂组合物以折射率小于1.42的乳液的形式公开,并包含:(a)25-70%的外相,其包含:(i)0.1-10%的活性物质 至少一种弹性体,其为由含Si-H的聚硅氧烷和式CH 2 = CH(CH 2)x CH = CH 2的α,ω-二烯制备的环甲基硅氧烷(和)聚二甲基硅氧烷交联聚合物,其中x = 1-20 通过在α,ω二烯中双键交联并加入= Si-H形成凝胶,该交联聚合物的粘度在50,000-3,000,000厘泊的范围内; (ii)具有HLB值<= 8的0.1-5%的硅氧烷共聚多元醇; (iii)以完成外相的量选择0.1-68%的挥发性硅氧烷; (iv)0-10%HLB值在1-15范围内的辅助表面活性剂或乳化剂; (v)0-5%的非挥发性硅酮; 和(b)30-75%的内相,其由以下制备:(i)7-25%(基于无水活性物质(不包括水合水合))止汗活性物质;(ii)0-10%乙醇 ;(iii)调整折射率所需的额外的水;(iv)0-5%的抗微生物剂;和(v)0-5%的可电离盐;其中施加到表面的水滴的电导率 的止汗剂和/或除臭剂组合物的薄膜是至少250微西门子/厘米/毫升,通过固定几何测试在至少7重量%的止汗活性剂的负载下测量。
    • 4. 发明授权
    • High oil clear emulsion with elastomer
    • 高透明乳液与弹性体
    • US06403069B1
    • 2002-06-11
    • US09693248
    • 2000-10-20
    • Suman ChopraJairajh MattaiLin FeiEric GueninXiaozhong Tang
    • Suman ChopraJairajh MattaiLin FeiEric GueninXiaozhong Tang
    • A61K732
    • A61K8/895A61K8/064A61K8/585A61K8/894A61K2800/262A61Q15/00
    • A clear antiperspirant and/or deodorant composition is disclosed in the form of an emulsion having a refractive index less than 1.42 and comprising: (a) 25-70% of an external phase comprising: (i) 0.1-10%, on an actives basis, of at least one elastomer which is a dimethicone/vinyldimethicone crosspolymer composition made by reacting a polymethylhydrogensiloxane with an alpha, omega-divinylpolydimethyl siloxane for which the dimethicone/vinyl-dimethicone crosspolymer composition is used at a concentration of 4-10% in cyclomethicone, has a refractive index in the range of 1.392-1.402 at 25 degrees C and a viscosity in the range of 0.013-1×104 Pascal seconds; (ii) 0.1-5% of a silicone copolyol having an HLB value ≦8; (iii) 0.1-68% of a volatile silicone selected in an amount to complete the external phase; (iv) 0-10% of a cosurfactant or emulsifier having an HLB value in the range of 1-15; (v) 0-5% of a non-volatile silicone; and (b) 30-75% of an internal phase which is made with: (i) 7-25% (on an anhydrous actives basis (excluding the waters of hydration) of an antiperspirant active; (ii) 0-10% ethanol; (iii) additional water as required to adjust the refractive index; (iv) 0-5% of an antimicrobial agent; and (v) 0-5% of an ionizable salt; wherein the conductance of a water droplet applied to the surface of a thin film of the antiperspirant and/or deodorant composition is at least 250 micro Siemens/cm/ml as measured by a fixed geometry test at a loading of at least 7% by weight level of antiperspirant active.
    • 透明止汗剂和/或除臭剂组合物以折射率小于1.42的乳液的形式公开,并包含:(a)25-70%的外相,其包含:(i)0.1-10%的活性物质 基于至少一种弹性体,其是通过使聚甲基氢硅氧烷与α,ω-二乙烯基聚二甲基硅氧烷反应制备的聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物组合物,其中在聚甲基硅氧烷中以4-10%的浓度使用聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交联聚合物组合物 在25℃下的折射率在1.392-1.402的范围内,粘度在0.013-1×104帕斯卡秒的范围内; (ii)具有HLB值<= 8的0.1-5%的硅氧烷共聚多元醇; (iii)以完成外相的量选择0.1-68%的挥发性硅氧烷; (iv)0-10%HLB值在1-15范围内的辅助表面活性剂或乳化剂; (v)0-5%的非挥发性硅酮; 和(b)30-75%的内相,其由以下制备:(i)7-25%(基于无水活性物质(不包括水合水合))止汗活性物质;(ii)0-10%乙醇 ;(iii)调整折射率所需的额外的水;(iv)0-5%的抗微生物剂;和(v)0-5%的可电离盐;其中施加到表面的水滴的电导率 的止汗剂和/或除臭剂组合物的薄膜是至少250微西门子/厘米/毫升,通过固定几何测试在至少7重量%的止汗活性剂的负载下测量。
    • 7. 发明授权
    • Antiperspirant product with dibenzylidene sorbitol and elastomer in dimethicone
    • 具有二亚苄基山梨糖醇和弹性体在二甲聚硅氧烷中的止汗剂产品
    • US06338841B1
    • 2002-01-15
    • US09682101
    • 2001-07-19
    • Jairajh MattaiClaudio OrtizEric GueninJohn Afflitto
    • Jairajh MattaiClaudio OrtizEric GueninJohn Afflitto
    • A61K732
    • A61K8/894A61K8/0229A61K8/042A61K8/345A61K8/498A61K8/731A61K8/891A61K2800/262A61K2800/31A61Q15/00
    • This invention comprises a clear to translucent anhydrous stick or gel antiperspirant and/or deodorant product having low tack and comprising: (a) a solvent phase comprising: (i) 0.2-4.0 weight % dibenzylidene sorbitol; (ii) 0.05-1.0 weight % of a co-gellant or structural integrity enhancer; (iii) 25-75 weight % of a solvent selected from the group consisting of polyhydric alcohols; (iv) an effective amount of an antiperspirant or deodorant; and (v) 0.1-5 weight % dimethicone copolyol; and (b) an oil phase comprising: (i) 0.25-5 weight % of a silicone elastomer (on a solids basis) in a first dimethicone wherein the dimethicone has a viscosity in the range of 6-100 centistokes and a flashpoint in the range of about greater than 115 degrees C. to 300 degrees C.; and (ii) 1-25 weight % of a second dimethicone (including the dimethicone from part (b)(i)), wherein the second dimethicone may be selected from the same group or a different group than the first dimethicone; and (iii) 0-10 weight % emollients; wherein the oil phase is 5-50% of the composition and the solvent phase is 50-95% of the composition.
    • 本发明包括具有低粘性的透明至半透明无水棒或凝胶止汗剂和/或除臭剂产品,并且包含:(a)溶剂相,其包含:(i)0.2-4.0重量%的二亚苄基山梨糖醇; (ii)0.05-1.0重量%的共胶凝剂或结构完整性增强剂; (iii)25-75重量%的选自多元醇的溶剂; (iv)有效量的止汗剂或除臭剂; 和(v)0.1-5重量%的聚二甲基硅氧烷共聚多元醇; 和(b)油相,其包含:(i)0.25-5重量%的第一聚二甲基硅氧烷中的硅氧烷弹性体(基于固体),其中聚二甲基硅氧烷的粘度在6-100厘沲的范围内, 范围约为115摄氏度至300摄氏度; 和(ii)1-25重量%的第二聚二甲基硅氧烷(包括来自部分(b)(i)的聚二甲基硅氧烷)),其中第二聚二甲基硅氧烷可以选自与第一聚二甲基硅氧烷相同的组或不同的基团; 和(iii)0-10重量%润肤剂; 其中油相为组合物的5-50%,溶剂相为组合物的50-95%。
    • 9. 发明授权
    • High efficacy antiperspirant stick with concentrated elastomer
    • 高功效止汗棒与浓缩弹性体
    • US06511658B2
    • 2003-01-28
    • US10035406
    • 2001-11-09
    • Jairajh MattaiEric GueninWilson LeePatricia Hall-PuzioAnne Gale
    • Jairajh MattaiEric GueninWilson LeePatricia Hall-PuzioAnne Gale
    • A61K732
    • A61K8/893A61K8/02A61K8/0229A61K8/042A61K8/31A61K8/342A61K8/361A61K8/37A61K8/375A61K8/39A61K8/585A61K8/8111A61K8/86A61K8/891A61K8/92A61K8/925A61K8/927A61Q15/00Y10S424/05
    • A high efficacy antiperspirant/deodorant stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C.; and (iv) has a polymer backbone of CH3CH2—(CH2—CH2)n—H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.; and (f) 1-30% of an elastomer in cyclomethicone composition comprising a cyclomethicone (and) dimethicone crosspolymer made with an ═Si—H containing polysiloxane and an alpha, omega-diene of formula CH2═CH(CH2)xCH═CH2, where x=1-20; provided that the ratio of wax:polyethylene is in the range of 1:1-1:10.
    • 可以通过组合(a)30-70%挥发性环甲基硅酮来制备高效止汗剂/除臭棒产品; (b)10-25%的止汗活性物质; (c)润肤剂的1-15%; (d)1-14%的包含选自聚乙烯均聚物和共聚物中的一种或多种的聚乙烯的聚乙烯,其中聚乙烯(i)至少为90%线性; (ii)分子量在300-3000(特别是300-1000,更特别是300-500)的范围内; (iii)的熔点在50-129℃的范围内。 和(iv)具有CH 3 CH 2 - (CH 2 -CH 2)n -H的聚合物主链,其中n是平均数,并且选择在10-106的范围内; (e)0.3-7%的与聚乙烯的共胶凝剂的蜡,其中蜡的熔点在40-97℃的范围内; 和(f)1-30%的环甲基硅氧烷组合物中的弹性体,其包含由含Si-H的聚硅氧烷和式CH 2 = CH(CH 2)x CH = CH 2的α,ω-二烯制备的环甲基硅氧烷(和)聚二甲基硅氧烷交联聚合物, 其中x = 1-20; 假定蜡:聚乙烯的比例在1:1至1:10的范围内。