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1. 发明公开

KR1020070091615A 광 조사에 의해 표면 릴리프 구조 및 광학적 이방성 구조를제조 및 유도하는 방법 및 광활성 필름 无效
标题翻译：光电膜，其制备和使用，以及通过辐射电影制备表面放射和光学非均质结构
公开(公告)号：KR1020070091615A
公开(公告)日：2007-09-11
申请号：KR1020077013119
申请日：2005-12-08
申请人： 프라운호퍼-게젤샤프트 츄어 푀르더룽 데어 안게반텐 포르슝에.파우.
发明人： 스툼페,조아침 , 골덴베르그,레오니드 , 쿨리코브스카,올가
IPC分类号： C08J5/00 , G03F7/00
CPC分类号： G11B7/245 , G03C1/733 , G11B7/246 , G11B7/2467 , G11B7/2475 , G11B7/249 , G11B7/25 , G11B7/2531 , G11B7/257 , Y10T428/24479 , Y10T428/24802
摘要： The present invention relates to a homogeneous, photoactive film consisting of or comprising a polyelectrolyte carrying residues which may undergo a photoreaction, the polyelectrolyte mainly comprising at least one structure according to any of formulae (I) to (IV), namely [Pol(R*-P-R')] oon+ n/x Ax- (I), n/x Ax+ [Pol(R*-P-R') ]oon- (II), [Pol(R1*-Q-R1')]oon+ n/x Ax- (III), n/x Ax+ [Pol(R1*-Q-R1')]oon-(IV), wherein Pol means a repeating unit of a linear or branched polymer chain, o indicates the number of the repeating unit of the polymer chain, and (R*-P-R') and (R1*-Q-R1') are n-fold positively or negatively charged side chains of the repeating unit Pol, wherein P is a group which is capable of photo-induced E/Z isomerization, Q is a group capable of participating in a photocycloaddition, or capable of participating in a photoinduced rearrangement, or the so called Photo-Fries reaction, A is a cation or anion which is oppositely charged, n is preferably 1 or 2, x is 1 or 2, and o is at least 2, with the proviso that in one polyelectrolyte, groups [R-P-R'] and/or [R1-Q-R1'] all have the same sign. The invention is further directed to the preparation of the film, its use and a method for the preparation of a replica of a film of the invention having a surface relief structure.
摘要翻译：本发明涉及一种均匀的光活性膜，其由携带可能经历光反应的残余物的聚电解质组成或包含，该聚电解质主要包含至少一种根据式（I）至（IV）中任一项的结构，即[Pol * - （I），n / x Ax + [Pol（R * -P-R'）] oon-（II），[Pol（R1 * -Q-R1' ）] oon + n / x Ax-（III），n / x Ax + [Pol（R1 * -Q-R1'）] oon-（IV）其中Pol表示直链或支链聚合物链的重复单元，o表示聚合物链的重复单元的数目和（R * -P-R'）和（R1 * -Q-R1'）是重复单元Pol的n倍带正电荷或带负电荷的侧链，其中P是能够进行光诱导的E / Z异构化的基团，Q是能够参与光环加成或能够参与光诱导重排的基团或所谓的光 - 反应反应，A是阳离子或阴离子， n相对充电，n优选为1或2，x为1或2，o为至少2，条件是在一个聚电解质中，[R-P-R']和/或[R1-Q-R1']基团都具有相同的符号。本发明进一步涉及膜的制备，其用途和制备本发明的具有表面浮雕结构的膜的复制品的方法。

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