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    • 3. 发明授权
    • Electrochemical assembly of organic molecules by the reduction of iodonium salts
    • 通过还原碘鎓盐来电化学组装有机分子
    • US07550071B1
    • 2009-06-23
    • US11065894
    • 2005-02-25
    • Shawn M. DirkStephen W. HowellDavid R. Wheeler
    • Shawn M. DirkStephen W. HowellDavid R. Wheeler
    • C25D7/12C25D11/00C25B3/00C25B3/12
    • C25D9/02C23C18/1896
    • Methods are described for the electrochemical assembly of organic molecules on silicon, or other conducting or semiconducting substrates, using iodonium salt precursors. Iodonium molecules do not assemble on conducting surfaces without a negative bias. Accordingly, the iodonium salts are preferred for patterning applications that rely on direct writing with negative bias. The stability of the iodonium molecule to acidic conditions allows them to be used with standard silicon processing. As a directed assembly process, the use of iodonium salts provides for small features while maintaining the ability to work on a surface and create structures on a wafer level. Therefore, the process is amenable for mass production. Furthermore, the assembled monolayer (or multilayer) is chemically robust, allowing for subsequent chemical manipulations and the introduction of various molecular functionalities for various chemical and biological applications.
    • 描述了使用碘鎓盐前体在硅或其它导电或半导体衬底上电化学组装有机分子的方法。 碘分子不会在没有负偏压的导电表面上组装。 因此,碘鎓盐优选用于依赖于负偏压的直接写入的图案化应用。 碘分子在酸性条件下的稳定性允许它们与标准硅处理一起使用。 作为定向组装方法,碘鎓盐的使用提供小特征,同时保持在表面上工作的能力并在晶片级上产生结构。 因此,该方法适合批量生产。 此外,组装的单层(或多层)是化学稳健的,允许随后的化学操作和引入用于各种化学和生物应用的各种分子功能。