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    • 8. 发明公开
    • 중합 촉매 조성물 및 폴리머의 제조 방법
    • 聚合催化剂组合物和聚合物生产方法
    • KR1020070110058A
    • 2007-11-15
    • KR1020077020132
    • 2006-02-21
    • 미쓰이 가가쿠 가부시키가이샤
    • 스즈키마코토이노우에요시히사노보리다다히토야마모토요시히로
    • C08F4/40C08F4/64C08F20/00C08F22/00
    • C08F10/00C08F4/00C08F4/26C08F4/40C08F112/08C08F120/14C08F120/18
    • A polymerization catalyst composition for a radical polymerizable monomer, comprising a transition metal-containing phosphazenium composition which is produced by mixing a phosphazenium compound represented by the general formula (1) below with a compound of a transition metal belonging to Groups 4 to 12 on the periodic table with an organic halogen compound: (1) wherein n is an integer of 1 or greater which represents the numbers of phosphazenium cations; Zn- represents an anion of an active hydrogen compound in the form that is induced by allowing to leave n protons from an active hydrogen compound having n active hydrogen atoms; a, b, c and d independently are an positive integer of 3 or smaller or 0, provided that all of a, b, c and d are not 0; and R1 to R 24 independently represent a hydrocarbon group having 1 to 10 carbon atoms and R1 and R2, R3 to R 4, R5 and R6, R7 and R8, R9 and R10, R11 and R12, R13 and R14, R15 and 16, R17 and R18, R19 and R20, R21 and R22, or R23 and R24 may together form a ring.
    • 一种自由基聚合性单体的聚合催化剂组合物,其含有过渡金属的磷氮杂鎓鎓组合物,其通过将下述通式(1)表示的磷氮烯基鏻化合物与属于第4〜12族的过渡金属的化合物 具有有机卤素化合物的周期表:(1)其中n为1或更大的整数,表示磷氮烯基鏻阳离子的数目; Zn-表示通过允许从具有n个活性氢原子的活性氢化合物离开n个质子而诱导的形式的活性氢化合物的阴离子; a,b,c和d独立地为3或更小或0的正整数,条件是a,b,c和d都不为0; 并且R 1至R 24独立地表示具有1-10个碳原子的烃基,且R 1和R 2,R 3至R 4,R 5和R 6,R 7和R 8,R 9和R 10,R 11和R 12,R 13和R 14,R 15和16, R 17和R 18,R 19和R 20,R 21和R 22或R 23和R 24可以一起形成环。