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1. 发明授权

US06284829B1 Silicone elastomer of high thermal conductivity 失效
标题翻译：硅氧烷弹性体导热性高
公开(公告)号：US06284829B1
公开(公告)日：2001-09-04
申请号：US09590803
申请日：2000-06-09
申请人： Bernard Dalbe , Yves Giraud
发明人： Bernard Dalbe , Yves Giraud
IPC分类号： C08K318
CPC分类号： C08K3/22 , C08K3/36 , C08L83/04
摘要： The polyorganosiloxane composition resulting in a silicone elastomer of high thermal conductivity, which can reach and even exceed 1.2 W/m.K, the elastomer retaining an elongation at break of greater than 30%, comprises at least one functional polyorganosiloxane which crosslinks by a polyaddition or polycondensation reaction or by the radical route, optionally a polyorganohydrosiloxane, a catalyst, optionally a reinforcing filler and a filler intended to increase the thermal conductivity which is present in the composition in the proportion of 35 to 70% by volume with respect to the total composition, this filler comprising at least two groups of particles of very different mean diameters, a first group having a mean particle diameter of between 10 and 40 mm, present in a predominant amount in the filler, and a second group having a mean particle diameter of less than 5 mm.
摘要翻译：该聚有机硅氧烷组合物产生导热性高的有机硅弹性体，其可以达到甚至超过1.2W / mK，保持断裂伸长率大于30％的弹性体包括至少一种通过加聚或缩聚交联的官能聚有机硅氧烷反应或通过自由基途径，任选的聚有机氢硅氧烷，催化剂，任选的增强填料和用于增加组合物中相对于总组合物的35至70体积％的比例存在的热导率的填料，该填料包含至少两组平均直径非常不同的颗粒组，平均粒径在10至40mm之间的第一组以占主要量的填料形式存在，第二组的平均粒径较小超过5毫米。

2. 发明授权

US06511714B2 Process for combating the appearance of mist during the coating of flexible supports with a crosslinkable liquid silicone composition in a roll device 失效
标题翻译：用于在辊装置中用可交联液体硅酮组合物涂覆柔性载体时防止雾的外观的方法
公开(公告)号：US06511714B2
公开(公告)日：2003-01-28
申请号：US09888617
申请日：2001-06-26
申请人： Paul Branlard , Frédéric Garnes , Yves Giraud , Christophe Guyot , Frédéric Magd
发明人： Paul Branlard , Frédéric Garnes , Yves Giraud , Christophe Guyot , Frédéric Magd
IPC分类号： B05D302
CPC分类号： C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： The invention relates to a process for combating the appearance of mist (misting) during the coating of flexible supports with at least one liquid silicone (RTV polyaddition) composition which is a precursor of silicone coating(s) using a roll coating device operating at high speed. The targeted aim is to increase the speed of appearance of the misting and subsequently to improve the appearance, the coverage and the mechanical properties of the silicone coating and industrial hygiene. For this, use is made of a liquid coating composition obtained by mixing: a silicone phase comprising one or more POSs (A) and optionally one or more (crosslinking) compound(s) (B), the viscosity &eegr; of which at 25° C. is between 100 and 800 mPa·s; with 1 to 10% by weight of noncellulose antimist particles (talc, silica, kaolin, TiO2), the D50 (in &mgr;m) of which is: 0.01≦D50≦2; and optionally with a liquid (D)—water/solvent.
摘要翻译：本发明涉及一种使用至少一种液体硅氧烷（RTV加聚）组合物涂覆柔性载体的雾（雾）的外观的方法，该液体硅氧烷（RTV加聚）组合物是使用在高温下操作的辊涂装置的硅氧烷涂层的前体速度。目标是提高雾化的出现速度，从而改善硅胶涂层的外观，覆盖和机械性能以及工业卫生。为此，使用通过混合获得的液体涂料组合物：包含一种或多种POS（A）和任选的一种或多种（交联）化合物（B）的硅氧烷相，其粘度et在25° C为100至800mPa.s;具有1至10重量％的非纤维素抗微粒（滑石粉，二氧化硅，高岭土，TiO 2），D50（母体）为：0.01 <= D50 <= 2; 和任选用液体（D） - 水/溶剂。

3. 发明授权

US08216321B2 Silicone/fluorinated organic compound mixed composition for conferring oleophobicity and/or hydrophobicity on a textile material 失效
标题翻译：硅酮/氟化有机化合物混合组合物，用于赋予织物材料上的疏水性和/或疏水性
公开(公告)号：US08216321B2
公开(公告)日：2012-07-10
申请号：US11547401
申请日：2005-03-30
申请人： Martial Deruelle , Yves Giraud
发明人： Martial Deruelle , Yves Giraud
IPC分类号： C08L83/04 , D06B19/00
CPC分类号： D06M15/643 , D06M15/277
摘要： Crosslinkable liquid composition which can crosslink to give a hydrophobic and/or oleophobic silicone elastomer coating, comprising a polyorganosiloxane (POS) resin A exhibiting, per molecule, on the one hand, at least two different siloxyl units chosen from those of M, D, T and Q types, one of the units being a T unit or a Q unit, and, on the other hand, at least three hydrolysable/condensable groups of OH and/or OR1 types, where R1 is a linear or branched C1 to C6, preferably C1 to C3, alkyl radical, a system for promoting attachment B and a polyfluoroacrylate F. Use of this composition to form a silicone elastomer sheath around the constituent yarns, fibers and/or filaments of a textile material and to confer long-lasting oleophobicity and/or hydrophobicity properties.
摘要翻译：可交联以产生疏水和/或疏油硅氧烷弹性体涂层的可交联液体组合物，其包含每分子表现出至少两种选自M，D， T和Q类型，其中一个单元是T单元或Q单元，另一方面是OH和/或OR1类型的至少三个可水解/可缩合的基团，其中R 1是直链或支链C 1至C 6 ，优选C1至C3烷基，用于促进附着物B的系统和聚氟丙烯酸酯F.使用该组合物在纺织材料的组成纱线，纤维和/或长丝周围形成硅氧烷弹性体护套，并赋予持久的疏油性和/或疏水性。

4. 发明授权

US08012593B2 Textile coating formulations comprising crosslinkable liquid silicones, metal alkoxides and functional coreactants 有权
标题翻译：包含可交联液体硅氧烷，金属醇盐和功能性共反应物的纺织涂料配方
公开(公告)号：US08012593B2
公开(公告)日：2011-09-06
申请号：US11979553
申请日：2007-11-05
申请人： Martial Deruelle , Yves Giraud
发明人： Martial Deruelle , Yves Giraud
IPC分类号： B32B25/20
CPC分类号： C08L83/04 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/46 , C08G77/70 , C08G77/80 , C08K5/057 , C09D183/04 , D06M15/643 , Y10T428/2915 , Y10T428/31663 , C08L83/00 , C08L2666/28 , C08L2666/14 , C08L2666/44
摘要： Crosslinkable liquid silicone compostions suited, on curing, for the long-lasting protective and/or applicational coating/treatment of textile substrates, for example, for imparting softness, hydrophobicity, oleophobicity, hydrophilicity or antistatic properties thereto, comprise a formulation of (a) at least one particular polyorganosiloxane (POS) resin, (B) at least one metal alkoxide and/or polyalkoxide, or combination thereof with at least one optionally alkoxylated organosilane and/or at least one organosilicon compound bearing at least one epoxy, amino, ureido, isocyanato and/or isocyanurate substituent, (C) at least one functional coreactant therefor, (D), optionally, at least one nonreactive additive and (E), also optionally, at least one auxiliary agent other than an additive (D).
摘要翻译：适用于固化时用于织物基材的持续保护和/或涂敷/处理的交联液体硅氧烷组合物，例如赋予其柔软度，疏水性，疏油性，亲水性或抗静电性能，包括（a）至少一种特定的聚有机硅氧烷（POS）树脂，（B）至少一种金属醇盐和/或聚烷氧化物，或其与至少一种任选烷氧基化的有机硅烷和/或至少一种带有至少一个环氧基，氨基，脲基的有机硅化合物，异氰酸酯基和/或异氰脲酸酯取代基，（C）至少一种功能性共反应物，（D），任选的至少一种非反应性添加剂和（E），还任选地至少一种除添加剂（D）以外的助剂。

5. 发明授权

US07972705B2 Use of a crosslinkable silicone-based inverse emulsion for producing “breathable waterproof” coatings 失效
标题翻译：使用可交联的硅酮反相乳液制造“透气防水”涂料
公开(公告)号：US07972705B2
公开(公告)日：2011-07-05
申请号：US12068245
申请日：2008-02-04
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： B32B25/20
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.
摘要翻译：在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性，保持对水的不渗透性。能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面，通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

6. 发明申请

US20080293876A1 Use of a crosslinkable silicone-based inverse emulsion for producing "breathable waterproof" coatings 失效
标题翻译：使用可交联的硅酮反相乳液制造“透气防水”涂料
公开(公告)号：US20080293876A1
公开(公告)日：2008-11-27
申请号：US12068245
申请日：2008-02-04
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： C08L83/04
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.
摘要翻译：在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性，保持对水的不渗透性。能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面，通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

7. 发明授权

US5661192A Organopolysiloxane composition for elastomer foam 失效
标题翻译：弹性体泡沫的有机聚硅氧烷组合物
公开(公告)号：US5661192A
公开(公告)日：1997-08-26
申请号：US722541
申请日：1996-09-27
申请人： Yves Giraud
发明人： Yves Giraud
IPC分类号： C08G77/14 , C08J9/08 , C08K3/26
CPC分类号： C08J9/08 , C08G77/14 , C08K3/26 , C08J2383/04
摘要： In an organopolysiloxane composition giving rise to elastomer foam, including at least one polyacyloxyorganopolysiloxane obtained by functionalization, with a polyacyloxysilane, of at least one reactive oil which is a polyhydroxylated polysiloxane intended to react in the presence of water to form the elastomer with formation of acid of formula R'COOH, in which R' denotes a hydrocarbon radical free from aliphatic unsaturation and which has from 1 to 15 carbon atoms, a blowing agent and optionally water, the blowing agent is at least one acidic or neutral carbonate of an alkali or alkaline-earth metal, which, by reacting with the acid R'COOH, gives carbon dioxide and preferably water.Objects, especially seals, thus obtained and kit for static mixing.
摘要翻译：在产生弹性体泡沫的有机聚硅氧烷组合物中，包括至少一种通过官能化获得的聚酰氧基有机聚硅氧烷与聚酰氧基硅烷，至少一种反应性油是多羟基化聚硅氧烷，其旨在在水存在下反应形成弹性体，形成酸式R'COOH，其中R'表示不具有脂族不饱和键且具有1至15个碳原子的烃基，发泡剂和任选的水，所述发泡剂是至少一种酸或中性的碱的碳酸盐或碱土金属通过与酸R'COOH反应得到二氧化碳，最好是水。由此得到的物体，特别是密封件，并用于静态混合。

8. 发明申请

US20070298320A1 Crosslinkable Composition for a Battery Electrolyte 有权
标题翻译：电池电解质的交联组合物
公开(公告)号：US20070298320A1
公开(公告)日：2007-12-27
申请号：US10553062
申请日：2004-03-23
申请人： Georges Barrandon , Catherine George , Carroll Vergelati , Yves Giraud
发明人： Georges Barrandon , Catherine George , Carroll Vergelati , Yves Giraud
IPC分类号： C08L83/04 , C08L83/06 , H01B1/12
CPC分类号： H01M10/0565 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/46 , C08L83/04 , H01M6/181 , H01M6/188 , H01M10/0525 , C08L83/00
摘要： The field of the present invention relates to the field of batteries and of polymer electrolytes for batteries and more particularly to the field of lithium batteries. The invention relates to a composition which can be polymerized and/or crosslinked by dehydrocondensation for a battery electrolyte comprising: a) at least one organohydropolysiloxane (POS) (A) having, per molecule, at least 2 hydrogen atoms directly bonded to silicon atoms; b) at least one organohydroxypolysiloxane (POS) (B) having, per molecule, at least 2 —OH groups directly bonded to silicon atoms; c) an effective amount of a dehydrocondensation catalyst (C); and d) at least one electrolyte salt (D); with the condition that the POS (A) and/or the POS (B) comprise(s), per molecule, at least one siloxyl unit comprising at least one group directly bonded to a silicon atom comprising a polyoxyalkylene (Poa) ether functional group.
摘要翻译：本发明的领域涉及用于电池的电池和聚合物电解质的领域，更具体地涉及锂电池领域。本发明涉及一种可通过电解质电解质脱水缩聚进行聚合和/或交联的组合物，包括：a）至少一种有机氢聚硅氧烷（POS）（A），每分子具有至少2个与硅原子键合的氢原子; b）至少一种有机羟基聚硅氧烷（POS）（B），每分子具有至少2个与硅原子键合的-OH基团; c）有效量的脱氢缩合催化剂（C）; 和d）至少一种电解质盐（D）; 条件是每个分子中POS（A）和/或POS（B）包含（s）至少一个含有至少一个直接键合到硅原子的基团的甲硅烷氧基单元，包括聚氧化烯（Poa）醚官能团。

9. 发明申请

US20050123689A1 Use of a crosslinkable silicone invert emulsion for producing breathable coatings 审中-公开
标题翻译：使用可交联的硅氧烷反相乳液生产透气涂料
公开(公告)号：US20050123689A1
公开(公告)日：2005-06-09
申请号：US10503726
申请日：2003-02-07
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： D06M11/79 , D06M13/513 , D06M15/643 , D06M15/65 , D06N3/12 , C08J7/04
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： The invention relates to the general field of silicone coating on various pliable supports, for example textiles, made of synthetic polymers (polyamide, polyester, etc.). An aim of the invention is to propose an effective process for producing coatings that are waterproof and permeable to moisture vapour, on pliable supports, this process allowing an improvement in the moisture vapour-permeability of the silicones while at the same time conserving the waterproofness. The process according to the invention which achieves this aim consists essentially in coating one of the faces of the support with a film formed by a water-in-oil inverse silicone emulsion comprising a continuous oily silicone phase φs, which can be crosslinked into an elastomer and which comprises a polyorganosiloxane (POS) A that is crosslinkable by polyaddition, by polycondensation, by cationic means or by free-radical means; optionally a crosslinking organosilicic compound B; optionally at least one catalyst C, an aqueous phase φa, a stabilizer, and in seeing to it that the silicone phase φs crosslinks and that removal of water occurs. The invention also relates to pliable supports made of polyamide or polyester, that are waterproof and permeable to moisture vapour, obtained by using a water-in-oil inverse silicone emulsion.
摘要翻译：本发明涉及在合成聚合物（聚酰胺，聚酯等）制成的各种柔韧载体上的硅酮涂层的一般领域，例如纺织品。本发明的目的是提出一种在柔韧的支撑物上生产防水和透湿的涂层的有效方法，该方法允许提高硅氧烷的透湿度，同时保持防水性。实现该目的的根据本发明的方法主要在于用由油包水反相硅氧烷乳液形成的膜涂覆载体的一个表面，所述油包水反相硅氧烷乳液包含连续的油性硅氧烷相phis，其可交联成弹性体并且其包含通过加聚可交联的聚有机硅氧烷（POS）A，通过缩聚，通过阳离子手段或通过自由基手段进行交联; 任选交联的有机硅化合物B; 任选地至少一种催化剂C，水相phia，稳定剂，并且认为有机硅相交联并发生水的除去。本发明还涉及通过使用油包水反相硅氧烷乳液获得的由聚酰胺或聚酯制成的柔性支撑体，其是防水的并且是透湿的。

10. 发明授权

US06825153B2 Lubricating composition based on siloxane, not releasing hydrogen, preparation method and use thereof 有权
标题翻译：基于硅氧烷的润滑组合物，不释放氢气，其制备方法和用途
公开(公告)号：US06825153B2
公开(公告)日：2004-11-30
申请号：US10148563
申请日：2002-09-13
申请人： Yves Giraud , Gérald Guichard , Ian Hawkins
发明人： Yves Giraud , Gérald Guichard , Ian Hawkins
IPC分类号： C10M17302
CPC分类号： C10M173/02 , B29C33/64 , C08G77/045 , C08G77/16 , C08G77/20 , C08G77/26 , C08G77/70 , C08G77/80 , C08L83/04 , C10M107/50 , C10M155/02 , C10M2201/02 , C10M2209/104 , C10M2209/12 , C10M2227/04 , C10M2227/083 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10M2229/051 , C10M2229/052 , C10M2229/053 , C10M2229/054 , C10N2220/02 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C08L83/00 , C08L2666/28
摘要： The invention concerns a lubricating composition, in the form of an oil-in-water emulsion, based on siioxane and not releasing hydrogen comprising: (a) a polydiorganosiloxane oil non-reactive to the lubricating properties having a dynamic viscosity of the order of 5.10−2 to 30.102 Pa.s at 25° C.; (b) a polyorganosiloxane resin bearing, before emulsification, condensable hydroxyl substituents and comprising before emulsification at least two syloxyl units selected among those of formula (R0)3SiO1/2(M); (R0)2SiO2/2(D); R0SiO3/2(T) and SiO4/2(Q), one at least of said units being a T or Q unit, formulae wherein: R0 represents a monovalent organic substituent, the average number per molecule of organic radicals R0 for a silicon atom ranging between 1 and 2; and said resin having a weight content of hydroxyl substituents ranging between 0.1 and 10 wt. %, and, preferably between 0.2 and 5 wt. %; (c) a crosslinking agent soluble in the silicone phase comprising at least two functions capable of reacting with the polyorganosiloxane resin (b); a condensation catalyst capable of catalysing the reaction of constituent (b) with constituent (c); (e) a surfactant; and (f) water.
摘要翻译：本发明涉及一种基于硅氧烷并且不释放氢的水包油乳液形式的润滑组合物，其包含：（a）不具有与润滑性能反应的聚二有机硅氧烷油，其动态粘度为5.10 在25℃下<-2>至30.10 2 Pa。（b）在乳化之前，在可乳化的羟基取代基之前具有聚有机硅氧烷树脂，并且在乳化之前包含选自式（R 0）3 SiO 1/2（M）的那些中的至少两种硫酸基单元; （R 0）2 SiO 2/2（D）; R0SiO3 / 2（T）和SiO4 / 2（Q）中的至少一个，所述单元中的至少一个为T或Q单元，其中：R 0表示一价有机取代基，硅原子的有机基团R 0的平均数范围在1到2之间; 并且所述树脂的羟基取代基的重量含量为0.1-10wt。％，优选0.2-5wt。％; （c）可溶于硅氧烷相的交联剂，其包含至少两种能够与聚有机硅氧烷树脂（b）反应的功能; 能够催化组分（b）与组分（c）的反应的缩合催化剂; （e）表面活性剂; 和（f）水。

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