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1. 发明公开

KR20120028067A Catalysts for preparing 1-hexene and method for preparing 1-hexene using the same 有权
标题翻译：用于制备1-HEXENE的催化剂和使用其制备1-HEXENE的方法
公开(公告)号：KR20120028067A
公开(公告)日：2012-03-22
申请号：KR20100090046
申请日：2010-09-14
申请人： HONAM PETROCHEMICAL CORP
发明人： KIM YOUNG KOOK , KIM HWA KYU , PARK JAE YOUNG , YOON SEUNG WOONG
IPC分类号： B01J31/12 , C07C2/30 , C07C11/107
CPC分类号： B01J31/12 , B01J31/143 , C07C2/30 , C07C11/107
摘要： PURPOSE: Catalyst for preparing 1-hexene and a method for preparing 1-hexene using the same are provided to save energy required for preparing 1-hexene and to prevent the use of chromium causing environmental problems. CONSTITUTION: Catalyst for preparing 1-hexene includes transition metal compound and cocatalyst compound. The transition metal compound is represented by chemical formula 1. The cocatalyst compound activates the transition metal compound by being reacted with the transition metal compound. In chemical formula 1, the M1 and the M2 are identical or different and is selected from a group including group 3 to 10 elements on the periodic table; the Cp1 and the Cp2 are identical or different and is ligand with a cyclopentadienyl structure which is substituted or non-substituted with one or more substituent selected from C1 to 20 alkyl group, C3 to 20 cycloalkyl group, C1 to 20 alkylsilyl group, C1 to 20 halo alkyl group, C6 to 20 aryl group, C7 to 20 arylalkyl group, C6 to 20 arylsilyl group, C7 to 20 alkylaryl group, C1 to 20 alkoxy group, C1 to 20 alkyl siloxy group, C6 to 20 aryloxy group, halogen group, and amino group; the B1 and the B2 are identical or different and are bridging group containing group 13 to 16 elements on the periodic table; the n is the integer of 1 to 0; and the Ar1 and the Ar2 are identical or different and are aryl group.
摘要翻译：目的：提供用于制备1-己烯的催化剂和使用其制备1-己烯的方法，以节省制备1-己烯所需的能量并防止使用铬引起环境问题。构成：用于制备1-己烯的催化剂包括过渡金属化合物和助催化剂。过渡金属化合物由化学式1表示。助催化剂化合物通过与过渡金属化合物反应来活化过渡金属化合物。在化学式1中，M1和M2相同或不同，选自元素周期表中第3至10族元素; Cp1和Cp2是相同或不同的，并且是具有环戊二烯基结构的配体，其被一个或多个选自C1至20烷基，C3至20环烷基，C1至20烷基甲硅烷基，C1- 20卤代烷基，C6〜20芳基，C7〜20芳烷基，C6〜20芳基甲硅烷基，C7〜20烷基芳基，C1〜20烷氧基，C1〜20烷基甲硅烷氧基，C6〜20芳氧基，卤素基和氨基; B1和B2是相同或不同的，并且是在周期表上含有13至16个元素的桥连基团; n为1〜0的整数; Ar 1和Ar 2相同或不同，为芳基。

2. 发明授权

KR100913888B1 CARBON DIOXIDE PURIFICATION METHOD AND EQUIPMENT FOR WASTE GAS OF PROCESS USING PURE OXYGEN COMBUSTION 有权
标题翻译：二氧化碳净化方法和使用纯氧气的废气进程的设备
公开(公告)号：KR100913888B1
公开(公告)日：2009-08-26
申请号：KR20090033712
申请日：2009-04-17
申请人： HONAM PETROCHEMICAL CORP , HANDOK ENG CO LTD
发明人： PARK GI CHUL , KIM YEON SEOP , LEE DONG HEE , HWANG YEAL SOON , LEE EUN IL , PARK WOO SUNG
IPC分类号： C01B32/50 , B01D53/92
CPC分类号： B01D53/62 , B01D2256/22 , B01D2257/708 , C01B32/50 , F23G5/50 , F23G7/065 , F23G2207/103 , F23G2207/104 , F23G2207/30 , F23G2208/10 , F23G2900/55003 , F23G2900/55011 , F23J2215/50 , F23L7/007 , Y02C10/04 , Y02E20/322 , Y02E20/344 , Y02P20/152 , B01D53/92
摘要： A carbon dioxide purification method and a device for waste gas of a process using pure oxygen combustion are provided to collect carbon dioxide of high purity, to prevent discharge of harmful materials. A device for waste gas of a process using pure oxygen combustion to collect carbon dioxide includes the followings: a combustion unit(140) burning VOC in exhaust gas in which combustible impurities are mixed; an air intake blower(130,210) and a burner; a pressure reducing valve(112) reducing pressure of exhaust gas; a mixer(122) mixing pure oxygen into the exhaust gas; an oxygen measuring unit(143) and a carbon dioxide supplying unit; a LEL measuring unit(131); an auxiliary fuel supply unit; and a heat exchanger(180) heating inflow waste gas and removing moisture among the burned gas.
摘要翻译：提供二氧化碳净化方法和使用纯氧燃烧的方法的废气装置以收集高纯度的二氧化碳，以防止有害物质的排放。一种使用纯氧燃烧收集二氧化碳的方法的废气装置包括：燃烧单元（140），其燃烧可燃杂质混入废气中的VOC; 进气鼓风机（130,210）和燃烧器; 减压阀（112），减少排气压力; 将纯氧混入废气中的混合器（122）; 氧测量单元（143）和二氧化碳供应单元; LEL测量单元（131）; 辅助燃料供应单元; 以及热交换器（180），其加热流入的废气并除去所述燃烧气体中的水分。

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