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1. 发明授权

KR100398083B1 고선택성 제초제 페녹시프로피온산 알콕시카보닐 아니리드 화합물 有权
标题翻译： 고선택성제초제페녹시프로피온산알콕시카보닐아니리드화
公开(公告)号：KR100398083B1
公开(公告)日：2003-09-19
申请号：KR1020000044837
申请日：2000-08-02
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김태준
IPC分类号： A01N43/76
CPC分类号： C07D263/58 , A01N43/76 , C07C233/54 , C07C235/24
摘要： The present invention relates to high selective herbicidal phenoxypropionic acid alkoxycarbonyl anilid compounds represented in formula 1, method of preparing thereof, their use to control barnyard grass produced from rice, and a composition as suitable herbicides,whereinR is a hydrogen atom, methyl or ethyl group;R1 is a hydrogen atom, C1-C6 alkyl, C1-C6 alkyl substituted with 1 to 3 of the group consisting of hydroxy, carboxyl, and a halogen atom, C3-C6 cycloalkyl, C3-C4 alkenyl, C3-C4 alkinyl, or C2-C4 alkoxyalkyl group;n is an integer of 1 or 2 and when n is 2, R1 can be a combination of other substituents.
摘要翻译：本发明涉及式1所示的高选择性除草苯氧丙酸烷氧羰基苯胺类化合物，其制备方法，其用于控制由水稻产生的稗草以及作为合适的除草剂的组合物，其中R为氢原子，甲基或乙基 ; R 1为氢原子，C 1 -C 6烷基，被1至3个由羟基，羧基和卤原子组成的组中取代的C 1 -C 6烷基，C 3 -C 6环烷基，C 3 -C 4烯基，C 3 -C 4炔基，或C 2 -C 4烷氧基烷基; n是1或2的整数，并且当n是2时，R 1可以是其他取代基的组合。

2. 发明公开

KR1020000011943A 제초성 페녹시프로피온산 Ｎ-알킬-Ｎ-2-플루오로페닐 아미드화합물 有权
标题翻译：除草酚羟基丙酸N-烷基-N-2-氟代丙烯酰胺化合物
公开(公告)号：KR1020000011943A
公开(公告)日：2000-02-25
申请号：KR1019990030067
申请日：1999-07-23
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김진석
IPC分类号： A01N43/76
CPC分类号： C07D263/58 , A01N43/76 , C07C235/16 , C07C309/66 , C07C309/73
摘要： PURPOSE: New phenoxpropionic acid N-alkyl-N-2-fluorophenyl amide compound having an excellent weeding activity and a herbicide composition containing the same are provided. CONSTITUTION: The compound is represented by the formula I, wherein R is methyl or ethyl; X is hydrogen atom, halogen atom, cyano, C1-C6 alkyl, C1-C6 alkoxy, C1-C3 haloalkyl substituted 1 to 3 halogen atoms, C1-C3 haloalkoxy substituted 1 to 3 halogen atoms, C2-C4 alkoxyalkoxy, phenoxy, benzyloxy, C2-C6 alkenyl, C2-C6 alkynyl, C2-C6 alkenyloxy, C2-C6 alkynyloxy or phenyl; Y is hydrogen or fludoro; and n is an integer of 1 or 2, with a proviso n is 2, X may be combined each other different substituent respectively. The compound may be used as hebicide by preparing with carrier, aid, surfacant and other herbiside which are used in agriculture filed.
摘要翻译：目的：提供具有优异除草活性的新的苯氧基丙酸N-烷基-N-2-氟苯基酰胺化合物和含有它们的除草剂组合物。构成：该化合物由式I表示，其中R是甲基或乙基; X是氢原子，卤原子，氰基，C1-C6烷基，C1-C6烷氧基，C1-C3卤代烷基取代的1〜3个卤素原子，C1-C3卤代烷氧基取代的1〜3个卤素原子，C2-C4烷氧基烷氧基，苯氧基，苄氧基，C 2 -C 6烯基，C 2 -C 6炔基，C 2 -C 6烯氧基，C 2 -C 6炔氧基或苯基; Y是氢或氟; n为1或2的整数，条件是n为2，X可分别相互组合。该化合物可以通过制备用于农业领域的载体，助剂，表面活性剂和其他草药来用作除莠剂。

3. 发明授权

KR100419853B1 제초활성을 가지는 광활성 (Ｒ)-페녹시프로피온산-Ｎ-메틸-Ｎ-2-플루오로페닐아미드 화합물 有权
标题翻译：具有除草活性的光敏（R） - 苯氧基丙酸-N-甲基-N-2-氟苯基酰胺化合物
公开(公告)号：KR100419853B1
公开(公告)日：2004-02-25
申请号：KR1020000024047
申请日：2000-05-04
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김진석 , 정봉진 , 권오연
IPC分类号： A01N37/18
摘要： 본 발명은 다음 화학식 1로 표시되는 광활성 (R)-페녹시프로피온산-Ｎ-메틸-Ｎ-2-플루오로페닐아미드 화합물과 그의 제조방법, 벼농사에서 발생하는 피를 방제하는 용도, 이들 화합물을 포함하는 제초제 조성물에 관한 것이다.

상기 화학식 1에서 : X, Y 및 n은 각각 발명의 상세한 설명란에서 정의한 바와 같다.

4. 发明公开

KR1020010105445A 제초활성을 가지는 광활성 (Ｒ)-페녹시프로피온산-Ｎ-메틸-Ｎ-2-플루오로페닐아미드 화합물 有权
标题翻译：具有除草活性的（R） - 苯氧基丙酸-N-甲基-N-2-氟代甲酰胺化合物
公开(公告)号：KR1020010105445A
公开(公告)日：2001-11-29
申请号：KR1020000024047
申请日：2000-05-04
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김진석 , 정봉진 , 권오연
IPC分类号： A01N37/18
CPC分类号： A01N43/76 , C07D263/58
摘要： 본 발명은 다음 화학식 1로 표시되는 광활성 (R)-페녹시프로피온산-Ｎ-알킬-Ｎ-2-플루오로페닐아미드 화합물과 그의 제조방법, 벼농사에서 발생하는 피를 방제하는 용도, 이들 화합물을 포함하는 제초제 조성물에 관한 것이다.

상기 화학식 1에서 : X, Y 및 n은 각각 발명의 상세한 설명란에서 정의한 바와 같다.

5. 发明授权

KR100750288B1 제초활성을 가지는테트라하이드로티아디아졸로피리다지논계 화합물 失效
标题翻译： 제초활성을가지는테트라하이드로티아디아졸로피리다지논계화
公开(公告)号：KR100750288B1
公开(公告)日：2007-08-20
申请号：KR1020060030662
申请日：2006-04-04
申请人： 한국화학연구원 , 주식회사 디비하이텍
发明人： 김대황 , 고영관 , 정근회 , 류재욱 , 우재춘 , 구동완 , 최정섭 , 정봉진 , 김태준 , 권오연
IPC分类号： A01N43/82 , A01P13/00
摘要： Tetrahydro thiadiazolo pyridazinone derivatives having herbicidal activity are provided to control gramineous weeds and broad-leaved weeds without harmful effects on useful crops such as corn and wheat, so that the compounds are useful as nonselective herbicide used in an orchard. The Tetrahydro thiadiazolo pyridazinone derivatives represented by the formula(1) are provided, wherein X is halogen atom or cyano group; Y is oxygen or sulfur; R is hydrogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C2-C6 alkoxyalkyl group, C1-C6 hydroxyalkyl group, C2-C6 alkenyl group or C2-C6 alkynyl group; R1 is C1-C6 alkyl group, C1-C6 haloalkyl group, C2-C6 alkenyl group, C2-C6 alkynyl group, phenyl group or benzyl group; and the benzene ring of the phenyl group or benzyl group is optionally substituted by hydrogen atom, C1-C6 alkyl group, C1-C6 alkoxy group, C1-C6 haloalkyl group, C2-C4 alkenyl group or C2-C4 alkynyl group.
摘要翻译：提供具有除草活性的四氢噻二唑并哒嗪酮衍生物以控制禾本科杂草和阔叶杂草，而对有用作物如玉米和小麦没有有害作用，从而使得该化合物可用作果园中使用的非选择性除草剂。提供由式（1）表示的四氢噻二唑并哒嗪酮衍生物，其中X是卤素原子或氰基; Y是氧或硫; R为氢原子，C1-C6烷基，C1-C6卤代烷基，C2-C6烷氧基烷基，C1-C6羟烷基，C2-C6烯基或C2-C6炔基; R 1为C 1 -C 6烷基，C 1 -C 6卤代烷基，C 2 -C 6烯基，C 2 -C 6炔基，苯基或苄基; 并且苯基或苄基的苯环任选被氢原子，C1-C6烷基，C1-C6烷氧基，C1-C6卤代烷基，C2-C4链烯基或C2-C4炔基取代。

6. 发明授权

KR100685473B1 제초활성을 가지는 하이단토인계 화합물 失效
标题翻译： 제초활성을가지는하이단토인계화합물
公开(公告)号：KR100685473B1
公开(公告)日：2007-02-26
申请号：KR1020050118376
申请日：2005-12-06
申请人： 한국화학연구원 , 주식회사 디비하이텍
发明人： 김대황 , 고영관 , 정근회 , 류재욱 , 우재춘 , 구동완 , 최정섭 , 정봉진 , 김태준 , 권오연
IPC分类号： A01N43/60 , A01P13/00
摘要： Hydantoin-based derivatives having herbicidal activity are provided to selectively control weeds without harmful effects to useful crops such as corn, and prevent environmental pollution by reducing the use amount of herbicides. The hydantoin-based derivatives having herbicidal activity, represented by the formula(1) are provided, wherein n is an integer from 0 to 3; R1 is hydrogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C2-C6 alkoxyalkyl group, C1-C6 hydroxyalkyl group, C2-C6 alkenyl group or C2-C6 alkynyl group; R2 is hydrogen atom, C1-C6 alkyl group, C1-C6 haloalkyl group, C2-C6 alkenyl group or C2-C6 alkynyl group; and X is hydrogen atom, halogen atom, cyano group, hydroxyl group, C1-C4 alkyl group, C1-C4 alkoxy group, C2-C4 alkenyl group, C2-C4 alkynyl group, C2-C4 alkoxyalkyl group or C1-C4 hydroxyalkyl group. The hydantoin-based derivatives having herbicidal activity, represented by the formula(1) are prepared by halogenization of hydantoin carboxylic acid represented by the formula(2) to prepare compounds represented by the formula(4), and reacting the compounds represented by the formula(4) with compounds represented by the formula(3). A herbicidal composition comprises the hydantoin-based derivatives having herbicidal activity, represented by the formula(1).
摘要翻译：提供具有除草活性的乙内酰脲类衍生物以选择性地控制杂草，而不会对有用作物例如玉米产生有害影响，并且通过减少除草剂的使用量来防止环境污染。提供了由式（1）表示的具有除草活性的乙内酰脲类衍生物，其中n是0-3的整数; R1为氢原子，C1-C6烷基，C1-C6卤代烷基，C2-C6烷氧基烷基，C1-C6羟烷基，C2-C6烯基或C2-C6炔基; R 2为氢原子，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 2 -C 6烯基或C 2 -C 6炔基; X为氢原子，卤原子，氰基，羟基，C1-C4烷基，C1-C4烷氧基，C2-C4烯基，C2-C4炔基，C2-C4烷氧基烷基或C1-C4羟烷基。由式（1）表示的具有除草活性的乙内酰脲类衍生物是通过将式（2）表示的乙内酰脲羧酸卤化以制备式（4）表示的化合物，然后使式（4）所示的化合物与式（3）所示的化合物反应。除草组合物包含由式（1）表示的具有除草活性的乙内酰脲衍生物。

7. 发明公开

KR1020090048750A 테트라하이드로인다졸계 화합물 및 이를 포함하는 제초제 无效
标题翻译：四氢衍生物衍生物和包含衍生物的除草剂
公开(公告)号：KR1020090048750A
公开(公告)日：2009-05-15
申请号：KR1020070114770
申请日：2007-11-12
申请人： 주식회사 디비하이텍 , 한국화학연구원
发明人： 고영관 , 정근회 , 류재욱 , 우재춘 , 구동완 , 김대황 , 최정섭 , 정봉진 , 김태준 , 최인영 , 석미영 , 최준혁 , 문기준
IPC分类号： C07D231/54 , A01N43/56
摘要： 테트라하이드로인다졸계 화합물 및 이를 포함하는 제초제가 제공된다.
상기 화합물은 과수원 등의 비선택성 제초제로서뿐만 아니라 옥수수, 밀 또는 벼와 같은 유용한 작물에는 약해를 주지 않으면서 화본과 및 광엽잡초를 잘 방제할 수 있다.

8. 发明授权

KR100314776B1 제초성 페녹시프로피온산 Ｎ-알킬-Ｎ-2-플루오로페닐 아미드화합물 有权
标题翻译： --- 2-除草苯氧基丙酸N-烷基-N-2-氟苯基酰胺
公开(公告)号：KR100314776B1
公开(公告)日：2001-11-17
申请号：KR1019990030067
申请日：1999-07-23
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김진석
IPC分类号： A01N43/76
CPC分类号： C07D263/58 , A01N43/76 , C07C235/16 , C07C309/66 , C07C309/73
摘要： 본발명은다음화학식 1로표시되는페녹시프로피온산 N-알킬-N-2-플루오로페닐아미드화합물과그의제조방법, 벼농사에서발생하는피를방제하는용도, 이들화합물을포함하는제초제조성물에관한것이다. 상기화학식 1에서 : R은메틸기, 또는에틸기를나타내고; X는수소원자, 할로겐원자, 시아노기, C∼C의알킬기, C∼C의알콕시기, 1∼3개의할로겐원자가치환된 C∼C의할로알킬기, 1∼3개의할로겐원자가치환된 C∼C의할로알콕시기, C∼C의알콕시알콕시기, 페녹시기, 벤질옥시기, C∼C의알케닐기, C∼C의알키닐기, C∼C의알케닐옥시기, C∼C의알키닐옥시기, 또는페닐기를나타내고; Y는수소원자, 또는플루오로(F)를나타내고; n은 1, 또는 2의정수를나타내며, n이 2일경우 X는각기다른치환체들의조합이되어도좋다.

9. 发明公开

KR1020010049975A 고선택성 제초제 페녹시프로피온산 알콕시카보닐 아니리드 화합물 有权
标题翻译：高选择性除草酚羟基丙酸烷氧基羰基化合物
公开(公告)号：KR1020010049975A
公开(公告)日：2001-06-15
申请号：KR1020000044837
申请日：2000-08-02
申请人： 주식회사 디비하이텍
发明人： 김대황 , 장해성 , 고영관 , 류재욱 , 우재춘 , 구동완 , 김태준
IPC分类号： A01N43/76
CPC分类号： C07D263/58 , A01N43/76 , C07C233/54 , C07C235/24
摘要： PURPOSE: A phenoxypropionic acid alkoxycarbonyl anilid compound, a process for producing the same, their use as a weed-killer against Deccan grass and a herbicidal composition containing the same are provided. Therefore, the composition is a suitable herbicide in the selective kill and control of grassy weeds in the presence of corn plants. CONSTITUTION: This compound of formula 1 is prepared by reaction of a compound of formula 7 and a compound of formula 8. In formula, R is H, methyl or ethyl; R1 is H, C1-6 alkyl, C1-6 alkyl substituted with 1 to 3 substituents selected from hydroxy, carboxy and halogen, C3-6 cycloalkyl, C3-4 alkenyl, C3-4 alkinyl or C2-4 alkoxyalkyl; n is an integer of 1 or 2 in which R1 may be combined with another substituent in case n is 2. The composition exhibits excellent herbicidal effect against barnyard grass, harmless to crops and safe to environment.
摘要翻译：目的：提供苯氧基丙酸烷氧基羰基苯胺化合物，其制备方法，它们作为除草剂的除草剂的用途和含有它们的除草组合物。因此，该组合物是在玉米植物存在下选择性杀死和控制草地杂草的合适的除草剂。构成：式1化合物通过式7化合物与式8化合物的反应制备。在式中，R为H，甲基或乙基; R1是H，C1-6烷基，被1-3个选自羟基，羧基和卤素的取代基取代的C1-6烷基，C3-6环烷基，C3-4烯基，C3-4炔基或C2-4烷氧基烷基; n为1或2的整数，其中在n为2的情况下，R1可与另一取代基组合。该组合物对稗草具有优异的除草效果，对作物无害，对环境安全。

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