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    • 10. 发明授权
    • Compound, manufacturing method thereof, acid generator, resist composition and method of forming resist pattern
    • 化合物,其制造方法,酸产生剂,抗蚀剂组合物和形成抗蚀剂图案的方法
    • US07745097B2
    • 2010-06-29
    • US12174293
    • 2008-07-16
    • Hideo HadaTakeshi IwaiTakehiro SeshimoAkiya KawaueKeita Ishiduka
    • Hideo HadaTakeshi IwaiTakehiro SeshimoAkiya KawaueKeita Ishiduka
    • G03F7/004G03F7/30
    • C07D335/02C07C309/04C07D333/46G03F7/0045G03F7/0397Y10S430/106Y10S430/111Y10S430/122Y10S430/123
    • There are provided a novel compound represented by a general formula (b1-1) shown below, which is useful as an acid generator for a resist composition and a manufacturing method thereof, a compound useful as a precursor of the novel compound and a manufacturing method thereof, an acid generator, a resist composition and a method of forming a resist pattern. (wherein, R1 represents an aryl group or alkyl group which may contain a substituent group; R3 represents a hydrogen atom or an alkyl group; n1 represents an integer of 0 or 1, and in the case that n1 is 1, R1 and R3 may mutually be bonded to form a ring with a 3- to 7-membered ring structure together with the carbon atom with which R1 is bonded and the carbon atom with which R3 is bonded; A represents a bivalent group which forms a ring with 3- to 7-membered ring structure together with the sulfur atom with which A is bonded, and the ring may contain a substituent group; R2 represents an aromatic group which may contain a substituent group, a linear or branched alkyl group of 1 to 10 carbon atoms which may contain a substituent group, or a linear or branched alkenyl group of 2 to 10 carbon atoms which may contain a substituent group; n represents an integer of 0 or 1; and Y1 represents an alkylene group of 1 to 4 carbon atoms in which hydrogen atoms may be substituted with fluorine atoms.).
    • 提供了由下述通式(b1-1)表示的新化合物,其可用作抗蚀剂组合物的酸产生剂及其制备方法,可用作新化合物的前体的化合物和制备方法 酸产生剂,抗蚀剂组合物和形成抗蚀剂图案的方法。 (其中,R1表示可以含有取代基的芳基或烷基,R3表示氢原子或烷基,n1表示0或1的整数,在n1为1的情况下,R 1和R 3可以 相互键合形成具有3〜7元环结构的环以及与R 1键合的碳原子和与R3结合的碳原子; A表示与3-至 7元环结构与A键合的硫原子一起形成,环可含有取代基; R2表示可含有取代基的芳香族基团,碳原子数1〜10的直链或支链烷基, 可以含有取代基,或可以含有取代基的2〜10个碳原子的直链或支链烯基; n表示0或1的整数; Y1表示碳原子数为1〜4的亚烷基,其中氢 原子可以被氟取代 oms)。