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    • 7. 发明公开
    • 8족 금속 촉매 착물 혼합물로부터 트리아릴포스핀을회수하는 방법
    • 从VIII族金属催化剂复合混合物中回收三价膦酸的方法
    • KR1020080023286A
    • 2008-03-13
    • KR1020077023971
    • 2006-03-22
    • 옥세아 코포레이션
    • 샤바쿨레쉬엔.
    • C07F9/50
    • B01J31/4053B01J31/2404B01J31/4023B01J31/4046B01J38/68B01J2231/321B01J2531/80B01J2531/821B01J2531/822B01J2531/824B01J2531/825B01J2531/827C07F9/5095Y02P20/584
    • Processes for recovering at least one triarylphosphine from a Group VIII metal catalyst triarylphosphine complex mixture are provided. The processes are particularly useful for recovering the triarylphosphine from spent Group VIII metal catalyst complex mixtures. The processes include the steps of (i) forming a distillate from a Group VIII catalyst complex mixture containing a Group VIII metal catalyst complex, a triarylphosphine, and a light ends component wherein the distillate contains at least a portion of the triarylphosphine as a vapor and at least a portion of the light ends component as a vapor; (ii) cooling the distillate to a temperature below the boiling point of the light ends component to form a condensate; (iii) crystallizing at least a portion of the triarylphosphine using the light ends component as a crystallizing liquid; and (v) recovering the crystallized triarylphosphine from the condensate. ® KIPO & WIPO 2008
    • 提供了从VIII族金属催化剂三芳基膦配合物混合物中回收至少一种三芳基膦的方法。 该方法特别适用于从废Ⅷ族金属催化剂络合物混合物中回收三芳基膦。 该方法包括以下步骤:(i)由含有第VIII族金属催化剂络合物,三芳基膦和轻馏分组分的VIII族催化剂络合物混合物形成馏出物,其中馏出物含有至少一部分三芳基膦作为蒸气, 轻馏分的至少一部分作为蒸气; (ii)将馏出物冷却到低于轻馏分组分沸点的温度以形成冷凝物; (iii)使用轻质末端成分作为结晶液体使至少一部分三芳基膦结晶; 和(v)从冷凝物中回收结晶的三芳基膦。 ®KIPO&WIPO 2008