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1. 发明授权

KR101460821B1 황 시멘트 생산물의 성형을 위한 주형 및 공정 有权
标题翻译：形成硫酸钙产品的模具和工艺
公开(公告)号：KR101460821B1
公开(公告)日：2014-12-02
申请号：KR1020097017007
申请日：2008-01-15
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 비보가리요제프알마 , 부어요헴오케 , 글라루끄 , 마우어마르그레트 , 반레스룩 , 베르비스트기로데마그다마리아
IPC分类号： B28B1/54 , B28B7/34 , C04B28/36
CPC分类号： B28B7/348 , B28B1/54 , C04B28/36 , C04B40/02
摘要： 본발명은황 시멘트생산물을성형하기위한주형을제공하고, 이주형은주물재료를수용하기위한내측용적을규정하는내측표면, 외측표면, 및내측표면과외측표면사이에포함되어있는경계벽을구비하고, 이경계벽은내측표면에직교하는방향으로최대 100 W/㎡K 의단위면적당열컨덕턴스를갖는다. 본발명은추가로황 시멘트생산물을성형하기위한공정을제공한다.

2. 发明公开

KR1020100038326A 황 시멘트 예비-조성물 및 그러한 황 시멘트 예비-조성물의 제조 방법 有权
标题翻译：硫磺水泥前体组合物和制备这种硫酸钙组合物的方法
公开(公告)号：KR1020100038326A
公开(公告)日：2010-04-14
申请号：KR1020097027493
申请日：2008-06-04
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 부르요헴오케 , 하멜린크코르넬리스 , 베르비스트기로데마그다마리아
IPC分类号： C04B14/06 , C04B24/16 , C04B24/42 , C04B28/36
CPC分类号： C04B28/365 , C04B2111/0075 , C04B24/42 , C04B40/0085
摘要： The present invention provides a sulphur cement pre-composition, comprising sulphur and at least a polysulphide-containing organosilane in an amount of at least 0.3 wt% based on the weight of the total composition, which polysulphide-containing organosilane is of the general molecular formula: (XSi)H(2n+1-m)C-S-CH(2n'+1-m') (3)m' (1) wherein a is an integer in the range of from 2 to 8, X and X' each are, independently, a hydrolysable group, n and n' each are, independently, an integer in the range of from 1 to 4, and m and m' each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such sulphur cement pre-composition, a process for the preparation of sulphur cement or sulphur cement-aggregate composite, a sulphur cement or a sulphur cement-aggregate composite and the use of such sulphur cement pre-composition.
摘要翻译：本发明提供一种硫磺水泥预组合物，其包含硫和至少含多硫化物的有机硅烷，其含量为总组合物重量的至少0.3重量％，该多硫化物的有机硅烷具有通式：（XSi）H（2n + 1-m）CS-CH（2n'+ 1-m'）（3）m'（1）其中a是2至8的整数，X和X' 各自独立地为可水解基团，n和n'各自独立地为1〜4的整数，m和m'各自独立地为1〜（2n）的整数， +1）。本发明还提供了一种制备这种硫磺水泥前体组合物的方法，一种制备硫磺水泥或硫磺水泥骨料复合材料的方法，硫磺水泥或硫磺水泥骨料复合材料，以及使用这种硫磺水泥预组合物。

3. 发明授权

KR101346041B1 황 시멘트 또는 황 시멘트-응집물 복합체의 제조방법 有权
标题翻译：制备硫酸钙或硫酸钙复合材料的方法
公开(公告)号：KR101346041B1
公开(公告)日：2013-12-31
申请号：KR1020087016363
申请日：2006-12-07
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 베르비스트기로데마그다마리아 , 판트리르로브알로이지우스마리아
IPC分类号： C04B28/36 , C01B17/04
CPC分类号： C04B28/365 , C04B12/00 , C04B28/36 , C04B14/06 , C04B24/42
摘要： 본 발명은 하기 단계를 포함하는 황 시멘트 또는 황 시멘트-응집물 복합체의 제조방법을 제공한다: (a) 적어도 무기 충전제 및/또는 응집물과 2개 이상의 유기실릴기를 갖는 폴리술피드-함유 유기실란을 혼합하고, 유기실란이 무기 충전제 및/또는 응집물과 반응하도록 하는 단계; (b) 단계 (a) 동안 또는 단계 (a) 이후에, 황이 액체인 온도에서 황 원소와 무기 충전제 및/또는 응집물을 혼합하여, 용융 황 및 무기 충전제 및/또는 응집물을 포함하는 혼합물을 수득하는 단계; 및 (c) 상기 혼합물을 고형화하여, 황 시멘트 또는 황 시멘트-응집물 복합체를 수득하는 단계. 또한, 본 발명은 상기 방법으로 수득가능한 황 시멘트 또는 황 시멘트-응집물 복합체, 및 황 시멘트 또는 황 시멘트-응집물 복합체에서 커플링제로서 2개 이상의 유기실릴기를 갖는 폴리술피드-함유 유기실란의 용도를 제공한다.

4. 发明公开

KR1020090110352A 황 시멘트 생산물의 성형을 위한 주형 및 공정 有权
标题翻译：形成硫酸钙产品的模具和工艺
公开(公告)号：KR1020090110352A
公开(公告)日：2009-10-21
申请号：KR1020097017007
申请日：2008-01-15
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 비보가리요제프알마 , 부어요헴오케 , 글라루끄 , 마우어마르그레트 , 반레스룩 , 베르비스트기로데마그다마리아
IPC分类号： B28B1/54 , B28B7/34 , C04B28/36
CPC分类号： B28B7/348 , B28B1/54 , C04B28/36 , C04B40/02
摘要： The present invention provides a mould for shaping a sulphur cement product, which mould has an inner surface describing an inner volume for receiving a cast material, an outer surface and a barrier comprised between the inner surface and the outer surface, which barrier has a thermal conductance per unit area of at most 100 W/m2K in a direction perpendicular to the inner surface. The invention further provides a process for shaping a sulphur cement product.
摘要翻译：本发明提供了一种用于成型硫磺水泥产品的模具，该模具具有描述用于接收铸造材料的内部容积的内表面，外表面和包含在内表面和外表面之间的屏障，该阻挡层具有热在与内表面垂直的方向上，每单位面积的电导率最多为100W / m2K。本发明还提供了一种硫磺水泥产品成型方法。

5. 发明公开

KR1020100037097A 황 시멘트 예비-조성물 및 그러한 황 시멘트 예비-조성물의 제조 방법 无效
标题翻译：硫磺水泥前体组合物和制备这种硫酸钙组合物的方法
公开(公告)号：KR1020100037097A
公开(公告)日：2010-04-08
申请号：KR1020107000668
申请日：2008-06-11
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 베르비스트기로데마그다마리아 , 반트리에롭알로이시우스마리아 , 란크쉐아르미하엘다비트
IPC分类号： C04B24/40 , C04B28/36
CPC分类号： C04B28/36 , C04B24/405 , C04B40/0039 , C04B12/00
摘要： The present invention provides a sulphur cement pre-composition, comprising sulphur and at least an organotitanate, which organotitanate is of the general molecular formula (1): wherein Ris CH-SRor CHand n is an integer in the range of from 1 to 4, m is an integer in the range or form 1 to 30 and a is an integer in the range of from 2 to 8, R4 is S, H, or CH(and p is an integer in the range of from 1 to 8, XO is an alkoxy or neoalkoxy group, Rand Rare, independently, a CH-SR, alkyl, neoalkyl, acyl or aryl group. The invention further provides a process for preparing such sulphur cement pre-composition, processes for the preparation of a sulphur cement product, a sulphur cement product and the use of such sulphur cement pre-composition. The invention even further relates to the use of an organotitanate stabilizing agent.
摘要翻译：本发明提供一种含硫和至少有机钛酸盐的硫磺水泥预组合物，有机钛酸盐具有通式（1）：其中Ris CH-SRor CH和n为1至4的整数， m为1〜30的整数，a为2〜8的整数，R4为S，H或CH（p为1〜8的整数，XO 本发明还提供了一种制备这种硫磺水泥预处理组合物的方法，硫磺水泥产品的制备方法硫磺水泥产品和使用这种硫磺水泥预组合物，本发明还涉及有机钛酸盐稳定剂的用途。

6. 发明公开

KR1020080073786A 황 시멘트 또는 황 시멘트-응집물 복합체의 제조방법 有权
标题翻译：制备硫酸钙或硫酸钙复合材料的方法
公开(公告)号：KR1020080073786A
公开(公告)日：2008-08-11
申请号：KR1020087016363
申请日：2006-12-07
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 베르비스트기로데마그다마리아 , 판트리르로브알로이지우스마리아
IPC分类号： C04B28/36 , C01B17/04
CPC分类号： C04B28/365 , C04B12/00 , C04B28/36 , C04B14/06 , C04B24/42
摘要： The present invention provides a process for the preparation of sulphur cement or a sulphur cement-aggregate composite comprising the following steps: (a) admixing at least an inorganic filler and/or aggregate and a polysulphide-containing organosilane having at least two organosilyl groups and allowing the organosilane to react with the inorganic filler and/or aggregate; (b) admixing during or after step (a) elemental sulphur with the inorganic filler and/or aggregate at a temperature at which sulphur is liquid to obtain an admixture comprising molten sulphur and inorganic filler and/or aggregate; and (c) solidifying the admixture to obtain sulphur cement or a sulphur cement-aggregate composite. The invention further provides sulphur cement or a sulphur cement-aggregate composite obtainable by such process and the use of a polysulphide-containing organosilane having at least two organosilyl groups as coupling agent in sulphur cement or a sulphur cement-aggregate composite.
摘要翻译：本发明提供一种制备硫磺水泥或硫磺水泥 - 骨料复合材料的方法，包括以下步骤：（a）至少混合至少一种无机填料和/或骨料和含有至少两个有机甲硅烷基的多硫化物的有机硅烷，使有机硅烷与无机填料和/或骨料反应; （b）步骤（a）期间或之后将硫元素与无机填料和/或骨料在硫气的温度下混合，得到包含熔融硫和无机填料和/或骨料的混合物; 和（c）固化混合物以获得硫磺水泥或硫磺水泥骨料复合材料。本发明还提供了可通过这种方法获得的硫磺水泥或硫磺水泥 - 骨料复合材料，并且使用具有至少两个有机甲硅烷基作为硫磺水泥或硫磺水泥 - 骨料复合材料中的偶联剂的多硫化物的有机硅烷。

7. 发明公开

KR1020070086102A 폐 촉매로부터 촉매 지지체의 제조 방법 无效
标题翻译：从废物催化剂制备催化剂支持的方法
公开(公告)号：KR1020070086102A
公开(公告)日：2007-08-27
申请号：KR1020077013258
申请日：2005-12-21
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 레인호우트마리누스요하네스 , 베르비스트기로데마그다마리아
IPC分类号： B01J23/94 , B01J21/06 , B01J38/68 , C07C1/04
CPC分类号： B01J35/0006 , B01J21/063 , B01J23/8892 , B01J23/94 , B01J37/0201 , B01J38/68 , C10G2/33
摘要： A method of preparing, preferably recycling, a catalyst support material is disclosed and is particularly applicable to recycling a titania support. The invention includes crushing the used catalyst support that is obtained by leaching catalytic components from a used supported catalyst and preferably combining it with new catalyst support in order to provide the required average particle size and ratio of crystal phases. The invention has a number of benefits including making use of used catalyst support materials which have been conventionally disposed of and also providing a method to more efficiently recycle the active component. Where the support is recycled for a similar application, less promoter may be required.
摘要翻译：公开了制备，优选地回收催化剂载体材料的方法，并且特别适用于回收二氧化钛载体。本发明包括将所使用的催化剂载体粉碎，所用的催化剂载体是通过从所使用的负载型催化剂中浸出催化组分而获得的，优选将其与新的催化剂载体结合，以提供所需的平均粒度和结晶相的比例。本发明具有许多益处，其中包括使用常规处理的用过的催化剂载体材料，并提供一种更有效地回收活性组分的方法。如果支持被回收用于类似的应用，则可能需要较少的启动子。

8. 发明授权

KR101468944B1 황 시멘트 예비-조성물 및 그러한 황 시멘트 예비-조성물의 제조 방법 有权
标题翻译：硫磺水泥前体组合物和制备这种硫酸钙组合物的方法
公开(公告)号：KR101468944B1
公开(公告)日：2014-12-04
申请号：KR1020097027493
申请日：2008-06-04
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 부르요헴오케 , 하멜린크코르넬리스 , 베르비스트기로데마그다마리아
IPC分类号： C04B14/06 , C04B24/16 , C04B24/42 , C04B28/36
CPC分类号： C04B28/365 , C04B2111/0075 , C04B24/42 , C04B40/0085
摘要： (식중, a 는 2 내지 8 의범위의정수이고, X 및 X' 는각각독립적으로가수분해기이고, n 및 n' 는각각독립적으로 1 내지 4 의범위의정수이고, m 및 m' 는각각독립적으로 1 내지 (2n+1) 의범위의정수임). 본발명은추가로, 상기황 시멘트예비-조성물의제조방법, 황시멘트또는황 시멘트-응집물복합물의제조방법, 황시멘트또는황 시멘트-응집물복합물, 및상기황 시멘트예비-조성물의용도를제공한다.

9. 发明公开

KR1020100041745A 개질된 황 및 개질된 황을 결합제로서 포함하는 제품 无效
标题翻译：改性硫和包含改性硫磺的产品作为粘合剂
公开(公告)号：KR1020100041745A
公开(公告)日：2010-04-22
申请号：KR1020107000208
申请日：2008-06-04
申请人： 쉘 인터내셔날 리써취 마트샤피지 비.브이.
发明人： 안텐스야니비르기타마리아 , 흐리스토바덴카게오르기에바 , 하멜린크코르넬리스 , 베르비스트기로데마그다마리아
IPC分类号： C01B17/02 , C04B28/36
CPC分类号： C04B28/36 , C01B17/0243 , C04B24/42 , C04B24/16
摘要： The invention provides modified sulphur comprising sulphur and a polysulphide-containing organosilane in an amount of in the range of from 0.3 to 25 wt % based on the weight of sulphur, in which modified sulphur the combined amount of sulphur and polysulphide-containing organosilane make up in the range of from 90 to 100 wt % of the obtained modified sulphur and wherein the polysulphide-containing organosilane is of the general molecular formula (1): (XSi)HCn-Sa-Cn'H(SiX'); wherein a is an integer in the range of from 2 to 8, X and X' each are, independently, a hydrolysable group, n and n' each are, independently, an integer in the range of from 1 to 4, and m and m' each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such modified sulphur, a sulphur cement product comprising the modified sulphur and a process for preparing such.
摘要翻译：本发明提供了含硫量和含多硫化物的有机硅烷的改性硫，其含量为硫磺重量的0.3-25％（重量），其中硫和多硫化物的有机硅烷的组合量组成在所得改性硫的90至100重量％的范围内，其中所述含多硫化物的有机硅烷具有通式（1）：（XSi）HCn-Sa-Cn'H（SiX'）; 其中a为2至8的整数，X和X'各自独立地为可水解基团，n和n'各自独立地为1至4的整数，m和 m'各自独立地为1〜（2n + 1）的整数。本发明还提供了制备这种改性硫的方法，包含改性硫的硫磺水泥产品及其制备方法。

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