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    • 1. 发明公开
    • 연료유의 저온 특성 개선용 첨가제
    • 改善燃料油冷性能的添加剂
    • KR1020080008285A
    • 2008-01-23
    • KR1020070071847
    • 2007-07-18
    • 클라리언트 파이넌스 (비브이아이)리미티드
    • 지겔코프벳티나라이만베르너크룰맛티아스노이하우스울리케쿠페츠마르쿠스그라프안드레
    • C10L1/19C10L1/183
    • C10L1/146C10L1/1641C10L1/165C10L1/1658C10L1/1966C10L1/1973C10L1/1981C10L1/1985C10L1/224C10L1/2364C10L10/14
    • An additive mixture, a method for preparing terpolymer, a method for improving the fluidity of fuel oil, a composition comprising the additive mixture, and a fuel composition comprising the additive mixture are provided to have a useful application to improve cold properties of fuel oil. An additive mixture comprises at least one terpolymer(A) of ethylene, propene and at least one ethylene-based unsaturated ester, and at least one additive component of 0.5-20 wt%. The terpolymer contains 6.0-12.0 mol % of structural units derived from at least one ethylene-based unsaturated ester having a C1-C3 alkyl radical, 0.5-4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and less than 8.0 methyl groups from chain ends per 100 CH2 groups. The additive component is effective as a cold additive for mineral oil, based on the terpolymer. The additive component is selected from at least one copolymer(B1) of ethylene and an ethylene-based unsaturated compound, a comb-shaped polymer(B2), and a mixture(B3) of the copolymer and the comb-shaped polymer. A content of ethylene-based unsaturated compound in the copolymer is higher than a content of the ethylene-based unsaturated ester in the terpolymer by no less than 2 mol%. Further, the ethylene-based unsaturated ester is a vinyl ester of carboxylic acid having 1~4 carbon number.
    • 提供添加剂混合物,三元共聚物的制备方法,改进燃料油的流动性的方法,包含该添加剂混合物的组合物和包含该添加剂混合物的燃料组合物被提供用于改善燃料油的冷特性。 添加剂混合物包含至少一种乙烯,丙烯和至少一种乙烯基不饱和酯的三元共聚物(A)和至少一种0.5-20重量%的添加剂组分。 三元共聚物含有6.0-12.0mol%的衍生自至少一种具有C1-C3烷基的乙烯基不饱和酯,0.5-4.0个由每100个脂族碳原子衍生自丙烯的甲基和少于8.0个甲基的结构单元, 每100个CH2基团的链末端。 添加剂组分基于三元共聚物作为矿物油的冷添加剂是有效的。 添加剂组分选自乙烯和乙烯类不饱和化合物的至少一种共聚物(B1),共聚物和梳形聚合物的梳状聚合物(B2)和混合物(B3)。 共聚物中乙烯类不饱和化合物的含量高于三元共聚物中乙烯类不饱和酯的含量不少于2摩尔%。 此外,乙烯类不饱和酯是具有1〜4个碳数的羧酸的乙烯基酯。