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    • 1. 发明授权
    • 스프레이 코팅을 이용한 β-상 PVDF 필름을 포함하는 발전소자의 제조방법
    • 使用喷雾涂层生产B相PVDF膜的元件的制备方法
    • KR101348902B1
    • 2014-01-08
    • KR1020130010542
    • 2013-01-30
    • 인하대학교 산학협력단
    • 노임준신백균정대용이선우
    • H01L41/22
    • H01L41/317H01L41/0805H01L41/187H01L41/193H01L41/39
    • The present invention relates to a method for manufacturing a generating element including a β-phase PVDF film using spray coating, specifically, to method for manufacturing a β-phase PVDF generating element comprising: dissolving PVDF in a solvent (step 1); manufacturing a PVDF film by spray-coating a solution, in which the PVDF is dissolved in step 1, onto a substrate (step 2); separating the PVDF film, manufactured in step 2, from the substrate (step 3); and interposing the β-phase PVDF film, separated in step 3, between a cathode part and an anode part. A method for manufacturing a β-phase PVDF generating element using spray coating may manufacture a β-phase PVDF film through a greatly simplified process in comparison with a conventional stretching and poling process, and particularly, easily manufacture the β-phase PVDF film by omitting a stretching process. In addition, by further comprising carbon nanotubes, there is an effect that electrical characteristics are further improved.
    • 本发明涉及一种用于制造包括使用喷涂的β相PVDF膜的发生元件的方法,具体地说,涉及制造β相PVDF产生元件的方法,包括:将PVDF溶解在溶剂(步骤1)中; 通过将PVDF在步骤1中溶解的溶液喷涂到基材上来制造PVDF膜(步骤2); 将步骤2中制造的PVDF膜从基板分离(步骤3); 并且将在步骤3中分离的β相PVDF膜插入阴极部分和阳极部分之间。 使用喷涂法制造β相PVDF发生元件的方法可以与常规的拉伸和极化工艺相比,通过大大简化的工艺制造β相PVDF膜,特别是通过省略容易地制造β相PVDF膜 拉伸过程。 此外,通过进一步包含碳纳米管,具有进一步提高电特性的效果。
    • 3. 发明公开
    • 고압전 계수 박막의 제조방법
    • 具有高压电常数的薄压电薄膜的制造方法
    • KR1020110139515A
    • 2011-12-29
    • KR1020100059644
    • 2010-06-23
    • 한국산업기술대학교산학협력단
    • 이희철이성의변진무
    • H01L41/318H01L41/39
    • H01L41/318C04B35/491H01L41/1876H01L41/39
    • PURPOSE: A fabrication method of thin piezoelectric films with high piezoelectric constant is provided to implement rapid reaction between materials by using a distillation with high temperature in manufacturing a PZT sol-gel solution. CONSTITUTION: In a fabrication method of thin piezoelectric films with high piezoelectric constant, a lead precursor is dissolved in C1-C10 alkoxy alcohol. The lead precursor solution is manufactured. A zirconium precursor and a titanium precursor are mixed in the C1-C10 alkoxy alcohol. A zirconium / titanium precursor solution is manufactured. The lead precursor solution and zirconium / titanium precursor solution are mixed. A PZT solution is manufactured. The C1-C10 alkoxy alcohol and ethylene glycol are added to the PZT solution. A PZT sol-gel solution is manufactured. The PZT sol-gel solution is heat-treated and is coated in the top of the substrate.
    • 目的:提供一种具有高压电常数的薄压电薄膜的制造方法,通过在制造PZT溶胶 - 凝胶溶液中使用高温蒸馏来实现材料之间的快速反应。 构成:在具有高压电常数的薄压电薄膜的制造方法中,将铅前体溶解在C1-C10烷氧基醇中。 制造铅前体溶​​液。 将锆前体和钛前体混合在C1-C10烷氧基醇中。 制造锆/钛前体溶液。 铅前体溶液和锆/钛前体溶液混合。 制造PZT溶液。 将C1-C10烷氧基醇和乙二醇加入到PZT溶液中。 制造PZT溶胶 - 凝胶溶液。 PZT溶胶 - 凝胶溶液被热处理并涂覆在基材的顶部。
    • 4. 发明公开
    • 무연(無鉛)계 압전 세라믹스 및 그 제조방법
    • 无铅压电陶瓷及其制备方法
    • KR1020040054965A
    • 2004-06-26
    • KR1020020081519
    • 2002-12-20
    • 한국산업기술평가원(관리부서:요업기술원)
    • 조정호이용현김병익
    • C04B35/46H01L41/187
    • H01L41/187C04B2235/3232H01L41/39
    • PURPOSE: Provided is a lead-free piezoelectric ceramics which can improve stability after being sintered, and prevent volatilization of PbO, thereby being environmentally friendly. The lead-free piezoelectric also has high specific gravity and good compaction property due to its homogeneous particle distribution and fine particles, and has improved dielectric constant and electric properties due to its optimized sintering and polarizing condition. CONSTITUTION: The lead-free piezoelectric ceramics is represented by the following formula 1 having a Perovskite structure: (A1/2B1/2)1-xCxTiO3, wherein A is Bi, Y or Sb ion; B is K or Na ion; C is Ca, Ba or Ni ion; x is an integer in the range of 0.0005-0.10. The piezoelectric ceramics is prepared by carrying out a first milling and calcination of a mixture of A, B and C at 600-1100 deg.C for 0.5-5 hours, wherein A is selected from Bi2O3, Y2O3 and Sb2O3; B is selected from K2CO3 and Na2CO3; C is selected from CaCO3, BaCO3 and NiO3 to obtain a first powder; and adding TiO2 to the first powder, and then carrying out a second milling and calcination at 600-900 deg.C for 0.5-5 hours to obtain a second powder.
    • 目的:提供一种无铅压电陶瓷,可以提高烧结后的稳定性,防止PbO的挥发,从而环保。 无铅压电材料由于其均匀的颗粒分布和细颗粒而具有高比重和良好的压实性能,并且由于其优化的烧结和极化条件而具有改善的介电常数和电性能。 构成:无铅压电陶瓷由具有钙钛矿结构的下式1表示:(A1 / 2B1 / 2)1-xCxTiO3,其中A为Bi,Y或Sb离子; B是K或Na离子; C是Ca,Ba或Ni离子; x是0.0005-0.10范围内的整数。 通过在600-1100℃下对A,B和C的混合物进行第一次研磨和煅烧0.5-5小时制备压电陶瓷,其中A选自Bi 2 O 3,Y 2 O 3和Sb 2 O 3; B选自K 2 CO 3和Na 2 CO 3; C选自CaCO 3,BaCO 3和NiO 3,得到第一粉末; 并向第一粉末中加入TiO 2,然后在600-900℃下进行第二次研磨和煅烧0.5-5小时,得到第二粉末。
    • 9. 发明公开
    • 저온소결 압전세라믹 조성물 및 그 제조방법
    • 低温烧结PSN-PZT-PNW压电陶瓷组合物及其制备
    • KR1020050004993A
    • 2005-01-13
    • KR1020030044104
    • 2003-07-01
    • 류주현
    • 류주현
    • C04B35/493
    • H01L41/187C04B2235/3281H01L41/39
    • PURPOSE: Provided is a low temperature sintered piezoelectric composition excellent in mechanical quality factor(Qm) and electromechanical coupling coefficient(Kp) by adding CuO to the PSN-PZT-PNW composition. CONSTITUTION: The PSN-PZT-PNW-based piezoelectric ceramic composition is prepared by the following steps of: mixing raw materials in the proportions corresponding to a PSN-PZT-PNW composition, 0.91Pb(Sb1/2Nb1/2)0.03(ZrxTi1-x)0.97O3 + 0.04Pb(Ni1/2W1/2)O3 + 0.3wt.% MnO2 (0.48
    • 目的:通过向PSN-PZT-PNW组合物中添加CuO,提供了机械品质因数(Qm)和机电耦合系数(Kp)优异的低温烧结压电组合物。 构成:以PSN-PZT-PNW组合物,0.91Pb(Sb1 / 2Nb1 / 2)0.03(ZrxTi1 / 2)为基准的比例混合原料,制备基于PSN-PZT-PNW的压电陶瓷组合物, x)0.97O3 + 0.04Pb(Ni1 / 2W1 / 2)O3 + 0.3wt。%MnO2(0.48 <= x <= 0.51); 球磨,干燥和煅烧混合物在850℃; 添加0.2-0.6重量%的CuO; 球磨和干燥得到压电组合物,用公式0.91Pb(Sb1 / 2Nb1 / 2)0.03(ZrxTi1-x)0.97O3 + 0.04Pb(Ni1 / 2W1 / 2)O3 + 0.3wt。%MnO2 + 0.6重量%的CuO(0.48 <= x <= 0.51); 形成干燥的组合物; 烧结于920℃。