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1. 发明公开

KR1020050092716A 질소 함유 경화 부위를 갖는 플루오로플라스틱 중합체 有权
标题翻译：具有含氮固化场的氟聚合物
公开(公告)号：KR1020050092716A
公开(公告)日：2005-09-22
申请号：KR1020057011221
申请日：2003-12-01
申请人： 쓰리엠 이노베이티브 프로퍼티즈 캄파니
发明人： 그루타트워너엠.에이. , 힌처클라우스 , 콜브로버트이. , 지플리스틸만
IPC分类号： C08F214/18 , C08F259/08
CPC分类号： C08F214/182 , C08F214/265 , C08F259/08
摘要： Provided is a fluoroplastic or latex comprising a nitrogen-containing cure site and units derived from a fluorinated monomer. Also provided is a curable blend comprising a fluoroplastic and a fluoroleastomer gum, wherein said fluoroplastic comprises a nitrogen-containing cure site and units derived from a fluorinated monomer. Also provided are cured, shaped articles, latex blends, and a process for preparing a fluoroplastic comprising: (a) introducing at least 60 weight percent of a first polymerizable composition comprising a fluorinated monomer into a polymerization reactor; (b) polymerizing said composition in said reactor; (c) introducing at least 70 weight percent of a second polymerizable composition comprising a nitrogen-containing cure site monomer into said reactor following addition of at least 80% by weight of said first polymerizable composition; and (d) copolymerizing said nitrogen- containing cure site monomer with said fluorinated monomer to form a fluoroplastic.
摘要翻译：本发明提供含有含氮固化部位的氟塑料或胶乳和衍生自氟化单体的单元。还提供了包含氟塑料和氟橡胶胶的可固化共混物，其中所述氟塑料包含含氮固化部位和衍生自氟化单体的单元。还提供了固化，成型制品，胶乳混合物和制备氟塑料的方法，包括：（a）将至少60重量％的包含氟化单体的第一可聚合组合物引入聚合反应器中; （b）在所述反应器中聚合所述组合物; （c）在加入至少80重量％的所述第一可聚合组合物之后，将至少70重量％的包含含氮固化部位单体的可聚合组合物引入所述反应器中; 和（d）使所述含氮固化位点单体与所述氟化单体共聚以形成氟塑料。

2. 发明授权

KR101098752B1 질소 함유 경화 부위를 갖는 플루오로플라스틱 중합체 有权
标题翻译：具有含氮固化场的氟聚合物
公开(公告)号：KR101098752B1
公开(公告)日：2011-12-23
申请号：KR1020057011221
申请日：2003-12-01
申请人： 쓰리엠 이노베이티브 프로퍼티즈 캄파니
发明人： 그루타트워너엠.에이. , 힌처클라우스 , 콜브로버트이. , 지플리스틸만
IPC分类号： C08F214/18 , C08F259/08
CPC分类号： C08F214/182 , C08F214/265 , C08F259/08
摘要： 본발명은질소함유경화부위및 플루오르화단량체로부터유래되는단위체를포함하는라텍스또는플루오로플라스틱을제공한다. 또한본 발명은플루오로플라스틱및 플루오로엘라스토머고무를포함하는경화성블렌드를제공하는데, 상기플루오로플라스틱은질소함유경화부위및 플루오르화단량체로부터유래되는단위체를포함한다. 또한본 발명은경화된성형물품, 라텍스블렌드, 및 (a) 플루오르화단량체를포함하는 60 중량% 이상의제1 중합성조성물을중합반응기내로도입하는단계; (b) 상기반응기에서상기조성물을중합하는단계; (c) 질소함유경화부위단량체를포함하는 70 중량% 이상의제2 중합성조성물을상기반응기내로도입한후 80 중량% 이상의상기제1 중합성조성물을첨가하는단계; 및 (d) 상기질소함유경화부위단량체를상기플루오르화단량체와공중합시켜플루오로플라스틱을형성하는단계를포함하는플루오로플라스틱의제조방법을제공한다.

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