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1. 发明授权

KR100466941B1 투명한 블록공중합체 수지의 제조방법 失效
标题翻译： 투명한블록공중합체수지의제조방법
公开(公告)号：KR100466941B1
公开(公告)日：2005-01-24
申请号：KR1020010078405
申请日：2001-12-12
申请人： 금호석유화학 주식회사
发明人： 김삼민 , 김종근 , 박종현
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： The present invention relates to a method for preparing a copolymer containing a combined linear and nonlinear block, that is, mikto block, a copolymer prepared from the method, and usages of the copolymer. More particularly, the present invention provides a novel method for preparing a multi-component copolymer by polymerization using a multifunctional compound and one charge of an initiator, and a copolymer having a mikto block including different types of terminal blocks.
摘要翻译：本发明涉及制备含有组合的线性和非线性嵌段即mikto嵌段的共聚物的方法，由该方法制备的共聚物和该共聚物的用途。更具体地说，本发明提供了一种通过使用多官能化合物和一个引发剂进料聚合制备多组分共聚物的新颖方法，以及具有包含不同类型端嵌段的多嵌段共聚物的共聚物。

2. 发明授权

KR100452813B1 2조성 선형 블락 공중합체， 그 제조방법 및 용도 失效
标题翻译： 2조성선형블락공중합체，그제조방법및용도
公开(公告)号：KR100452813B1
公开(公告)日：2004-10-14
申请号：KR1020020026692
申请日：2002-05-15
申请人： 금호석유화학 주식회사
发明人： 김종근 , 김삼민 , 최대승 , 박종현
IPC分类号： C08F295/00
CPC分类号： C08L53/02 , C08F297/04
摘要： The present invention relates to a bimodal linear block copolymer containing a tapered block and its manufacturing method. The bimodal linear block copolymer includes a hepta-block copolymer of vinyl aromatic block(PS1)-conjugated diene block(PB1)-tapered block(T1)-vinyl aromatic block(PS2-PS3)-conjugated diene block(PB2)-tapered block(T2)-vinyl aromatic block (PS4), and a tetra-block copolymer of vinyl aromatic block(PS3)-conjugated diene block(PB2)-tapered block(T2)-vinyl aromatic block (PS4) as prepared by adding two charges of an initiator. The bimodal linear block copolymer is prepared by adding several charges of the initiator, vinyl aromatic monomers and conjugated diene monomers to acquire transparency, toughness, rigidity and flexibility, and thereby can be used for sheets or films, or injection or blow molding products.
摘要翻译：本发明涉及含有锥形嵌段的双峰线性嵌段共聚物及其制造方法。双峰线型嵌段共聚物包括乙烯基芳族嵌段（PS1） - 共轭二烯嵌段（PB1） - 嵌段嵌段（T1） - 乙烯基芳族嵌段（PS2-PS3） - 共轭二烯嵌段（PB2） - 嵌段嵌段（T2） - 乙烯基芳香嵌段（PS4）和乙烯基芳香嵌段（PS3） - 共轭二烯嵌段（PB2） - 嵌段嵌段（T2） - 乙烯基芳香嵌段（PS4）的四嵌段共聚物的发起人。双峰线性嵌段共聚物是通过加入几个引发剂，乙烯基芳族单体和共轭二烯单体以获得透明性，韧性，刚性和柔韧性，从而可以用于片材或薄膜，或注塑或吹塑产品。

3. 发明授权

KR100452812B1 2조성 선형 블락 공중합체，제조방법 및 용도 失效
标题翻译： 2조성선형블락공중합체，제조방법및용도
公开(公告)号：KR100452812B1
公开(公告)日：2004-10-14
申请号：KR1020020026691
申请日：2002-05-15
申请人： 금호석유화학 주식회사
发明人： 김종근 , 김삼민 , 최대승 , 박종현
IPC分类号： C08F295/00
CPC分类号： C08F297/04
摘要： The present invention relates to a bimodal linear block copolymer containing a tapered block and its manufacturing method. The bimodal linear block copolymer includes a hexa-block copolymer of vinyl aromatic block(PS1)-conjugated diene block(PB1)-tapered block(T1)-vinyl aromatic block(PS2-PS3)-conjugated diene block(PB2)-vinyl aromatic block (PS4) as prepared by adding two charges of an initiator, and a tri-block copolymer of vinyl aromatic block(PS3)-conjugated diene block(PB2)-vinyl aromatic block (PS4). The bimodal linear block copolymer is prepared by adding more than one charge of the initiator, vinyl aromatic monomers and conjugated diene monomers to acquire transparency, toughness, rigidity and flexibility, and thereby can be used for sheets or films, or injection or blow molding products.
摘要翻译：本发明涉及含有锥形嵌段的双峰线性嵌段共聚物及其制造方法。双峰线性嵌段共聚物包括乙烯基芳族嵌段（PS1） - 共轭二烯嵌段（PB1） - 嵌段（T1） - 乙烯基芳族嵌段（PS2-PS3） - 共轭二烯嵌段（PB2） - 乙烯基芳香烃的六嵌段共聚物通过加入两种电荷的引发剂和乙烯基芳族嵌段（PS3） - 共轭二烯嵌段（PB2） - 乙烯基芳族嵌段（PS4）的三嵌段共聚物制备的嵌段（PS4）。双峰线性嵌段共聚物是通过加入多于一个的引发剂，乙烯基芳族单体和共轭二烯单体以获得透明性，韧性，刚性和柔韧性，从而可以用于片材或薄膜，或注塑或吹塑产品。

4. 发明授权

KR100471716B1 연속식 음이온 중합에 의한 내충격 비닐 방향족 고분자의제조방법 失效
标题翻译：通过连续阴离子聚合法制备高抗冲乙烯基芳族聚合物的方法
公开(公告)号：KR100471716B1
公开(公告)日：2005-03-10
申请号：KR1020020045949
申请日：2002-08-03
申请人： 금호석유화학 주식회사
发明人： 배종현 , 박종현 , 김종근 , 최대승 , 김삼민
IPC分类号： C08F2/26 , C08F12/08 , C08F279/02
CPC分类号： C08F297/04
摘要： 본 발명은 비닐 방향족류 100몰에 대해 중합 개시제 0.01∼1몰, 공액디엔 단량체 1∼100몰을 투입하여 전체 반응물 대비 50∼500 (w/v)% 양의 탄화수소 용매 존재 하에서 30∼160℃의 중합 온도로 연속식 음이온 용액 중합방법에 의해 투명 내충격 고분자를 제조하는 방법에 있어서, 상기 연속식 음이온 중합방법은 3기의 완전교반 반응기를 직렬식으로 연결한 후 첫 번째 반응기(1a)에서는 반응개시제, 비닐 방향족 단량체, 용매 및 극성유기물을 연속적으로 투입하여 비닐 방향족 고분자를 제조하고, 두 번째 반응기(1b)에서는 첫 번째 반응기에서 중합된 비닐 방향족 고분자에 다시 유기용매, 비닐 방향족 단량체, 공액디엔 단량체를 연속적으로 투입하여 테이퍼드 공액디엔-비닐 방향족 공중합체의 분자사슬을 형성시키고, 세 번째 반응기(1c)에서는 두 번째 반응� �에서 중합된 고분자에 다시 유기용매와 비닐 방향족 단량체 또는 다관능성 화합물을 투입하여 내충격 고분자를 제조하여 반응 종결제로 반응을 종결시켜 잔류 탄화수소 용매와 미반응 단량체를 제거시킴을 특징으로 하는 최종 고분자의 수평균 분자량이 20,000∼1,000,000 이고 분자량 분포도가 1.1∼20 인 투명 내충격 비닐 방향족 고분자의 제조방법에 관한 것이다. 본 발명에 의해 제조된 고분자는 큰 분자량 분포도를 가지게 되어 최종 제품의 가공이 용이하게 되고, 용이한 반응열 제어에 의한 생산 안정성, 소량의 용매 사용으로 인한 반응 용매의 회수 용이성 및 높은 생산성을 가지게 된다. 또한 본 발명은 유기 금속화합물을 개시제로 사용하며, 완전 교반 연속식 반응기를 이용하여 투명 내충격 고분자, 특히 산업적으로 많이 사용되는 투명 내충격 폴리스티렌수지의 제조에 관한 새로운 방법이며, 연속식 반응을 이용하여 배치식 중합법의 낮은 생산성을 보완한 것이다.

5. 发明授权

KR100428514B1 선형과 비선형성 구조가 혼합된 중합체 및 그 제조방법 失效
标题翻译： 선형과비선형성구조가혼합된합합체및그제조방
公开(公告)号：KR100428514B1
公开(公告)日：2004-04-29
申请号：KR1020010071280
申请日：2001-11-16
申请人： 금호석유화학 주식회사
发明人： 김삼민 , 김종근 , 박종현
IPC分类号： C08F297/04
CPC分类号： C08F297/044 , C08F297/04 , C08L53/02 , C08L2666/02
摘要： A combined linear and nonlinear polymer (i.e., having a combined linear, branched and radial structure) P+PnD according to the present invention is represented by (P+PnD)-+Li, where P is a polymer of a monovinyl aromatic monomer or a conjugated diene monomer; PD is a nonlinear polymer having a combined linear, branched and radial structure due to a multifunctional compound D bonded to the polymer P; n is an integer ranging from 2 to 10 and represents the average number of bonds between the monovinyl aromatic or conjugated diene polymer P and the multifunctional compound D; and +Li represents a metal ion as a partner of the active anion (P+PnD)-. The combined linear and nonlinear polymer of the present invention, characterized by nonlinearity-related properties (i.e., low melting viscosity, low melting properties and high mechanical properties), can be used alone as a plastic material and freely introduced to different copolymer resins that are used as stiffening agents having a different property such as impact strength or thermal stability.
摘要翻译：（P + PnD） - + Li表示根据本发明的组合线性和非线性聚合物（即，具有组合线性，分支和放射状结构）P + PnD，其中P是单乙烯基芳族单体的聚合物或共轭二烯单体; PD是由于键合到聚合物P上的多官能化合物D而具有组合的直链，支链和放射状结构的非线性聚合物; n是2-10的整数，表示单乙烯基芳族或共轭二烯聚合物P与多官能化合物D之间的平均键数; 并且+ Li表示作为活性阴离子（P + PnD） - 的配偶体的金属离子。以非线性相关特性（即低熔融粘度，低熔融特性和高机械特性）为特征的本发明的组合线性和非线性聚合物可以单独用作塑料材料并且可以自由地引入不同的共聚物树脂用作具有不同性能例如冲击强度或热稳定性的硬化剂。

6. 发明公开

KR1020030088771A 2조성 선형 블락 공중합체，제조방법 및 용도 失效
标题翻译：双组分线性嵌段共聚物，制备方法及其用途
公开(公告)号：KR1020030088771A
公开(公告)日：2003-11-20
申请号：KR1020020026691
申请日：2002-05-15
申请人： 금호석유화학 주식회사
发明人： 김종근 , 김삼민 , 최대승 , 박종현
IPC分类号： C08F295/00
CPC分类号： C08F297/04
摘要： PURPOSE: A two-component linear block copolymer, its preparation method and a bubble pack prepared by using the copolymer are provided, to improve the transparency, the strength and the flexibility. CONSTITUTION: The two-component linear block copolymer contains a tapered block, is obtained from at least one vinyl aromatic monomer of C8-C12 and at least one conjugated diene monomer of C4-C6, and comprises 55-95 wt% of a vinyl aromatic monomer and 5-45 wt% of a conjugated diene monomer. The two-component linear block copolymer comprises 30-90 wt% of a hexablock copolymer of vinyl aromatic block-conjugated diene block-tapered block-vinyl aromatic block-conjugated diene block-vinyl aromatic block; and 10-70 wt% of a triblock copolymer of vinyl aromatic-conjugated diene block-vinyl aromatic block.
摘要翻译：目的：提供双组分线性嵌段共聚物，其制备方法和使用共聚物制备的气泡包，以提高透明度，强度和柔韧性。构成：双组分线性嵌段共聚物含有锥形嵌段，由C 8 -C 12的至少一种乙烯基芳族单体和至少一种C 4 -C 6的共轭二烯单体获得，并且包含55-95wt％的乙烯基芳族单体和5-45重量％的共轭二烯单体。双组分线性嵌段共聚物包含30-90重量％的乙烯基芳族嵌段共轭二烯嵌段 - 嵌段 - 乙烯基芳族嵌段 - 共轭二烯嵌段 - 乙烯基芳族嵌段的六嵌段共聚物; 和10-70重量％的乙烯基芳族 - 共轭二烯嵌段 - 乙烯基芳族嵌段的三嵌段共聚物。

7. 发明公开

KR1020030039900A 선형과 비선형성 구조가 혼합된 중합체 및 그 제조방법 失效
标题翻译：聚合物与线性和非线性结构混合及其制备方法
公开(公告)号：KR1020030039900A
公开(公告)日：2003-05-22
申请号：KR1020010071280
申请日：2001-11-16
申请人： 금호석유화학 주식회사
发明人： 김삼민 , 김종근 , 박종현
IPC分类号： C08F297/04
CPC分类号： C08F297/044 , C08F297/04 , C08L53/02 , C08L2666/02
摘要： PURPOSE: A polymer mixed with the linear and nonlinear structures and its preparation method are provided, wherein the polymer has a low melting viscosity, a low melting properties and high mechanical properties. CONSTITUTION: The polymer is represented by (P + PnD)- Li+, wherein P is a polymer of a monovinyl aromatic monomer or a conjugated diene monomer; PD is a nonlinear polymer where the polymer(P) of a monovinyl aromatic monomer or a conjugated diene monomer is present in the mixed state of linear, branched or radical polymers by a multifunctional compound(D); n is an average binding number of the polymer(P) by the multifunctional compound(D), and is an integer of 2-10; (P + PnD)- represents a vinyl aromatic or conjugated diene polymer mixed with the linear and nonlinear structures; and Li+ is a lithium cation. Preferably the polymer(P) has a mass average molecular weight of 500-1,000,000.
摘要翻译：目的：提供与线性和非线性结构物混合的聚合物及其制备方法，其中聚合物具有低熔融粘度，低熔点和高机械性能。构成：聚合物由（P + PnD）-Li +表示，其中P是单乙烯基芳族单体或共轭二烯单体的聚合物; PD是一种非线性聚合物，其中单乙烯基芳族单体或共轭二烯单体的聚合物（P）以多官能化合物（D）以直链，支链或自由基聚合物的混合状态存在; n是多官能化合物（D）的聚合物（P）的平均结合数，为2-10的整数，（P + PnD） - 表示与线性和非线性结构混合的乙烯基芳族或共轭二烯聚合物; Li +是锂阳离子。优选聚合物（P）的质均分子量为500-1,000,000。

8. 发明公开

KR1020030088772A 2조성 선형 블락 공중합체， 그 제조방법 및 용도 失效
标题翻译：双组分线性嵌段共聚物，制备方法及其用途
公开(公告)号：KR1020030088772A
公开(公告)日：2003-11-20
申请号：KR1020020026692
申请日：2002-05-15
申请人： 금호석유화학 주식회사
发明人： 김종근 , 김삼민 , 최대승 , 박종현
IPC分类号： C08F295/00
CPC分类号： C08L53/02 , C08F297/04
摘要： PURPOSE: A two-component linear block copolymer comprising a heptablock copolymer and a tetrablock copolymer, its preparation method and a bubble pack prepared by using the copolymer are provided, to improve the transparency, the strength and the flexibility. CONSTITUTION: The two-component linear block copolymer comprising a heptablock copolymer and a tetrablock copolymer, contains a tapered block, is obtained from at least one vinyl aromatic monomer of C8-C12 and at least one conjugated diene monomer of C4-C6, and comprises 55-95 wt% of a vinyl aromatic monomer and 5-45 wt% of a conjugated diene monomer. The two-component linear block copolymer comprises 30-90 wt% of a heptablock copolymer of vinyl aromatic block-conjugated diene block-tapered block-vinyl aromatic block-conjugated diene block-tapered block-vinyl aromatic block; and 10-70 wt% of a tetrablock copolymer of vinyl aromatic-conjugated diene block-tapered block-vinyl aromatic block.
摘要翻译：目的：提供包含七嵌段共聚物和四嵌段共聚物的双组分线性嵌段共聚物，其制备方法和通过使用共聚物制备的气泡包，以提高透明度，强度和柔性。构成：包含七嵌段共聚物和四嵌段共聚物的双组分线性嵌段共聚物含有渐缩嵌段，其由C 8 -C 12的至少一种乙烯基芳族单体和至少一种C 4 -C 6的共轭二烯单体获得，并且包含 55-95重量％的乙烯基芳族单体和5-45重量％的共轭二烯单体。双组分线性嵌段共聚物包含30-90重量％的乙烯基芳族嵌段共轭二烯嵌段 - 嵌段 - 乙烯基芳族嵌段 - 共轭二烯嵌段 - 嵌段 - 乙烯基芳族嵌段的七嵌段共聚物; 和10-70重量％的乙烯基芳族 - 共轭二烯嵌段 - 嵌段 - 乙烯基芳族嵌段的四嵌段共聚物。

9. 发明公开

KR1020030048498A 투명한 블록공중합체 수지의 제조방법 失效
标题翻译：制备透明嵌段共聚物树脂的方法及其获得的共聚物及其用途
公开(公告)号：KR1020030048498A
公开(公告)日：2003-06-25
申请号：KR1020010078405
申请日：2001-12-12
申请人： 금호석유화학 주식회사
发明人： 김삼민 , 김종근 , 박종현
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： PURPOSE: A process for preparing transparent block copolymer resins is provided to simplify the working process and to improve the mechanical properties such as strength and flexibility of the resin. A block copolymer having various structures and compositions and a transparent bottle and a bubble pack obtained therefrom are also provided. CONSTITUTION: The process for preparing transparent block copolymer resins comprises the step of polymerizing 55 to 95 wt% of at least one of vinyl aromatic monomers and 45 to 5 wt% of at least one of conjugated diene monomers under solution polymerization conditions by multiple introductions of the monomers. The process is characterized by comprising the steps of: introducing a monovinyl aromatic monomer, a polar organic compound and an anionic initiator to obtain an anionic polymer block; introducing a multi-functional compound and a conjugated diene monomer to obtain a mikto-block of the polymer in which linear and non-linear structures are mixed; introducing a conjugated diene monomer; introducing a vinyl aromatic monomer; and introducing a multi-functional coupling agent.
摘要翻译：目的：提供一种制备透明嵌段共聚物树脂的方法，以简化工作过程并提高机械性能，如树脂的强度和柔韧性。还提供了具有各种结构和组成的嵌段共聚物和由其获得的透明瓶和泡罩组。构成：制备透明嵌段共聚物树脂的方法包括在溶液聚合条件下通过多次引入的聚合条件，在溶液聚合条件下聚合55至95重量％的至少一种乙烯基芳族单体和45至5重量％的至少一种共轭二烯单体的步骤单体。该方法的特征在于包括以下步骤：引入单乙烯基芳族单体，极性有机化合物和阴离子引发剂以获得阴离子聚合物嵌段; 引入多官能化合物和共轭二烯单体以获得其中混合线性和非线性结构的聚合物的弹性嵌段; 引入共轭二烯单体; 引入乙烯基芳族单体; 并引入多功能偶联剂。

10. 发明公开

KR1020020068020A 연속식 음이온 중합에 의한 내충격 비닐 방향족 고분자의제조방법 失效
标题翻译：通过连续阴离子聚合制备耐冲击乙烯基芳族聚合物的制备方法
公开(公告)号：KR1020020068020A
公开(公告)日：2002-08-24
申请号：KR1020020045949
申请日：2002-08-03
申请人： 금호석유화학 주식회사
发明人： 배종현 , 박종현 , 김종근 , 최대승 , 김삼민
IPC分类号： C08F2/26 , C08F12/08 , C08F279/02
CPC分类号： C08F297/04
摘要： PURPOSE: A method for preparing a transparent impact-resistant vinyl aromatic polymer by continuous anionic polymerization is provided, to obtain the polymer with a mean number molecular weight of 20,000-1,000,000 and a distribution of molecular weight of 1.1-20. CONSTITUTION: The method comprises the step of reacting 100 mol of a vinyl aromatic compound, 0.01-1 mol of a polymerization initiator and 1-100 mol of a conjugated diene monomer in the presence of 50-500 w/v% of hydrocarbon solvent at 30-160 deg.C. Also the method comprises the steps of connecting three complete stirring reactors in serial; injecting a reaction initiator, a vinyl aromatic monomer, a solvent and a polar organic compound continuously into a first reactor(1a) to prepare a vinyl aromatic polymer; injecting the obtained vinyl aromatic polymer, an organic solvent, a vinyl aromatic monomer and a conjugated diene monomer continuously into the second reactor(1b) to form the molecular chain of tapered conjugated diene-vinyl aromatic copolymer; injecting the obtained polymer, an organic solvent, a vinyl aromatic monomer or a polyfunctional compound into the third reactor(1c) to obtain an impact-resistant polymer; and terminating the reaction with a reaction terminator and removing the remaining hydrocarbon and the unreacted monomer.
摘要翻译：目的：提供通过连续阴离子聚合制备透明耐冲击乙烯基芳族聚合物的方法，得到平均数分子量为20,000-1,000,000，分子量为1.1-20的聚合物。方案：该方法包括在50-500w / v％的烃溶剂存在下，将100mol乙烯基芳族化合物，0.01-1mol聚合引发剂和1-100mol共轭二烯单体反应的步骤 30-160摄氏度该方法还包括连续连接三台完整的搅拌反应器的步骤; 将反应引发剂，乙烯基芳族单体，溶剂和极性有机化合物连续注入到第一反应器（1a）中以制备乙烯基芳族聚合物; 将获得的乙烯基芳族聚合物，有机溶剂，乙烯基芳族单体和共轭二烯单体连续注入到第二反应器（1b）中以形成渐缩共轭二烯 - 乙烯基芳族共聚物的分子链; 将所得聚合物，有机溶剂，乙烯基芳族单体或多官能化合物注入第三反应器（1c）中以获得耐冲击聚合物; 并用反应终止剂终止反应并除去剩余的烃和未反应的单体。

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