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1. 发明授权

KR102025194B1 우수한 내수성, 내화학성, 및 내후성을 갖는 고분자 공중합체를 포함하는 복합체 및 이의 제조방법. 有权
公开(公告)号：KR102025194B1
公开(公告)日：2019-09-25
申请号：KR1020130009618
申请日：2013-01-29
申请人： 주식회사 한국엔티켐
发明人： 김중현 , 이선종 , 이승환 , 박홍관 , 김인영 , 조원석 , 유도혁 , 이정준
IPC分类号： C08K5/42 , C08F20/10 , C08J5/18 , C08K3/04 , C08L65/00 , C08K3/08 , C08L101/12

2. 发明授权

KR101970698B1 우수한 내수성, 내화학성, 및 내후성을 갖는 고분자 공중합체 및 이의 제조방법. 有权
公开(公告)号：KR101970698B1
公开(公告)日：2019-08-13
申请号：KR1020120086173
申请日：2012-08-07
申请人： 주식회사 한국엔티켐
发明人： 김중현 , 이선종 , 이승환 , 박홍관 , 김인영 , 조원석 , 유도혁 , 이정준
IPC分类号： C08F261/02 , C08F2/24 , C08J5/18

3. 发明公开

KR1020140096707A 우수한 내수성, 내화학성, 및 내후성을 갖는 고분자 공중합체를 포함하는 복합체 및 이의 제조방법. 审中-实审
标题翻译：具有优异耐水性，耐化学性和耐候性的高分子量共聚物复合物及其制备方法。
公开(公告)号：KR1020140096707A
公开(公告)日：2014-08-06
申请号：KR1020130009618
申请日：2013-01-29
申请人： 주식회사 한국엔티켐
发明人： 김중현 , 이선종 , 이승환 , 박홍관 , 김인영 , 조원석 , 유도혁 , 이정준
IPC分类号： C08L101/12 , C08K5/41 , C08F20/10 , C08J5/18
CPC分类号： C08K5/42 , C08F20/10 , C08J5/18 , C08K3/04 , C08K3/08 , C08K2201/001 , C08L65/00 , C08L101/12
摘要： The purpose of the present invention is to form a hydrophobic group by removing a hydrophilic group of a conductive emulsifier having the hydrophilic group, and making the emulsifier react with an alcoholic polymer. Additionally, the present invention allows natural electrical characteristics of conductive emulsifiers or conductive materials while having excellent water resistance by inducing a chemical bond by copolymerization without a physical bond by a binder which is a nonconductor. Accordingly, the present invention provides a graft copolymer having electrical conductivity capable of being applied as a conductive material, a graft copolymer of an alcoholic polymer and a conductive emulsifier having properties that natural physical properties such as electrical conductivity and the like are not changed even when the graft copolymer is left for a long time in the atmosphere or is impregnated with a polar solvent, and a manufacturing method thereof.
摘要翻译：本发明的目的是通过除去具有亲水基团的导电乳化剂的亲水基团并使乳化剂与醇聚合物反应形成疏水基团。此外，本发明允许导电乳化剂或导电材料的自然电特性，同时通过通过共聚而引起化学键而具有优异的耐水性，而不通过作为非导体的粘合剂的物理粘合。因此，本发明提供具有能够作为导电性材料使用的导电性的接枝共聚物，具有使导电性等天然物理性能等导致的醇类聚合物和导电性乳化剂的接枝共聚物即使当接枝共聚物在大气中放置很长时间或用极性溶剂浸渍，及其制造方法。

4. 发明公开

KR1020140019970A 우수한 내수성, 내화학성, 및 내후성을 갖는 고분자 공중합체 및 이의 제조방법. 审中-实审
标题翻译：具有优异耐水性，耐化学性和耐候性的高分子量共聚物及其制造方法。
公开(公告)号：KR1020140019970A
公开(公告)日：2014-02-18
申请号：KR1020120086173
申请日：2012-08-07
申请人： 주식회사 한국엔티켐
发明人： 김중현 , 이선종 , 이승환 , 박홍관 , 김인영 , 조원석 , 유도혁 , 이정준
IPC分类号： C08F261/02 , C08F2/24 , C08F273/00 , C08J5/18
CPC分类号： C08F261/02 , C08F2/24 , C08J5/18
摘要： The purpose of the present invention is to remove the hydrophilic group of a conductive emulsifier having a hydrophilic group and form a hydrophobic group through reaction with another alcoholic polymer. The present invention is able to maintain intrinsic electrical properties of a conductive emulsifier or conductive material while having excellent water resistance by inducing chemical bonds due to copolymerization without physical bonds due to a binder which is a non-conductor. Accordingly, the present invention provides a graft copolymer having electrical conductivity capable of application as a conductive material by producing dehydrocondensation between the alcoholic polymer and conductive emulsifier, a graft copolymer between the alcoholic polymer and conductive emulsifier having properties that intrinsic physical properties such as conductivity are not changed when being dipped in a polar solvent or being neglected in atmosphere for a long time, and a manufacturing method thereof. [Reference numerals] (AA) Step of preparing a conductive emulsifier solution; (BB) Step of preparing alcoholic polymers; (CC) Step of preparing a mixed solution by mixing the conductive emulsifier solution and alcoholic polymers; (DD) Step of heat-treating the mixed solution
摘要翻译：本发明的目的是通过与另一种醇聚合物的反应来除去具有亲水基团的导电乳化剂的亲水基团并形成疏水基团。本发明能够通过由于作为非导体的粘合剂而由于由于共聚而没有物理键而引起化学键而具有优异的耐水性而保持导电乳化剂或导电材料的固有电性能。因此，本发明提供了具有导电性的接枝共聚物，其通过在醇类聚合物和导电性乳化剂之间进行脱氢缩合作为导电性材料，醇系聚合物与导电性乳化剂之间的接枝共聚物具有诸如导电性等固有物理性质当浸渍在极性溶剂中或在大气中长时间被忽略时，它们不会改变，及其制造方法。（AA）制备导电乳化剂溶液的步骤（AA）（BB）制备醇类聚合物的步骤; （CC）通过混合导电乳化剂溶液和醇类聚合物制备混合溶液的步骤; （DD）对混合溶液进行热处理的工序

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