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    • 2. 发明公开
    • 아조 모이어티를 포함하는 금속착물 착색제
    • 金属复合颜料包含AZO MOIETY展示各种颜色,并具有可用于各种应用的耐久性改进
    • KR1020050017755A
    • 2005-02-23
    • KR1020030055022
    • 2003-08-08
    • 삼성전자주식회사
    • 정연경유승민이경훈
    • C09B45/00
    • C09B45/04
    • PURPOSE: Provided metal complex colorant having improved endurances such as light stability and water-resistance as well as exhibition of varied colors and useful in applications including fabric, food, medicine, cosmetic, paint, ink, ceramics requiring colors. CONSTITUTION: The metal complex colorant is represented by the following formula 1 (wherein A1 and A2 each independently contain substituted or non-substituted alkenylene group having 2 to 30 carbon atoms with at least one double bonds and are conjugated moieties with azo groups; X1 and X2 each are hydroxy group, or alkoxy group, carboxyl group or substituted and/or non-substituted amino group having 1 to 4 carbon atoms; M is multi-valent transition metal; L is neutral or anionic ligand; T is mono-substituted or multi-substituted hydrophilic functional group; N is integer of 1 to 3; J is linker). The multi-valent transition metal is selected from silver, aluminum, gold, cerium, cobalt, chromium, copper, europium, iron, potassium, germanium, indium, lanthanide, manganese, nickel, palladium, platinum, rhodium, ruthenium, scandium, silicon, samarium, titanium, uranium, zinc or zirconium.
    • 目的:提供具有改善的耐光性,耐光性和耐水性的金属络合物着色剂以及各种颜色的展示,并且可用于包括织物,食品,医药,化妆品,油漆,油墨,需要颜色的陶瓷的应用中。 构成:金属络合物着色剂由下式1表示(其中A1和A2各自独立地含有具有2-30个碳原子的取代或未取代的亚烯基,具有至少一个双键,并且具有偶氮基团的共轭部分; X1和 X2分别是羟基或烷氧基,羧基或具有1-4个碳原子的取代和/或未取代的氨基; M是多价过渡金属; L是中性或阴离子配体; T是单取代或 多取代亲水性官能团; N为1〜3的整数; J为连接基)。 多价过渡金属选自银,铝,金,铈,钴,铬,铜,铕,铁,钾,锗,铟,镧系元素,锰,镍,钯,铂,铑,钌,钪, ,钐,钛,铀,锌或锆。