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1. 发明公开

KR1020060003161A 비소 오염 토양의 복원방법 无效
标题翻译：一种污染土壤污染土壤的方法
公开(公告)号：KR1020060003161A
公开(公告)日：2006-01-10
申请号：KR1020040051962
申请日：2004-07-05
申请人： 주식회사 에코솔루션 , 이의상
发明人： 황종식 , 이상봉 , 유도윤 , 이의상 , 이승우 , 이인원
IPC分类号： B09C1/08
CPC分类号： B09C1/08 , A62D3/36
摘要： 본 발명은 비소로 오염된 토양의 복원방법에 관한 것으로서, (S1) 비소로 오염된 토양에 철 이온이 함유된 산성 용액을 투입하여 비소를 불용성의 비산철 형태로 고정화하는 단계; 및 (S2) CaO를 투입하여 상기 (S1) 단계로 처리된 토양의 pH를 중성으로 중화시키면서 비산철 형태로 고정화되지 않은 잔류 비소를 칼슘-비소 화합물의 형태로 고정화하는 단계를 포함한다. 본 발명에 따른 비소 오염 토양의 복원방법은 간단하고 경제적일 뿐만 아니라, 토양에 존재하는 비소를 효율적으로 불용화시켜 토양을 복원하므로서 비소에 의한 환경오염을 방지할 수 있다.
비소*오염*토양*염화철*생석회

2. 发明公开

KR1020060003168A 비소 및 납으로 오염된 토양의 복원방법 无效
标题翻译：污染土壤和铅污染土壤的方法
公开(公告)号：KR1020060003168A
公开(公告)日：2006-01-10
申请号：KR1020040051970
申请日：2004-07-05
申请人： 주식회사 에코솔루션 , 이의상
发明人： 황종식 , 이상봉 , 유도윤 , 이의상 , 이승우 , 이인원
IPC分类号： B09C1/08
CPC分类号： B09C1/08 , A62D3/36
摘要： 본 발명은 비소 및 납으로 오염된 토양의 복원방법에 관한 것으로서, (S1) 비소 및 납으로 오염된 토양에 철 이온이 함유된 산성 용액을 투입하는 단계; (S2) 인산염을 투입하여 상기 (S1) 단계에 의하여 고정화되지 않은 잔류 비소 및 납을 각각 불용성의 금속인산염인 납인산염 및 비소인산염으로 고정화하는 단계; 및 (S3) CaO를 투입하여 상기 (S2) 단계로 처리된 토양의 pH를 중성으로 중화시키는 단계를 포함한다. 본 발명에 따른 비소 및 납으로 오염된 토양의 복원방법은 간단하고 경제적일 뿐만 아니라, 환경에 거의 영향을 주지 않고 토양에 존재하는 비소와 납을 효율적으로 불용화시켜 토양을 복원할 수 있다.
비소*납*오염*토양*염화철*인산염*생석회

3. 发明公开

KR1020110019585A 바이오디젤을 함유한 연료유용 저온 유동성 향상제 조성물 및 이를 이용하여 제조한 저온 유동성 향상제 有权
标题翻译：具有生物柴油和燃料油的低温流动改性组合物使用其
公开(公告)号：KR1020110019585A
公开(公告)日：2011-02-28
申请号：KR1020090077186
申请日：2009-08-20
申请人： 한국화학연구원 , 주식회사이맥솔루션 , 주식회사 에코솔루션
发明人： 김영운 , 정근우 , 임대재 , 황종식
IPC分类号： C10L1/19 , C10L1/192 , C10L10/14 , C10G3/00
CPC分类号： Y02E50/13 , Y02P30/20 , C10L1/19 , C10G3/00 , C10L1/192 , C10L10/14 , C10L2200/0476
摘要： PURPOSE: A low temperature flow improver composition for a fuel containing biodiesel, and a low temperature flow improver using thereof are provided to improve the permeability of a filter. CONSTITUTION: A low temperature flow improver composition for a fuel containing biodiesel contains a monomer compound including the following: 10~95parts of vegetable oil originated ester monomer by weight obtained by reacting meth acrylic acid or acrylic acid, with vegetable oil originated fatty alcohol; and 5~90parts of monomer by weight selected from maleic anhydride, styrene, and an ester monomer marked with chemical formula 1.
摘要翻译：目的：提供用于含有生物柴油的燃料的低温流动改进剂组合物和使用其的低温流动改进剂以提高过滤器的渗透性。构成：含有生物柴油的燃料的低温流动性改进剂组合物含有以下单体化合物：10〜95份由甲基丙烯酸或丙烯酸与植物油起始的脂肪醇反应获得的植物油起始酯单体; 和5〜90份选自马来酸酐，苯乙烯和用化学式1标记的酯单体的单体。

4. 发明授权

KR100484594B1 기상 및 액상 유기화합물의 추출을 위한 다중상 추출장치 有权
标题翻译：用于萃取蒸气和液相有机化合物的多相萃取装置
公开(公告)号：KR100484594B1
公开(公告)日：2005-04-20
申请号：KR1020030055878
申请日：2003-08-12
申请人： 주식회사 에코솔루션 , 장윤영
发明人： 장윤영 , 황종식 , 이상봉 , 유도윤 , 이승우 , 이인원 , 김성원
IPC分类号： B09C1/02
摘要： 본 발명은 토양 및 지하수에 함유된 유기화합물을 추출하여 오염지역을 복원하는 다중상 추출장치에 관한 것으로서, 복원현장에 수직으로 매설되는 튜브형태의 추출정; 상기 추출정의 일측에 고정되고, 추출정의 중공을 따라 특정 깊이까지 그 단부가 연장된 고정관; 상기 추출정 내부에 유입되는 지하수의 수면에 떠 있도록 부력을 갖는 한편, 지하수의 수위변동시 상기 고정관을 따라 상하로 슬라이딩하도록 결합되는 제1플로팅부재; 일측이 상기 제1플로팅부재에 고정되는 한편, 그 일단이 상기 고정관의 단부에 연결되어 연통되고, 그 타단으로부터 지하수 수면의 나플이 유입되는 연질소재의 유동관; 및 상기 고정관과 연통되도록 설치되어 흡입력을 제공하는 펌핑수단;을 포함한다.

5. 发明授权

KR100462118B1 오염 토양 및 지하수 복원을 위한 이중정의 제작방법 및시공방법 有权
标题翻译： 오염토양및지하수복원을위한이중정의제작방법및시공방
公开(公告)号：KR100462118B1
公开(公告)日：2004-12-17
申请号：KR1020020085350
申请日：2002-12-27
申请人： 주식회사 에코솔루션
发明人： 황종식 , 이상봉 , 전기식 , 공준 , 신정엽 , 강우재 , 전진오 , 오경철 , 김희연 , 문소영
IPC分类号： B09C1/00
摘要： PURPOSE: A method for manufacturing double-structural well for remediation of contaminated soil and underground water by injecting air into unsaturated zone and extracting air from the unsaturated zone and injecting air into aquifer at the same time is provided, and a method for constructing the double-structural well is provided. CONSTITUTION: The method for constructing a double-structural well(10) for remediation of contaminated soil and underground water comprises a step (a) of drilling a hole having certain depth and diameter at a double-structural well installation position; a step (b) of inserting the double-structural well into the drilled hole; a step (c) of forming first filter bag section(50) by filling gravel in the drilled hole in such a manner that the gravel covers all screens(24) for aquifer; a step (d) of forming an aquifer casing section(60) by filling bentonite from an upper part of the first filter bag section to a lower part of screens(14) for unsaturated zone; a step (e) of forming second filter bag section(70) by filling gravel in an upper part of the aquifer casing section in such a way that the gravel covers all of the screens for unsaturated zone; a step (f) of forming an unsaturated zone casing section(80) having certain length by filling bentonite in an upper part of the second filter bag section; and a step (g) of filling a finishing material(90) obtained by mixing cement with bentonite from the unsaturated zone casing section to the ground surface.
摘要翻译：目的：提供一种用于通过将空气注入不饱和区并从非饱和区中抽取空气并同时向含水层中注入空气来修复污染土壤和地下水的双结构井的方法，以及一种用于构造双层结构井的方法，提供结构井。组成：用于修复污染土壤和地下水的双结构井（10）的方法包括步骤（a）：在双结构井安装位置钻一定深度和直径的孔; 将双重结构的井插入钻孔的步骤（b）通过在所述钻孔中填充砾石以使得所述砾石覆盖用于含水层的所有筛网（24）的方式形成第一过滤袋部（50）的步骤（c）; 通过将膨润土从所述第一过滤袋部分的上部填充到用于非饱和区域的筛网（14）的下部而形成含水层套管部分（60）的步骤（d）; 通过在所述含水层壳体部分的上部填充砾石而形成所述第二过滤袋部分（70）的步骤（e），使得所述砾石覆盖所有用于非饱和区域的筛网; 通过在第二过滤袋部分的上部填充膨润土而形成具有一定长度的不饱和区域壳体部分（80）的步骤（f）; 以及将通过将水泥与膨润土混合而得到的装饰材料（90）从所述不饱和区域壳体部分填充到地面的步骤（g）。

6. 发明公开

KR1020040058828A 오염 토양 및 지하수 복원을 위한 이중 구조의 복원 정 有权
标题翻译：补救污染土壤和地下水的双重结构
公开(公告)号：KR1020040058828A
公开(公告)日：2004-07-05
申请号：KR1020020085341
申请日：2002-12-27
申请人： 주식회사 에코솔루션
发明人： 황종식 , 이상봉 , 전기식 , 공준 , 신정엽 , 강우재 , 전진오 , 오경철 , 김희연 , 문소영
IPC分类号： B09C1/00
摘要： PURPOSE: A double-structural well for remediating contaminated soil and underground water by injecting air into unsaturated zone of underground and extracting air from the unsaturated zone and injecting air into aquifer of underground at the same time is provided. CONSTITUTION: The double-structural well(10) comprises an unsaturated zone extraction well(12) which has a certain length, and on a lower outer circumferential surface of which a plurality of screens are formed to extract air in unsaturated zone; an aquifer injection well(22) which is extended from a lower part of the unsaturated zone extraction well in such a manner that the aquifer injection well is blocked from the unsaturated zone extraction well, and on a lower outer circumferential surface of which a plurality of screens are formed to inject air into aquifer; and an air supply pipe(20) installed in the unsaturated zone extraction well and connected with the aquifer injection well to supply air into the aquifer injection well from the outside, wherein the unsaturated zone extraction well and the aquifer injection well are formed in a cylindrical pipe shape, the air supply pipe is positioned in the center of the unsaturated zone extraction well, and a blocking block is installed at a lower part of the unsaturated zone extraction well in such a way that the blocking block is contacted with the outer circumferential surface of the air supply pipe. The double-structural well(30) comprises an unsaturated zone injection well(32) which has a certain length, and on a lower outer circumferential surface of which a plurality of screens are formed to inject air into unsaturated zone; an aquifer injection wells(42) which is extended from a lower part of the unsaturated zone injection well in such a manner that the aquifer injection well is blocked from the unsaturated zone injection well, and on a lower outer circumferential surface of which a plurality of screens are formed to inject air into aquifer; and an air supply pipe(40) installed in the unsaturated zone injection well and connected with the aquifer injection well to supply air into the aquifer injection well from the outside.
摘要翻译：目的：通过将空气注入地下不饱和区域并从不饱和区域抽取空气并同时向地下水层注入空气，来补救污染土壤和地下水的双重结构井。构成：双结构井（10）包括具有一定长度的不饱和区提取井（12），并且在其下外周表面上形成有多个筛网以提取不饱和区域中的空气; 含水层注入井（22），其从所述不饱和区域提取井的下部延伸，使得所述含水层注入井从所述不饱和区域提取井被阻挡，并且在其下外周表面上具有多个形成筛网以将空气注入含水层中; 以及安装在不饱和区域提取井中并与含水层注入井连接以从外部向含水层注入井供应空气的供气管（20），其中不饱和区提取井和含水层注入井形成为圆柱形管状，空气供给管位于不饱和区提取井的中心，阻塞块安装在不饱和区提取井的下部，使阻挡块与外周面接触的供气管。双结构井（30）包括具有一定长度的不饱和区域注入井（32），并且在其下外圆周表面上形成有多个筛网以将空气注入到不饱和区域中; 含水层注入井（42），其从所述不饱和区域注入井的下部延伸，使得所述含水层注入井从所述不饱和区域注入井被阻挡，并且在其下外周表面上具有多个形成筛网以将空气注入含水层中; 以及安装在不饱和区注入井中并与含水层注入井连接以从外部向含水层注入井供应空气的供气管道（40）。

7. 发明公开

KR1020030070451A 토양 및 지하수의 복원을 위한 유기화합물 추출장치 有权
标题翻译：提取土壤和地下水有机化合物的设备
公开(公告)号：KR1020030070451A
公开(公告)日：2003-08-30
申请号：KR1020020009995
申请日：2002-02-25
申请人： 주식회사 에코솔루션
发明人： 장윤영 , 황종식 , 이상봉 , 유도윤 , 박정억 , 이승우 , 이인원 , 김성원
IPC分类号： E21B43/12
CPC分类号： B09C1/02 , B09C2101/00
摘要： PURPOSE: Provided is an apparatus for extracting organic compounds from soil and ground water for their remediation. CONSTITUTION: The apparatus comprises an extracting well(10) in tube form having a screen(10a) at a lower end which is located under the ground, an extracting pipe(11) received in the extracting well(10), a suction device(15) connected to the extracting pipe(11) for supplying extracting force, a vessel(13) coupled to the extracting pipe(11) in such a way to receive an inlet formed at a lower end of the extracting pipe(11) and provided with a weir(13a) along an upper end thereof, and a float member(12) for floating the vessel(13) on the surface of underwater permeated into the extracting pipe(11), wherein the extracting pipe(11) has elasticity so as for the vessel(13) to float on the underwater even water level of the underwater fluctuates.
摘要翻译：目的：提供从土壤和地下水中提取有机化合物进行修复的设备。构成：该装置包括管形式的提取井（10），其具有位于地下的下端的筛网（10a），容纳在提取井（10）中的抽出管（11），抽吸装置 15），其连接到用于提供抽取力的抽取管（11），与所述提取管（11）联接以容纳形成在所述提取管（11）的下端的入口的容器（13），并且提供沿着其上端具有堰（13a）和浮子（12），用于将渗透到提取管（11）中的水下的表面上的容器（13）漂浮，其中提取管（11）具有弹性至于船只（13）浮在水下的水下甚至水下波动。

8. 发明公开

KR1020020037136A 미생물 활성제 투입 콘트롤러를 채용한 오폐수 처리시스템 및 방법 失效
标题翻译：废水处理系统采用控制器介绍生物活化剂及其操作方法
公开(公告)号：KR1020020037136A
公开(公告)日：2002-05-18
申请号：KR1020000067142
申请日：2000-11-13
申请人： 주식회사 에코솔루션
发明人： 손명기 , 이경희 , 전기식 , 이상봉 , 황종식
IPC分类号： C02F3/00
摘要： PURPOSE: A wastewater treatment system adopting a controller introducing biological activator is provided to control the amount of the biological activator. CONSTITUTION: The system comprises a storage tank(100) which stores and supplies biological activator; a biological disposal tank(40) which degrades and disposes the inflow water by biological degradable reaction; a sensor(11) which measures BOD, COD of the inflow water; a pipeline(82) which supplies water; a mixing tank(80) which supplies the biological activator to the biological disposal tank after dilution with tap water; a valve(81) which is installed on the pipeline to control flowrate of the water; a valve(101) which controls dosage of the biological activator; a controller(90) which controls mixing rate of water and biological activator by controlling opening and shutting of the valves.
摘要翻译：目的：提供采用控制器引入生物活化剂的废水处理系统，以控制生物活化剂的用量。构成：该系统包括储存和供应生物活化剂的储罐（100）; 通过生物降解反应降解和处置流入水的生物处理罐（40）; 传感器（11），其测量流入水的BOD，COD; 供水的管道（82）混合罐（80），其在用自来水稀释后将生物活化剂供应到生物处理罐; 安装在管道上以控制水的流量的阀门（81）; 控制生物活化剂的剂量的阀门（101）控制器（90），其通过控制阀的打开和关闭来控制水和生物活化剂的混合速率。

9. 发明公开

KR1020070068292A 초임계 알코올 및 용매를 이용한 바이오디젤의 제조방법 有权
标题翻译：使用超临界醇和溶剂制备生物体的方法
公开(公告)号：KR1020070068292A
公开(公告)日：2007-06-29
申请号：KR1020060133916
申请日：2006-12-26
申请人： 주식회사 에코솔루션
发明人： 황종식 , 유기풍
IPC分类号： C10L1/02 , C10L1/182 , C10G3/00 , C11C3/00
CPC分类号： C11C3/003 , C10L1/026 , Y02E50/13 , Y02P30/20 , C10G3/00 , C10L1/182 , C10L2290/12 , C10L2290/24 , Y02P20/544
摘要： A method for preparing fatty acid alkyl ester(biodiesel) by esterifying a vegetable oil in the presence of a supercritical lower alcohol and a supercritical solvent with a boiling point similar to that of the lower alcohol is provided. A method for preparing fatty acid alkyl ester(biodiesel) comprises the steps of: (a) esterifying a vegetable oil in the presence of a supercritical lower alcohol and a supercritical solvent with a boiling point similar to that of the lower alcohol; (b) recovering fatty acid alkyl ester(biodiesel) from the esterified reaction solution. The supercritical solvent with a boiling point similar to that of the lower alcohol is selected from the group consisting of CFC-based solvents, HCFC-based solvents and HFC-based solvents. The lower alcohol is methanol. The vegetable oil is selected from the group consisting of palm oil, soybean oil, rape-seed oil, canola oil, safflower oil, corn oil, colza oil, linseed oil, sunflower oil, poppy oil, walnut oil, peanut oil, cottonseed oil, rice bran oil, camellia seed oil, castor oil, and olive oil. The step(a) is performed in a reactor with an agitation means. The step(a) is performed in a fluidized-bed reactor. The step(a) is performed by esterifying the vegetable oil and the lower alcohol at a mole ratio of 1:5 to 1:20. The method further comprises the step of recovering the lower alcohol and solvent to recirculate the recovered lower alcohol and solvent to the esterification process after performing the step(b).
摘要翻译：提供了在超临界低级醇和具有与低级醇类似的沸点的超临界溶剂的存在下酯化植物油来制备脂肪酸烷基酯（生物柴油）的方法。制备脂肪酸烷基酯（生物柴油）的方法包括以下步骤：（a）在沸点相当于低级醇的超临界低级醇和超临界溶剂的存在下酯化植物油; （b）从酯化反应溶液中回收脂肪酸烷基酯（生物柴油）。沸点相似于低级醇的超临界溶剂选自CFC类溶剂，HCFC类溶剂和HFC类溶剂。低级醇是甲醇。植物油选自棕榈油，大豆油，油菜籽油，卡诺拉油，红花油，玉米油，菜籽油，亚麻子油，向日葵油，罂粟油，胡桃油，花生油，棉籽油米糠油，山茶籽油，蓖麻油和橄榄油。步骤（a）在具有搅拌装置的反应器中进行。步骤（a）在流化床反应器中进行。步骤（a）通过以1:5至1:20的摩尔比酯化植物油和低级醇来进行。该方法还包括在执行步骤（b）之后回收低级醇和溶剂以将回收的低级醇和溶剂再循环到酯化过程的步骤。

10. 发明授权

KR100382210B1 미생물 활성제 투입 콘트롤러를 채용한 오폐수 처리시스템 및 방법 失效
标题翻译： 미생물활성제투입콘트롤러를채용한오폐수처리시스템및방
公开(公告)号：KR100382210B1
公开(公告)日：2003-05-01
申请号：KR1020000067142
申请日：2000-11-13
申请人： 주식회사 에코솔루션
发明人： 손명기 , 이경희 , 전기식 , 이상봉 , 황종식
IPC分类号： C02F3/00
摘要： PURPOSE: A wastewater treatment system adopting a controller introducing biological activator is provided to control the amount of the biological activator. CONSTITUTION: The system comprises a storage tank(100) which stores and supplies biological activator; a biological disposal tank(40) which degrades and disposes the inflow water by biological degradable reaction; a sensor(11) which measures BOD, COD of the inflow water; a pipeline(82) which supplies water; a mixing tank(80) which supplies the biological activator to the biological disposal tank after dilution with tap water; a valve(81) which is installed on the pipeline to control flowrate of the water; a valve(101) which controls dosage of the biological activator; a controller(90) which controls mixing rate of water and biological activator by controlling opening and shutting of the valves.
摘要翻译：目的：提供采用引入生物活化剂的控制器的废水处理系统以控制生物活化剂的量。组成：该系统包括储存和供应生物活化剂的储罐（100）; 生物处置槽（40），其通过生物可降解反应降解和处理流入水; 测量流入水的BOD，COD的传感器（11）供应水的管线（82）混合槽（80），其在用自来水稀释后将生物活性剂供应到生物处理槽; 一个安装在管道上的阀门（81），用于控制水的流量; 控制生物活化剂的剂量的阀（101）控制器（90），其通过控制阀的打开和关闭来控制水和生物活化剂的混合速率。

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