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1. 发明申请

US20060205974A1 Processes for producing aromatic dicarboxylic acids 审中-公开
标题翻译：制备芳族二羧酸的方法
公开(公告)号：US20060205974A1
公开(公告)日：2006-09-14
申请号：US11075008
申请日：2005-03-08
申请人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd , Stephan Schunk , Oliver Busch
发明人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd , Stephan Schunk , Oliver Busch
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26 , C07C63/24
摘要： Processes for the liquid phase oxidation of one or more of a para- or a meta-substituted dialkyl aromatic compound are disclosed, the processes including a step of combining in a reaction medium the one or more para- or meta-substituted dialkyl aromatic compound, a solvent mixture comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 130° C. to about 180° C., in the presence of a catalyst composition comprising cobalt, manganese, bismuth, and bromine. The processes produce the corresponding aromatic dicarboxylic acid product with improved conversion, while reducing the formation of carbon oxides.
摘要翻译：公开了一种或多种对位或间位取代的二烷基芳族化合物的液相氧化方法，所述方法包括在反应介质中将一种或多种对位或间位取代的二烷基芳族化合物，包含水和具有2-4个碳原子的饱和有机酸和含氧气体的溶剂混合物在约130℃至约180℃的温度下，在催化剂组合物存在下，包含钴，锰，铋和溴。该方法产生具有改进转化率的相应芳族二羧酸产物，同时减少碳氧化物的形成。

2. 发明申请

US20060205975A1 Processes for producing aromatic dicarboxylic acids 有权
公开(公告)号：US20060205975A1
公开(公告)日：2006-09-14
申请号：US11075009
申请日：2005-03-08
申请人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd
发明人： Gino Lavoie , Robert Hembre , Charles Sumner , Joseph Bays , Daniel Compton , Brent Tennant , Bryan Davenport , David Lange , Thomas Floyd
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26 , C07C63/15 , C07C63/16 , C07C63/24
摘要： Processes for producing aromatic dicarboxylic acids are disclosed, the processes including a step of combining in a reaction medium a dialkyl aromatic, a solvent comprising water and a saturated organic acid having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 125° C. to about 155° C., in the presence of a catalyst composition comprising cobalt, manganese, zirconium, and bromine, wherein the weight ratio of cobalt to manganese in the reaction mixture is from about 10 to about 400. The processes provide improved conversion, while reducing the formation of carbon oxides and other by-products.

3. 发明申请

US20060205977A1 Processes for producing terephthalic acid 审中-公开
标题翻译：生产对苯二甲酸的方法
公开(公告)号：US20060205977A1
公开(公告)日：2006-09-14
申请号：US11214406
申请日：2005-08-29
申请人： Charles Sumner , Robert Hembre , David Lange , Gino Lavoie , Brent Tennant , Thomas Floyd , Bryan Davenport , Daniel Compton , Joseph Bays
发明人： Charles Sumner , Robert Hembre , David Lange , Gino Lavoie , Brent Tennant , Thomas Floyd , Bryan Davenport , Daniel Compton , Joseph Bays
IPC分类号： C07C51/16 , C07C51/255
CPC分类号： C07C51/265 , C07C63/26
摘要： Processes for producing terephthalic acid are disclosed, the processes comprising combining in a reaction medium p-xylene, a solvent comprising water and one or more saturated organic acids having from 2-4 carbon atoms, and an oxygen-containing gas, at a temperature from about 135° C. to about 165° C., in the presence of a catalyst composition comprising cobalt atoms and manganese atoms, with bromine atoms provided as a promoter. The amount of cobalt used may be from about 1,800 ppm to about 6,000 ppm, with respect to the total weight of the liquid in the reaction medium, and the weight ratio of cobalt to manganese may be from about 40 to about 400. The processes according to the invention produce terephthalic acid as a precipitated reaction product, with typically no more than about 10 ppm 2,6-dicarboxyfluorenone produced, with respect to the weight of the terephthalic acid produced, or no more than about 20 ppm 2,6-dicarboxyfluorenone, with respect to the total weight of the reaction medium, per batch or upon one pass through a reactor. The terephthalic acid so produced may be further purified by one or more additional oxidation reactions, without the need for expensive hydrogenation purification processes.
摘要翻译：公开了制备对苯二甲酸的方法，该方法包括在反应介质中混合对二甲苯，包含水和一种或多种具有2-4个碳原子的饱和有机酸的溶剂和含氧气体，约135℃至约165℃，在包含钴原子和锰原子的催化剂组合物存在下，提供溴原子作为助催化剂。相对于反应介质中的液体的总重量，所使用的钴的量可以为约1,800ppm至约6,000ppm，并且钴与锰的重量比可以为约40至约400.根据本发明产生对苯二甲酸作为沉淀反应产物，相对于所生产的对苯二甲酸的重量，通常不超过约10ppm的2,6-二羧基芴酮，或不超过约20ppm的2,6-二羧基芴酮，相对于反应介质的总重量，每批次或一次通过反应器。如此生产的对苯二甲酸可以通过一个或多个另外的氧化反应进一步纯化，而不需要昂贵的氢化纯化方法。

4. 发明申请

US20060165582A1 Production of synthesis gas 审中-公开
标题翻译：生产合成气
公开(公告)号：US20060165582A1
公开(公告)日：2006-07-27
申请号：US11044144
申请日：2005-01-27
申请人： Donald Brooker , Joseph Bays
发明人： Donald Brooker , Joseph Bays
IPC分类号： C01B31/00
CPC分类号： C10J3/466 , C10J3/84 , C10J2300/0906 , C10J2300/093 , C10J2300/0946 , C10J2300/0973 , C10J2300/0983 , C10J2300/1631 , C10J2300/1807 , C10J2300/1846 , C10K1/10 , C10K1/101
摘要： Disclosed are gasification processes for the production of mixtures of carbon monoxide and hydrogen, by the partial oxidation of a carbonaceous feedstock material wherein carbon values contained in a solid slag effluent from the partial oxidation reactor are recovered and recycled to the gasification reactor.
摘要翻译：公开了通过碳质原料的部分氧化生产一氧化碳和氢气的混合物的气化方法，其中包含在来自部分氧化反应器的固体渣流出物中的碳值被回收并再循环到气化反应器。

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