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    • 2. 发明公开
    • 관능화된 나노입자
    • 功能性纳米粒子
    • KR1020080027791A
    • 2008-03-28
    • KR1020077030372
    • 2006-05-17
    • 시바 홀딩 인크
    • 뮐러마르틴뮈흘레바흐안드레아스기젠베르크토마스보에디디에루흐토마스림프랑소와파일러레온하르트렌츠로만미쇼로랑
    • C08K3/34C09C3/12C08K5/00
    • C09B69/103C09B67/0097C09B68/20C09B68/443C09B69/10
    • The present invention discloses functionalized nanoparticles comprising on the surface a covalently bound radical of formula (1), wherein the nanoparticles are SiO2, Al2O3 or mixed SiO2 and Al2O3 nanoparticles, R1 and R2 are independently of each other hydrogen, nanoparticle surface-O-, or a substituent, n is 1, 2, 3, 4, 5, 6, 7 or 8, and Y is a radical of formula-B1-D1 (2a), wherein B1 is the direct bond or a bridge member, and D1 is a radical of a cationic dye, a radical of a phthalocyanine dye which carries no water-solubilizing group, or a radical of a fluorescent dye selected from the group consisting of coumarins, benzocoumarins, xanthenes, benzo[a]xanthenes, benzo[b]xanthenes, benzo[c]xanthenes, phenoxazines, benzo[a]phenoxazines, benzo[b]phenoxazines, benzo[c] phenoxazines, napthalimides, naphtholactams, azlactones, methines, oxazines, thiazines, diketopyrrolopyrroles, quinacridones, benzoxanthenes, thio-epindolines, lactamimides, diphenylmaleimides, acetoacetamides, imidazothiazines, benzanthrones, phthalimides, benzotriazoles, pyrimidines, pyrazines and triazines, or Y is a radical of formula-B 2 D2 (2b), wherein B2 is an organic radical comprising at least one group having a negative charge, and D2 is a cationic dye selected from the group consisting of monoazo, disazo, polyazo, methine, azamethine, diphenylmethane, triphenylmethane, triaminotriaryl methane, azine, oxazine, cyanine and anthraquinone dyes. ® KIPO & WIPO 2008
    • 本发明公开了在表面上包含式(1)的共价结合基团的官能化纳米颗粒,其中纳米颗粒是SiO 2,Al 2 O 3或混合的SiO 2和Al 2 O 3纳米颗粒,R 1和R 2彼此独立地是氢,纳米颗粒表面-O-, 或取代基,n为1,2,3,4,5,6,7或8,并且Y为式B1-D1(2a)的基团,其中B1为直接键或桥式构件,D1为 是阳离子染料的自由基,不含水溶性基团的酞菁染料的基团,或选自香豆素,苯并香豆素,呫吨,苯并[a]呫吨,苯并[b 苯并[c]呫吨酮,苯并[c]呫吨酮,吩恶嗪,苯并[a]吩恶嗪,苯并[b]吩恶嗪,苯并[c]吩恶嗪,萘二酰亚胺,萘内酰胺,吖内酯,次甲基,恶嗪,噻嗪,二酮吡咯并吡咯,喹吖啶酮,苯并恶庚烯,硫代 - ,内酰胺,二苯基马来酰亚胺,乙酰乙酰胺,咪唑硫基 吖嗪,苯并呋喃,邻苯二甲酰亚胺,苯并三唑,嘧啶,吡嗪和三嗪,或Y是式-B2D2(2b)的基团,其中B2是包含至少一个具有负电荷的基团的有机基团,D2是阳离子 选自单偶氮,二偶氮,多偶氮,次甲基,氮杂酮,二苯基甲烷,三苯甲烷,三氨基三芳基甲烷,吖嗪,恶嗪,花青和蒽醌染料的染料。 ®KIPO&WIPO 2008