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1. 发明授权

US06852229B2 Method for preparing high-purity ionic liquids 失效
标题翻译：制备高纯度离子液体的方法
公开(公告)号：US06852229B2
公开(公告)日：2005-02-08
申请号：US10277420
申请日：2002-10-22
申请人： Christian P. Mehnert , Nicholas C. Dispenziere , Raymond A. Cook
发明人： Christian P. Mehnert , Nicholas C. Dispenziere , Raymond A. Cook
IPC分类号： B01J31/02 , C07C45/50 , C07D213/20 , C07D521/00 , B01D11/04
CPC分类号： C07D213/20 , B01J31/0234 , C07D231/12 , C07D233/56 , C07D249/08
摘要： A method for preparing a high-purity ionic liquid having a pH value of 7 and an elemental analysis deviation of less than 0.5 wt % between a calculated elemental analysis and a found elemental analysis for each of carbon, hydrogen and nitrogen, wherein the method comprises forming a monophasic or biphasic mixture of an ionic liquid and an inert liquid. When the monophasic mixture is formed, it is filtered to yield a filtrate from which the high-purity ionic liquid is recovered. When the biphasic mixtures is formed, it is separated into an aqueous phase and ionic liquid phase, whereby the ionic liquid phase is filtered to yield a filtrate from which the high-purity ionic liquid is recovered. Furthermore, the present purification procedure can be used for the clean-up of a contaminated ionic liquid by extracting it into a polar extractant to form an extract containing the ionic liquid. Water traces are removed from the extract. Then, the extract is filtered and the high-purity ionic liquid is recovered from the filtered extract.
摘要翻译：在计算的元素分析和针对碳，氢和氮各自的元素分析中，制备pH值为7并且元素分析偏差小于0.5重量％的高纯度离子液体的方法，其中所述方法包括形成离子液体和惰性液体的单相或双相混合物。当形成单相混合物时，将其过滤以产生从其中回收高纯度离子液体的滤液。当形成双相混合物时，将其分离成水相和离子液相，由此过滤离子液相以产生从其中回收高纯度离子液体的滤液。此外，本纯化方法可用于通过将污染的离子液体提取到极性萃取剂中以形成含有离子液体的提取物来清理污染的离子液体。从提取物中除去水迹。然后，将提取物过滤并从过滤的提取物中回收高纯度离子液体。

2. 发明授权

US5254783A Catalyst comprising amorphous NiO on silica/alumina support and process for butene dimerization 失效
标题翻译：包含在二氧化硅/氧化铝载体上的无定形NiO的催化剂和用于丁烯二聚的方法
公开(公告)号：US5254783A
公开(公告)日：1993-10-19
申请号：US938094
申请日：1992-08-31
申请人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
发明人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
IPC分类号： B01J23/755 , B01J37/02 , B01J37/03 , C07C2/04
CPC分类号： B01J23/755 , B01J37/0217 , B01J37/031
摘要： The present invention provides for a catalyst composition which is effective for use in the production of dimer products and higher olefin products from lower olefins such as propylene and butene in high yields and with an average degree of branching in the dimer products of less than about 1.6 methyl groups per molecule, generally in the range of from about 1.0 to 1.4 methyl groups per molecule. The present invention also provides a process for producing such dimer and higher olefin products using the catalyst composition of this invention. The catalyst of the invention comprises an amorphous nickel oxide (NiO) present as a disperse substantial monolayer on the surfaces of a silica (SiO.sub.2) support, which support also contains minor amounts of an oxide of aluminum, gallium or indium such that the ratio of NiO to metal oxide present in the catalyst is within the range of from about 4:1 to about 100:1. The catalyst may be prepared by precipitating a water insoluble nickel salt onto the surfaces of a silica support which has been impregnated with the metal oxide or onto a silica-alumina support which has been dealuminized such that the resulting nickel oxide/alumina ratio will fall within the ranges set forth above. The catalyst may then be activated by calcination in the presence of oxygen at a temperature within the range of from about 500.degree. to 700.degree. C.
摘要翻译：本发明提供了一种催化剂组合物，其有效用于以高产率从低级烯烃如丙烯和丁烯生产二烯体产物和高级烯烃产物，并且二聚体产物中的平均支化度小于约1.6 每个分子的甲基基团，通常在每分子约1.0至1.4个甲基的范围内。本发明还提供了使用本发明的催化剂组合物生产这种二聚物和较高级烯烃产物的方法。本发明的催化剂包括在二氧化硅（SiO 2）载体的表面上作为分散实质单层存在的无定形氧化镍（NiO），该载体还含有少量的铝，镓或铟的氧化物，存在于催化剂中的NiO与金属氧化物在约4:1至约100:1的范围内。催化剂可以通过将水不溶性镍盐沉淀到已经浸渍有金属氧化物的二氧化硅载体的表面上或已经脱铝的二氧化硅 - 氧化铝载体上，使得所得到的氧化镍/氧化铝比落入上述范围。催化剂然后可以在氧的存在下在约500-700℃的温度下煅烧来活化。

3. 发明授权

US5073658A Catalyst comprising TiO.sub.2 dispersed phase on a monolayer of SiO.sub.2 on alumina support 失效
标题翻译：包含TiO 2分散相的催化剂在氧化铝载体上的SiO 2单层上
公开(公告)号：US5073658A
公开(公告)日：1991-12-17
申请号：US644959
申请日：1991-01-22
申请人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
发明人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
IPC分类号： B01J21/12 , B01J23/08 , B01J37/08 , C07C2/10
CPC分类号： B01J37/086 , B01J21/12 , B01J23/08 , C07C2/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/08
摘要： The present invention provides for a non-nickel-containing catalyst which is effective for use in the production of dimer products and higher olefin products from a butene starting material at relatively high conversion, good selectivity towards octene production and good activity maintenance over prolonged polymerization times. The catalyst is prepared by impregnating an amorphous trivalent metal oxide support selected from the group consisting of aluminum oxide, gallium oxide and indium oxide with a silicon-containing precursor compound which, after calcination, yields a substantial mono layer of SiO.sub.2 on the surface of the metal oxide support. A disperse layer of TiO.sub.2 is then deposited on the surface of the SiO.sub.2 monolayer by application of a solvent solution of a precursor compound containing titanium onto the SiO.sub.2 monolayer, followed by calcination to reduce the precursor titanium compound to TiO.sub.2.
摘要翻译：本发明提供一种非镍的催化剂，其有效用于从相对较高转化率的丁烯原料生产二聚体产物和较高级烯烃产物，对于辛烯生产具有良好的选择性，并且在延长的聚合时间内具有良好的活性维持。催化剂是通过将选自氧化铝，氧化镓和氧化铟的无定形三价金属氧化物载体与含硅前体化合物浸渍制备的，其在煅烧后在其表面上产生基本的单层SiO 2 金属氧化物载体。然后通过将含有钛的前体化合物的溶剂溶液施加到SiO 2单层上，然后将TiO 2的分散层沉积在SiO 2单层的表面上，随后煅烧以将前体钛化合物还原成TiO 2。

4. 发明授权

US5113034A Dimerization catalyst and process therefor 失效
标题翻译：二聚催化剂及其工艺
公开(公告)号：US5113034A
公开(公告)日：1992-05-12
申请号：US740251
申请日：1991-08-05
申请人： Stuart L. Soled , Nicholas C. Dispenziere, Jr. , Ramzi Y. Saleh , Sabato Miseo
发明人： Stuart L. Soled , Nicholas C. Dispenziere, Jr. , Ramzi Y. Saleh , Sabato Miseo
IPC分类号： B01J21/06 , B01J23/30 , B01J27/047 , B01J27/053 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C11/107
CPC分类号： B01J21/066 , B01J21/063 , B01J23/30 , B01J27/053 , C07C2/10 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12
摘要： A solid, acid catalyst, supported or unsupported, comprised of an anion modified Group IVB oxide is used to dimerize C.sub.3 or C.sub.4 containing feedstreams.

5. 发明授权

US4692428A Preparation and use of catalysts comprising mixtures of tungsten oxide and silica on alumina 失效
标题翻译：制备和使用包含氧化钨和二氧化硅在氧化铝上的混合物的催化剂
公开(公告)号：US4692428A
公开(公告)日：1987-09-08
申请号：US815201
申请日：1985-12-31
申请人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr. , Richard S. Polizzotti
发明人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr. , Richard S. Polizzotti
IPC分类号： B01J23/30 , C10G11/04 , B01J21/12
CPC分类号： B01J23/30 , C10G11/04
摘要： Useful cracking catalysts and catalyst supports comprising mixtures of tungsten oxide and silica supported on alumina are prepared by forming a composite of a mixture of (a) particles of tungsten oxide or one or more suitable tungsten oxide precursors, (b) particles of silica and (c) particles of porous alumina and steaming said composite at a temperature of at least about 500.degree. C. in a non-reducing environment for a time sufficient for at least a portion of the tungsten oxide and silica to disperse over the alumina surface. The mixture of silica and tungsten oxide wets, spreads out and reacts with the surface hydroxyl groups of the alumina.
摘要翻译：通过形成（a）氧化钨颗粒或一种或多种合适的氧化钨前体的混合物，（b）二氧化硅颗粒和（a）的混合物的复合物，制备包含氧化钨和负载在氧化铝上的二氧化硅的混合物的有用的裂解催化剂和催化剂载体， c）多孔氧化铝颗粒并在非还原环境中在至少约500℃的温度下将所述复合材料蒸汽充分足以使至少一部分氧化钨和二氧化硅分散在氧化铝表面上的时间。二氧化硅和氧化钨的混合物润湿，展开并与氧化铝的表面羟基反应。

6. 发明授权

US5169824A Catalyst comprising amorphous NiO on silica/alumina support 失效
标题翻译：包含在二氧化硅/氧化铝载体上的无定形NiO的催化剂
公开(公告)号：US5169824A
公开(公告)日：1992-12-08
申请号：US644998
申请日：1991-01-22
申请人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
发明人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
IPC分类号： B01J23/755 , B01J37/02 , B01J37/03
CPC分类号： B01J37/0217 , B01J23/755 , B01J37/031
摘要： The present invention provides for a catalyst composition which is effective for use in the production of dimer products and higher olefin products from lower olefins such as propylene and butene in high yields and with an average degree of branching in the dimer products of less than about 1.6 methyl groups per molecule, generally in the range of from about 1.0 to 1.4 methyl groups per molecule. The present invention also provides a process for producing such dimer and higher olefin products using the catalyst composition of this invention. The catalyst of the invention comprises an amorphous nickel oxide (NiO) present as a disperse substantial monolayer on the surfaces of a silica (SiO.sub.2) support, which support also contains minor amounts of an oxide of aluminum, gallium or indium such that the ratio of NiO to metal oxide present in the catalyst is within the range of from about 4:1 to about 100:1. The catalyst may be prepared by precipitating a water insoluble nickel salt onto the surfaces of a silica support which has been impregnated with the metal oxide or onto a silica-alumina support which has been dealuminized such that the resulting nickel oxide/alumina ratio will fall within the ranges set forth above. The catalyst may then be activated by calcination in the presence of oxygen at a temperature within the range of from about 500.degree. to 700.degree. C.
摘要翻译：本发明提供了一种催化剂组合物，其有效用于以高产率从低级烯烃如丙烯和丁烯生产二烯体产物和高级烯烃产物，并且二聚体产物中的平均支化度小于约1.6 每个分子的甲基基团，通常在每分子约1.0至1.4个甲基的范围内。本发明还提供了使用本发明的催化剂组合物生产这种二聚物和较高级烯烃产物的方法。本发明的催化剂包括在二氧化硅（SiO 2）载体的表面上作为分散实质单层存在的无定形氧化镍（NiO），该载体还含有少量的铝，镓或铟的氧化物，存在于催化剂中的NiO与金属氧化物在约4:1至约100:1的范围内。催化剂可以通过将水不溶性镍盐沉淀到已经浸渍有金属氧化物的二氧化硅载体的表面上或已经脱铝的二氧化硅 - 氧化铝载体上，使得所得到的氧化镍/氧化铝比落入上述范围。催化剂然后可以在氧的存在下在约500-700℃的温度下煅烧来活化。

7. 发明授权

US4891127A Preparation and use of catalysts comprising a mixture of tungsten oxide and silica supported on a boehmite-like surface 失效
标题翻译：制备和使用包含负载在勃姆石样表面上的氧化钨和二氧化硅的混合物的催化剂
公开(公告)号：US4891127A
公开(公告)日：1990-01-02
申请号：US310984
申请日：1989-02-15
申请人： Lawrence L. Murrel , Nicholas C. Dispenziere, Jr.
发明人： Lawrence L. Murrel , Nicholas C. Dispenziere, Jr.
IPC分类号： B01J21/12 , B01J23/30
CPC分类号： B01J21/12 , B01J23/30
摘要： Useful cracking catalysts and catalyst supports comprising a mixture of tungsten oxide and silica supported on a boehmite-like surface which, in turn, is supported on alumina are prepared by forming a composite of particles of (a) tungsten oxide, (b) silica and (c) boehmite and subjecting the composite to steaming at a temperature of at least about 500.degree. C. During the steaming, the tungsten oxide and silica react with the surface of the boehmite as the boehmite converts to alumina.
摘要翻译：包含负载在勃姆石状表面上的氧化钨和二氧化硅的混合物的有用的裂化催化剂和催化剂载体，其反过来负载在氧化铝上，通过形成（a）氧化钨，（b）二氧化硅和（c）勃姆石，并使复合材料在至少约500℃的温度下蒸汽。在蒸汽期间，随着勃姆石转化为氧化铝，氧化钨和二氧化硅与勃姆石的表面反应。

8. 发明授权

US4708945A Catalysts comprising silica supported on a boehmite-like surface, their preparation and use 失效
标题翻译：包含负载在勃姆石状表面上的二氧化硅的催化剂，其制备和用途
公开(公告)号：US4708945A
公开(公告)日：1987-11-24
申请号：US815220
申请日：1985-12-31
申请人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
发明人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
IPC分类号： B01J21/04 , B01J21/08 , B01J21/12 , B01J37/02 , C04B41/87 , C10G11/04 , C10G47/02
CPC分类号： B01J21/12 , B01J37/024 , C10G11/04
摘要： Useful cracking catalysts and catalyst supports comprising silica supported on a boehmite-like surface are prepared by compositing particles of silica or hydrated silica with particles of porous boehmite and subjecting the resulting composite to high temperature steaming at a temperature of at least about 600.degree. C. for a time sufficient to disperse at least a portion of the silica over the boehmite surface as the boehmite converts to .gamma.-Al.sub.2 O.sub.3. The silica wets, spreads out and reacts with the surface hydroxyl groups of the transforming boehmite.
摘要翻译：通过将二氧化硅或水合二氧化硅的颗粒与多孔勃姆石的颗粒合并并将所得复合材料在至少约600℃的温度下进行高温蒸汽来制备包含负载在勃姆石样表面上的二氧化硅的有用的裂解催化剂和催化剂载体。足以在勃姆石转化为γ-Al 2 O 3时将至少一部分二氧化硅分散在勃姆石表面上。二氧化硅浸湿，展开并与转化勃姆石的表面羟基反应。

9. 发明授权

US4831007A Preparation and use of catalysts comprising a mixture of tungsten oxide and silica supported on a boehmite-like surface 失效
标题翻译：制备和使用包含负载在勃姆石样表面上的氧化钨和二氧化硅的混合物的催化剂
公开(公告)号：US4831007A
公开(公告)日：1989-05-16
申请号：US815202
申请日：1985-12-31
申请人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
发明人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr.
IPC分类号： B01J21/12 , B01J23/30
CPC分类号： B01J23/30 , B01J21/12
摘要： Useful cracking catalysts and catalyst supports comprising a mixture of tungsten oxide and silica supported on a boehmite-like surface which, in turn, is supported on alumina are prepared by forming a composite of particles of (a) tungsten oxide, (b) silica and (c) boehmite and subjecting the composite to steaming at a temperature of at least about 500.degree. C. During the steaming, the tungsten oxide and silica react with the surface of the boehmite as the boehmite converts to alumina.
摘要翻译：包含负载在勃姆石状表面上的氧化钨和二氧化硅的混合物的有用的裂化催化剂和催化剂载体，其反过来负载在氧化铝上，通过形成（a）氧化钨，（b）二氧化硅和（c）勃姆石，并使复合材料在至少约500℃的温度下蒸汽。在蒸汽期间，随着勃姆石转化为氧化铝，氧化钨和二氧化硅与勃姆石的表面反应。

10. 发明授权

US4778779A Catalysts comprising silica supported on alumina, their preparation and use 失效
标题翻译：包含负载在氧化铝上的二氧化硅的催化剂，其制备和用途
公开(公告)号：US4778779A
公开(公告)日：1988-10-18
申请号：US37506
申请日：1987-04-13
申请人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr. , David E. Vaughan
发明人： Lawrence L. Murrell , Nicholas C. Dispenziere, Jr. , David E. Vaughan
IPC分类号： B01J21/12 , C10G11/04 , C10G47/16
CPC分类号： C10G11/04 , B01J21/12
摘要： Useful cracking catalysts and catalyst supports comprising silica supported on alumina are prepared by compositing particles of silica or silica precursor with particles of porous alumina and subjecting the resulting composite to high temperature steaming in a non-reducing environment at a temperature of at least about 500.degree. C. for a time sufficient to disperse at least a portion of the silica over the alumina surface. The silica wets, spreads out and reactions with the surface hydroxyul groups of the alumina. The supported silica on alumina composites that can be made from this process may exhibit properties of both bulk silica and bulk alumina at the same time, bulk silica and alumina whose exterior surface only has been modified with silica as wells as composites exhibiting surface properties different from both bulk silica and bulk alumina.
摘要翻译：通过将二氧化硅或二氧化硅前体的颗粒与多孔氧化铝的颗粒合成，并将所得的复合材料在至少约500℃的非还原性环境中进行高温蒸汽来制备包含负载在氧化铝上的二氧化硅的有用的裂解催化剂和催化剂载体在足以在氧化铝表面上分散二氧化硅的至少一部分的时间。二氧化硅湿润，扩散和与氧化铝的表面羟基的反应。可以由该方法制备的负载二氧化硅的氧化铝复合材料可以同时显示本体二氧化硅和本体氧化铝的本体二氧化硅和氧化铝的性质，其外表面仅仅用二氧化硅作为表面改性的复合材料，表现出与本体二氧化硅和体积氧化铝。

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